化工新型材料

化工新型材料 ›› 2022, Vol. 50 ›› Issue (10) : 173-178. DOI: 10.19817/j.cnki.issn1006-3536.2022.10.033

科学研究

Na₂SO₄改性Co₃O₄催化NaBH₄-NH₃BH₃复合物水解放氢性能研究

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Study on the catalytic performance of Na₂SO₄ modified Co₃O₄ for hydrogen release from NaBH₄-NH₃BH₃ composite hydrolysis

Liu Yonghui¹, Zhang Lidan¹, Yang Mao¹, Deng Zimeng¹, Wu Yucheng¹, Wu Chaoling², Wang Xiaolian¹

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Received		Published
2021-06-07		2022-10-20
Issue Date	Revised Date
2022-11-01	2021-06-07

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摘要

NaBH₄-NH₃BH₃复合物(xSB-AB,x=2,4,6,8)具有比单体更好的水解放氢性能,但在温和条件下的产氢效率仍然不够理想。将Na₂SO₄改性的Co₃O₄用于催化NaBH₄-NH₃BH₃复合物水解,发现它表现出比纯Co₃O₄更为优异的催化性能。Na₂SO₄改性的Co₃O₄催化2NaBH₄-NH₃BH₃在40℃水解时,8min的产氢量达到了2430mL/g。结果表明:Na₂SO₄本身对NaBH₄-NH₃BH₃复合物水解无催化作用,但可能有利于Co₃O₄原位转化为具有高催化活性的Co-B合金,从而提升NaBH₄-NH₃BH₃复合物的放氢性能。

Abstract

NaBH₄-NH₃BH₃ composite (xSB-AB,x=2,4,6,8) has better hydrolysis performance than its monomer,but the hydrogen production efficiency under mild conditions is still not ideal.Co₃O₄ modified by Na₂SO₄ was used to catalyze the hydrolysis of NaBH₄-NH₃BH₃ composite.It was found that it exhibited better catalytic performance than pure Co₃O₄.Typically,the hydrogen yield of 2NaBH₄-NH₃BH₃ catalyzed by Na₂SO₄ modified Co₃O₄ at 40℃ for 8 min can reach 2430mL/g.Our analysis shown that Na₂SO₄ had no catalytic effect on the hydrolysis of NaBH₄-NH₃BH₃ composite,but it may facilitate the in-situ conversion of Co₃O₄ to Co-B alloy with high catalytic activity,thereby improving the hydrogen release performance of NaBH₄-NH₃BH₃ composite.

关键词

NaBH₄-NH₃BH₃ / Na₂SO₄ / Co₃O₄ / 水解

Key words

NaBH₄-NH₃BH₃ / Na₂SO₄ / Co₃O₄ / hydrolysis

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Na₂SO₄改性Co₃O₄催化NaBH₄-NH₃BH₃复合物水解放氢性能研究[J]. 化工新型材料, 2022, 50(10): 173-178 DOI:10.19817/j.cnki.issn1006-3536.2022.10.033

