金属有机框架材料(MOFs)是一类由金属离子和有机配体通过配位形成的高度有序的晶体聚合物,具有多变的拓扑结构及独特的物理化学性质。因其具备高的比表面积、可调整的孔径、高密度活性位点和高催化活性等优点日益受到人们的关注。近十几年来,众多科研工作者尝试将MOFs材料用于光催化反应与电催化反应,并取得了一系列科研成果。以近年来基于MOFs材料的催化反应类型为分类依据,对其在光催化与电催化中的应用研究进行综述,并对其未来发展进行展望。
Metal-organic frameworks (MOFs),as a kind of highly ordered porous coordination polymers,are composed of inorganic metal units and organic ligands,having variable topologies and unique physical and chemical properties.MOFs have attracted extensive attention because of their ultrahigh surface area,adjustable pore size,rich active sites as well as high catalytic activity.In recent years,researchers have tried to use MOFs materials for photocatalysis and electrocatalysis,and achieved a series of remarkable achievements.According to the reaction styles,the article summarized the applications of MOFs in photocatalysis and electrocatalysis in recent years,and the future research directions were also discussed.
[1] Bao J,Yang G H,Yoneyama Y,et al.Significant advances in C1 catalysis:highly efficient catalysts and catalytic reactions[J].ACS Catal,2019,9(4):3026-3053.
[2] Wei Y S,Zhang M,Zou R,et al.Metal-organic framework-based catalysts with single metal sites[J].Chem Rev,2020,120(21):12089-12174.
[3] Zhou H C,Long J R,Yaghi O M.Introduction to metal-organic frameworks[J].Chem Rev,2012,112(2):673-674.
[4] Yi J D,Zhang M D,Hou Y,et al.N-doped carbon aerogel derived from a metal-organic framework foam as an efficient electrocatalyst for oxygen reduction[J].Chem Asian J,2019,14(20):3642-3647.
[5] Wei Y S,Zhang M,Zou R,et al.Metal-organic framework-based catalysts with single metal sites[J].Chem Rev,2020,120(21):12089-12174.
[6] Xu W J,Li W,Wen H,et al.Metal/metal-organic framework interfacial ensemble-induced dual site catalysis towards hydrogen generation[J].Appl Catal,B,2021,286:119946.
[7] Zhao S N,Wang G,Poelman D,et al.Luminescent lanthanide MOFs:a unique platform for chemical sensing[J].Materials,2018,11(4):572.
[8] Song H,Li X J,Jiang B L,et al.Preparation of novel and highly stable Py/MOF and its adsorptive desulfurization performance[J].Ind Eng Chem Res,2019,58(42):19586-19598.
[9] Li Z,Wang H Z,Canossa S,et al.Pore chemistry of metal-organic frameworks[J].Adv Funct Mater,2020,30(41):2000238.
[10] Zhao S N,Wang G,Poelman D,et al.Metal organic frameworks based materials for heterogeneous photocatalysis[J].Molecules,2018,23(11):2947.
[11] Yu H,Toyao T,Miyahara K,et al.Visible-light-driven photocatalytic water oxidation catalysed by iron-based metal-organic framework[J].Chem Commun,2016,52(29):5190-5193.
[12] Zhang F M,Sheng J L,Yang Z D,et al.Rational design of MOF/COF hybrid materials for photocatalytic H2 evolution in the presence of sacrificial electron donors[J].Angew Chem Int Ed,2018,57(37):12106-12110.
[13] Zuo Q,Liu T T,Chen C S,et al.Ultrathin metal-organic framework nanosheets with ultrahigh loading of single Pt atoms for efficient visible-light-driven photocatalytic H2evolution[J].Angew Chem Int Ed,2019,58(30):10198-203.
[14] Ma X,Wang L,Zhang Q,et al.Switching on the photocatalysis of metal-organic frameworks by engineering structural defects[J].Angew Chem Int Ed,2019,58(35):12175-12179.
[15] Song Y,Li Z,Zhu Y,et al.Titanium hydroxide secondary building units in metal-organic frameworks catalyze hydrogen evolution under visible light[J].J Am Chem Soc,2019,141(31):12219-12223.
[16] Feng X Y,Pi Y H,Song Y,et al.Metal-organic frameworks significantly enhance photocatalytic hydrogen evolution and CO2 reduction with earth-abundant copper photosensitizers[J].J Am Chem Soc,2020,142(2):690-695.
[17] Wang S B,Wang X C.Imidazolium ionic liquids,imidazolylidene heterocyclic carbenes,and zeoliticimidazolate frameworks for CO2 capture and photochemical reduction[J].Angew Chem Int Ed,2016,55(7):2308-2320.
