先后采用等离子体和丙烯酸(AA)蒸汽处理碳纤维织物(CF)得到表面含有活性基团的活性碳纤维织物(ACF),分别将聚吡咯(PPy)聚合沉积在CF和ACF表面上制备了复合电极,采用扫描电子显微镜(SEM)、傅里叶变换红外光谱仪(FT-IR)、X射线光电子能谱仪(XPS)、紫外分光光度仪(UV)以及电化学工作站对复合电极的表面形貌、PPy分子构象以及所组成的超级电容器的电化学性能进行测试研究。结果表明:沉积在ACF表面上的PPy具有更为松散的形貌和更为优异的导电性,PPy与ACF之间结合力更强,由ACF/PPy为电极组成的超级电容器的电化学性能得到明显改善。有望为制备PPy复合电极提供新的思路和方向。
Carbon fiber fabric (CF) was treated with plasma and acrylic acid (AA) steam to obtain activated carbon fiber fabric (ACF) with active groups on the surface.Polypyrrole (PPy) was polymerized and deposited on the surface of CF and ACF respectively to prepare composite electrodes.Scanning electron microscopy (SEM),fourier transform infrared spectroscopy (FT-IR),X-ray photoelectron spectroscopy (XPS),ultraviolet spectrophotometer (UV) and electrochemical workstation were used to study the surface morphology,PPy molecular conformation and electrochemical performance of the composite electrode.The results shown that the PPy deposited on the ACF surface had more loose morphology and better conductivity,and the binding force between PPy and ACF was stronger.The electrochemical performance of the supercapacitor composed of ACF/PPy electrode was obviously improved.To provide new idea and direction for the preparation of PPy composite electrode was expected.
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基金资助
安徽工程大学科研启动基金资助项目(2020YQQ023和2020YQQ024);安徽工程大学校级科研项目(Xjky2020042和Xjky2020044);安徽省纺织结构复合材料国际联合研究中心开放基金(2021ACTC08);安徽工程大学本科生科研项目(2021ffky02和2021ffky03)
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