碳纤维与碳纳米管形成的多尺度复合增强体不仅有助于复合材料界面结合有效传递载荷,同时有益于性能及寿命的提高。从物理和化学两个方面,综述了化学气相沉积、化学接枝、电泳沉积、表面涂层、浸渍法这5种主要的碳纤维与碳纳米管界面结合方法、重要因素及优缺点,同时对其性能的提高进行了总结与展望。指出了限制其规模化应用的原因,阐述了探索简单、可控、有效、规模化的新型碳纤维与碳纳米管的结合方法将是实现碳纤维复合材料的性能定制化研究的未来方向。
The multi-scale composite enhancer formed by carbon fiber and carbon nanotubes not only helps to transfer the effective load at the composite interface,but also improves the performance and life span.This paper,from physical and chemical aspects,reviewed chemical vapor deposition,chemical grafting,electrophoresis deposition,surface coating and immersion method,as well as important factors and disadvantages of the interface of carbon fiber and carbon nanotube.It also summarized the performance and pointed out the reasons limiting its scale application.The exploration of new simple,controllable,effective scale binding method of carbon fiber with carbon nanotubes contributed to realize composite performance customization,which should be the future research direction.
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基金资助
山东省泰山学者项目(ts20190937)
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