[18] Chen E X,Qiu M,Zhang Y F,et al.Acid and base resistant zirconium polyphenolate-metalloporphyrin scaffolds for efficient CO2 photoreduction[J].Adv Mater,2018,30(2):1704388.
[19] Chen S Y,Hai G D,Gao H Y,et al.Modulation of the charge transfer behavior of Ni(Ⅱ)-doped NH2-MIL-125(Ti):regulation of Ni ions content and enhanced photocatalytic CO2 reduction performance[J].Chem Eng J,2021,406:126886.
[20] Li J,Huang H L,Xue W J,et al.Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2photoreduction to CH4[J].Nat Catal,2021,4:719-729.
[21] Xu C Y,Pan Y T,Wan G,et al.Turning on visible-light photocatalytic C—H oxidation over metal-organic frameworks by introducing metal-to-cluster charge transfer[J].J Am Chem Soc,2019,141(48):19110-19117.
[22] Liu H,Xu C Y,Li D D,et al.Photocatalytic hydrogen production coupled with selective benzylamine oxidation over MOF composites[J].Angew Chem Int Ed,2018,57(19):5379-5383.
[23] Zhu Y Y,Lan G X,Fan Y J,et al.Mergingphotoredox and organometallic catalysts in a metal-organic framework significantly boosts photocatalytic activities[J].Angew Chem Int Ed,2018,57(43):14090-14094.
[24] Prier C K,Rankic D A,Macmillan D W C.ChemInform abstract:visible light photoredox catalysis with transition metal complexes:applications in organic synthesis[J].Chem Rev,2013,113(7):5322-5363.
[25] Liu J W,Zhang K,Chen Z Y,et al.A porous and stable porphyrin metal-organic framework as an efficient catalyst towards visible-light-mediated aerobic cross-dehydrogenative-coupling reactions[J].Chem Asian J,2020,15(7):1118-1124.
[26] Rui K,Zhao G Q,Chen Y P,et al.Hybrid 2D dual-metal-organic frameworks for enhanced water oxidation catalysis[J].Adv Funct Mater,2018,28(26):1801554.
[27] Qian Q Z,Li Y P,Liu Y,et al.Ambient fast synthesis and active sites deciphering of hierarchical foam-like trimetal-organic framework nanostructures as a platform for highly efficient oxygen evolution electrocatalysis[J].Adv Mater,2019,31(23):1901139.
[28] Huang Z Q,Wang B,Pan D S,et al.Rational design of a N,S Co-doped supermicroporous CoFe-organic framework platform for water oxidation[J].Chem Sus Chem,2020,13(10):2564-2570.
[29] Wei Y S,Sun L,Wang M,et al.Fabricating dual-atom iron catalysts for efficient oxygen evolution reaction:a heteroatom modulator approach[J].Angew Chem Int Ed,2020,59(37):16013-16022.
[30] Micheroni D,Lan G X,Lin W B.Efficient electrocatalytic proton reduction with carbon nanotube-supported metal-organic frameworks[J].J Am Chem Soc,2018,140(46):15591-15595.
[31] Lin Z Y,Yang Y,Li M S,et al.Dual graphitic-n doping in a six-membered C-ring of graphene-analogous particles enables an efficient electrocatalyst for the hydrogen evolution reaction[J].Angew Chem Int Ed,2019,58(47):16973-16980.
[32] Dou S,Song J J,Xi S B,et al.Boosting Electrochemical CO2 reduction on metal-organic frameworks via ligand doping[J].Angew Chem Int Ed,2019,58(12):4041-4045.
[33] Yi J D,Xie R K,Xie Z L,et al.Highly selective CO2electroreduction to CH4 by insitu generated Cu2O single-type sites on a conductive MOF:stabilizing key intermediates with hydrogen bonding[J].Angew Chem Int Ed,2020,59(52):23641-23648.
[34] Yi J D,Si D H,Xie R K,et al.Conductive two-dimensional phthalocyanine-based metal-organic framework nanosheets for efficient electroreduction of CO2[J].Angew Chem Int Ed,2021,60(31):17108-17114.
[35] Zhao R,Liang Z B,Gao S,et al.Puffing up energetic metal-organic frameworks to large carbon networks with hierarchical porosity and atomically dispersed metal sites[J].Angew Chem Int Ed,2019,58(7):1975-1979.
[36] Chen S S,Song Z X,Lyu J H,et al.Anhydride post-synthetic modification in a hierarchical metal-organic framework[J].J Am Chem Soc,2020,142(9):4419-4428.
基金资助
国家自然科学基金(21801158);青岛市博士后应用研究项目(2020036);青岛理工大学环境科学与工程一流学科开放课题(QUTSEME201934);青岛大学省部共建生物多糖纤维成形与生态纺织国家重点实验室开放课题面上项目(KF2020201)
PDF
