石墨烯/ABS 3D打印复合材料的制备与性能研究

吕冰倩, 陆佳琪, 刘威, 沈书缘, 计建炳, 张智亮*

化工新型材料 ›› 2023, Vol. 51 ›› Issue (1) : 254 -258.

PDF
化工新型材料 ›› 2023, Vol. 51 ›› Issue (1) : 254-258. DOI: 10.19817/j.cnki.issn1006-3536.2023.01.048
开发与应用

石墨烯/ABS 3D打印复合材料的制备与性能研究

    吕冰倩, 陆佳琪, 刘威, 沈书缘, 计建炳, 张智亮*
作者信息 +

Preparation of graphene/ABS 3D printing composite materials and its performance

  • Lv Bingqian, Lu Jiaqi, Liu Wei, Shen Shuyuan, Ji Jianbing, Zhang Zhiliang
Author information +
文章历史 +
PDF

摘要

采用气体驱动液相剥离法制备了石墨烯/丙烯腈-丁二烯-苯乙烯共聚物(ABS)3D打印复合材料,测试了材料的力学性能和导电性能。结果表明:石墨烯的添加可以显著地提升3D打印耗材的拉伸强度、弹性模量及导电性;当石墨烯添加质量为4.8%时,复合材料的拉伸强度、弹性模量、最大拉力及电导率达到最大,分别为210MPa、5166MPa、0.4kN及4.46×10-3S/m。

Abstract

The graphene/acrylonitrile-butadiene-styrene copolymer (ABS) 3D printing composite materials were prepared by gas-driven liquid-phase exfoliation method.The mechanical properties and electrical conductivity of the materials were tested.The results showed that the addition of graphene significantly improved the tensile strength,elastic modulus and conductivity of 3D printing composite materials.When the graphene content was 4.8%,the tensile strength,elastic modulus,maximum tensile force,and electrical conductivity reached the maximum and were 210MPa,5166MPa,380N,and 4.56×10-3S/m,respectively.

关键词

丙烯腈-丁二烯-苯乙烯 / 石墨烯 / 3D打印 / 复合材料

Key words

acrylonitrile-butadiene-styrene copolymer / graphene / 3D printing / composite materials

引用本文

引用格式 ▾
石墨烯/ABS 3D打印复合材料的制备与性能研究[J]. 化工新型材料, 2023, 51(1): 254-258 DOI:10.19817/j.cnki.issn1006-3536.2023.01.048

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 冷洋,许苗军,李斌.3D打印高分子材料的研究进展[J].化工新型材料,2017,45(12):198-201.
[2] Yu W W,Zhang J,Wu J R,et al.Incorporation of graphitic nano-filler and poly(lactic acid) in fused deposition modeling[J].Journal of Applied Polymer Science,2017,134:15.
[3] 唐鹿,薛飞,李旺,等.熔融沉积成型3D打印ABS材料的改性与应用研究[J].化工新型材料,2017(12):19-21,26.
[4] 马晓坤,张慧冬,马伯乐,等.3D打印用碳纤维/ABS复合材料的制备[J].化工新型材料,2019,47(9):229-231.
[5] Jyoti J,Singh B P,Arya A K,et al.Dynamic mechanical properties of multiwall carbon nanotube reinforced ABS composites and their correlation with entanglement density,adhesion,reinforcement and C factor[J].RSC Advances,2016,6(5):3997-4006.
[6] Sharma S K,Gupta V,Tandon R P,et al.Synergic effect of graphene and MWCNT fillers on electromagnetic shielding properties of graphene-MWCNT/ABS nanocomposites[J].RSC Advances,2016,6(22):18257-18265.
[7] Shrivastava N K,Suin S,Maiti S,et al.An approach to reduce the percolation threshold of MWCNT in ABS/MWCNT nanocomposites through selective distribution of CNT in ABS matrix[J].RSC Advances,2014,4:24584.
[8] Hernandez Y,Nicolosi V,Lotya M,et al.High-yield production of graphene by liquid-phase exfoliation of graphite[J].Nature Nanotechnology,2008,3(9):563-568.
[9] Goncalves H,Fernandes J,Moura C,et al.Easy process to obtain suspended graphene flakes on TEM grids[J].Materials Research Express,2015,2(5):2053-1591.
[10] Meyer J C,Geim A K,Katsnelson M I,et al.The structure of suspended graphene sheets[J].Nature,2007,446:60-63.
[11] Meyer J C.Transmission electron microscopy (TEM) of graphene[J].Graphene,2014:101-123.
[12] 舒浩然.形状记忆聚合物及其复合材料形状记忆性能研究[D].南京:南京航空航天大学,2012.
[13] Stevanovic D,Lowe A,Kalyanasundaram S,et al.Chemical and mechanical properties of vinyl-ester/ABS blends[J].Polymer,2002,43(16):4503-4514.
[14] Young R J,Kinloch I A,Gong L,et al.The mechanics of graphene nanocomposites:a review[J].Composites Science and Technology,2012,72(12):459-1476.
[15] 李前进,诸葛祥群,赵俊,等.石墨/丙烯腈-丁二烯-苯乙烯共聚物导电3D打印复合耗材的制备与性能研究[J].化工新型材料,2018,46(11):72-75,79.
[16] Ferrari A C,Meyer J C,Scardaci V,et al.Raman spectrum of graphene and graphene layers[J].Physical Review Letters,2006,97(18):187401.
[17] Sun Y Q,Shi G Q.Graphene/polymer composites for energy applications[J].Journal of Polymer Science Part B-Polymer Physics,2013,51(4):231-253.
[18] Xu Q,Mondal B,Lyons A,et al.Fabricating superhydrophobic polymer surfaces with excellent abrasion resistance by a simple lamination templating method[J].ACS Applied Materials & Interfaces,2011,3(9):3508-3514.
[19] Wei X,Li D,Jiang W,et al.3D Printable graphene composite[J].Scientific Reports,2015,5(1):11181.

基金资助

国家自然科学基金(21406198)

AI Summary AI Mindmap
PDF

583

访问

0

被引

导航
相关文章

AI思维导图

/