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参考文献

原文顺序 | 出版日期 | 本文引用

[1] Huang X,Liu Y,Wen H,et al.Ensemble-boosting effect of Ru-Cu alloy on catalytic activity towards hydrogen evolution in ammonia borane hydrolysis[J].Applied Catalysis B:Environmental,2021,287:119960.
[2] 冯钊,吴朝玲,钟爽,等.廉价75#硅铁合金水解制氢剂的制备及性能[J].功能材料,2020,51(9):78-83.
[3] Chu H,Li N,Qiu X,et al.Poly(N-vinyl-2-pyrrolidone)-stabilized ruthenium supported on bamboo leaf-derived porous carbon for NH₃BH₃ hydrolysis[J].International Journal of Hydrogen Energy,2019,44:29255-29262.
[4] Liu Y,Guo H,Sun K,et al.Magnetic CoO_x@C-reduced graphene oxide composite with catalytic activity towards hydrogen generation[J].International Journal of Hydrogen Energy,2019,44:28163-28172.
[5] Yüksel Alpaydin C,Gülbay S K,Ozgur Colpan C.A review on the catalysts used for hydrogen production from ammonia borane[J].International Journal of Hydrogen Energy,2020,45(5):3414-3434.
[6] Soltani M,Zabihi M.Hydrogen generation by catalytic hydrolysis of sodium borohydride using the nano-bimetallic catalysts supported on the core-shell magnetic nanocomposite of activated carbon[J].International Journal of Hydrogen Energy,2020,45(22):12331-12346.
[7] Yang J,Yuan Q,Liu Y,et al.Low-cost ternary Ni-Fe-P catalysts supported on Ni foam for hydrolysis of ammonia borane[J].Inorganic Chemistry Frontiers,2019,6:1189-1194.
[8] Zhou S,Yang Y,Zhang W,et al.Structure-regulated Ru particles decorated P-vacancy-rich CoP as a highly active and durable catalyst for NaBH₄ hydrolysis[J].Journal of Colloid and Interface Science,2021,591:221-228.
[9] Chen W,Ji J,Duan X,et al.Unique reactivity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane[J].Chemical Communications,2014,50(17):2142-2144.
[10] Xu D,Wang W,Tian M,et al.Immobilization of Pt nanoparticles in hollow mesoporous silica nanocapsules:an aggregation- and leaching-resistant catalyst[J].Journal of Colloid and Interface Science,2018,516:407-415.
[11] Fang Y,Li J,Togo T,et al.Ultra-small face-centered-cubic Ru nanoparticles confined within a porous coordination cage for dehydrogenation[J].Chem,2018,4:555-563.
[12] Hu M,Wang H,Wang Y,et al.Alumina nanofiber-stabilized ruthenium nanoparticles:highly efficient catalytic materials for hydrogen evolution from ammonia borane hydrolysis[J].International Journal of Hydrogen Energy,2017,42(38):24142-24149.
[13] Chu H,Li N,Qiu S,et al.Ruthenium supported on nitrogen-doped porous carbon for catalytic hydrogen generation from NH₃BH₃ hydrolysis[J].International Journal of Hydrogen Energy,2019,44:1774-1781.
[14] Lu Z,Jiang H,Yadav M,et al.Synergistic catalysis of Au-Co@SiO₂ nanospheres in hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage[J].Journal of Materials Chemistry,2012,22(11)5065.
[15] Zhang X,Zhang Q,Xu B,et al.Efficient hydrogen generation from the NaBH₄ hydrolysis by cobalt-based catalysts:positive roles of sulfur-containing salts[J].ACS Applied Materials & Interfaces,2020,12:9376-9386.
[16] Feng X,Chen X,Qiu P,et al.Copper oxide hollow spheres:synthesis and catalytic application in hydrolytic dehydrogenation of ammonia borane[J].International Journal of Hydrogen Energy,2018,43(45):20875-20881.
[17] Amoo K O,Onyeozili E N,Kalu E E,et al.Activity of varying compositions of Co-Ni-P catalysts for the methanolysis of ammonia borane[J].International Journal of Hydrogen Energy,2016,41:21221-21235.
[18] Bozkurt G,özer A,Yurtcan A B.Hydrogen generation from sodium borohydride with Ni and Co based catalysts supported on Co₃O₄[J].International Journal of Hydrogen Energy,2018,43(49):22205-22214.
[19] Yuan H,Huo W,Hao Y,et al.Hydrogen generation from hydrolysis of sodium borohydride using nanosized NiB amorphous alloy catalysts[J].Nano,2020,15(6):16077.
[20] Simagina V I,Komova O V,Ozerova A M,et al.Cobalt oxide catalyst for hydrolysis of sodium borohydride and ammonia borane[J].Applied Catalysis A:General,2011,394:86-92.
[21] Damjanović L,Majchrzak M,Bennici S,et al.Determination of the heat evolved during sodium borohydride hydrolysis catalyzed by Co₃O₄[J].International Journal of Hydrogen Energy,2011,36(3):1991-1997.
[22] Lu D,Liao J,Li H,et al.Co₃O₄/CuMoO₄ hybrid microflowers composed of nanorods with rich particle boundaries as a highly active catalyst for ammonia borane hydrolysis[J].ACS Sustainable Chemistry & Engineering,2019,7:16474-16482.
[23] Netskina O V,Kochubey D I,Prosvirin I P,et al.Cobalt-boron catalyst for NaBH₄ hydrolysis:the state of the active component forming from cobalt chloride in a reaction medium[J].Molecular Catalysis,2017,441:100-108.
[24] Xu J,Du X,Wei Q,et al.Efficient hydrolysis of sodium borohydride by Co-B supported on nitrogen-doped carbon[J].Chemistry Select,2020,5:6683-6690.
[25] Patel N,Fernandes R,Gupta S,et al.Co-B catalyst supported over mesoporous silica for hydrogen production by catalytic hydrolysis of ammonia borane:a study on influence of pore structure[J].Applied Catalysis B:Environmental,2013,140-141:125-132.
[26] İzgi M S,Şahinö,Saka C.Hydrogen production from NaBH₄ using Co-Cu-B catalysts prepared in methanol:effect of plasma treatment[J].International Journal of Hydrogen Energy,2016,41(3):1600-1608.
[27] Liao J,Lv F,Feng Y,et al.Electromagnetic-field-assisted synthesis of Ni foam film-supported CoCu alloy microspheres composed of nanosheets:a high performance catalyst for the hydrolysis of ammonia borane[J].Catalysis Communications,2019,122:16-19.
[28] Chen B,Chen S,Bandal H A,et al.Cobalt nanoparticles supported on magnetic core-shell structured carbon as a highly efficient catalyst for hydrogen generation from NaBH₄ hydrolysis[J].International Journal of Hydrogen Energy,2018,43:9296-9306.
[29] Sahiner N,Ozay O,Inger E,et al.Superabsorbent hydrogels for cobalt nanoparticle synthesis and hydrogen production from hydrolysis of sodium boron hydride[J].Applied Catalysis B:Environmental,2011,102(1-2):201-206.
[30] Wei L,Cao X,Ma M,et al.Co₃O₄ nanowires as efficient catalyst precursor for hydrogen generation from sodium borohydride hydrolysis[J].Functional Materials Letters,2018,11:1850018.
[31] Wei L,Dong X,Ma M,et al.Co₃O₄ hollow fiber:an efficient catalyst precursor for hydrolysis of sodium borohydride to generate hydrogen[J].International Journal of Hydrogen Energy,2018,43(3):1529-1533.
[32] Huang Z,Wu C,Chen Y,et al.The catalyst-free hydrolysis behaviors of NaBH₄-NH₃BH₃ composites[J].International Journal of Hydrogen Energy,2012,37(6):5137-5142.
[33] Xu Y,Chen J,Wu C,et al.Hydrogen generation from hydrolysis of NaBH₄-NH₃BH₃ composite promoted by AlCl₃[J].International Journal of Hydrogen Energy,2016,41:16344-16351.
[34] 吴海文,吴朝玲,陈云贵,等.LaH₃稀土催化及球磨时间对Mg₁₇Al₁₂氢化物水解性能的影响[J].功能材料,2011,42(增刊V):977-980.
[35] Xu Y,Wu C,Chen Y,et al.Hydrogen generation behaviors of NaBH₄-NH₃BH₃ composite by hydrolysis[J].Journal of Power Sources,2014,261:7-13.