基于含7-氧杂降冰片烯并降莰烷二胺的疏水性聚酰亚胺薄膜的合成与研究

熊磊1,2, 陈笑天1, 黄景1, 吴美林1, 刘峰2, 李亮荣3*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (10) : 102 -105.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (10) : 102-105. DOI: 10.19817/j.cnki.issn1006-3536.2022.10.020
新材料与新技术

基于含7-氧杂降冰片烯并降莰烷二胺的疏水性聚酰亚胺薄膜的合成与研究

    熊磊1,2, 陈笑天1, 黄景1, 吴美林1, 刘峰2, 李亮荣3*
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Synthesis and research of hydrophobic PI film derived from diamine with 7-oxonorbornene fused norcamphane

  • Xiong Lei1,2, Chen Xiaotian1, Huang Jing1, Wu Meilin1, Liu Feng2, Li Liangrong3
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摘要

以降冰片烯单酐、呋喃、对氯硝基苯为起始原料,通过D-A反应、LiAlH4还原、亲核取代和硝基还原四步法合成了一种新型含7-氧杂降冰片烯并降莰烷大体积结构的二胺单体,并通过该二胺与联苯四酸二酐(BPDA)缩聚制备了一种新型脂环族聚酰亚胺薄膜。结果表明,该聚酰亚胺材料具有良好的溶解性与疏水性。

Abstract

A new diamine containing 7-oxonorbornene fused norcamphane was synthesized by the way of D-A reaction,carbonyl reduction,nucleophilic substitution reaction and nitryl reduction,starting with nadic anhydrous,furan and 1-chloro-4-nitrobenzene as raw materials.It was demonstrated that the novel polyimide film(PI) which was prepared by the novel diamine and biphenyl tetracarboxylic dianhydride was soluble and hydrophobic.

关键词

聚酰亚胺 / 二胺 / 7-氧杂降冰片烯降莰烷 / 合成 / 疏水性

Key words

polyimide / diamine / 7-oxonorbornene fused norcamphane / synthesis / hydrophobicity

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基于含7-氧杂降冰片烯并降莰烷二胺的疏水性聚酰亚胺薄膜的合成与研究[J]. 化工新型材料, 2022, 50(10): 102-105 DOI:10.19817/j.cnki.issn1006-3536.2022.10.020

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参考文献

[1] Zhang H,Li J,Tian Z,et al.Synthesis and properties of novel alicyclic-functionalized polyimides prepared from natural-(D)-camphor[J].J Appl Polym Sci,2013,129(6):3333-3340.
[2] Zhai L,Yang S,Fan L.Preparation and characterization of highly transparent and colorless semi-aromatic polyimide films derived from alicyclic dianhydride and aromatic diamines[J].Polymer,2012,53(16):3529-3539.
[3] Wang Z H,Fang G Q,He J J,et al.Semi-aromatic thermosetting polyimide resins containing alicyclic units for achieving low melt viscosity and low dielectric constant[J].React Funct Polym,2020,146:104411.
[4] Park C Y,Kim E H,Kim J H,et al.Novel semi-alicyclic polyimide membranes:synthesis,characterization,and gas separation properties[J].Polymer,2018,151(29):325-333.
[5] 姜岗岚,吴琳,杨洋,等.半脂环型无色透明聚酰亚胺薄膜的低热膨胀化研究进展[J].化工新型材料,2021,49(7):1-5.
[6] Zhuang Y,Seong J G,Lee Y M.Polyimides containing aliphatic/alicyclic segments in the main chains[J].Prog Polym Sci,2019,92:35-88.
[7] Xiong L,Wang X,Qi H,et al.Synthesis of a new siloxane-containing alicyclic dianhydride and the derived polyimides with improved solubility and hydrophobicity[J].J Appl Polym Sci,2013,127(3):1493-1501.
[8] 熊磊,陈时建,郭建业,等.含氧杂环/环己基大体积结构二元酸酐的合成与研究[J].化工新型材料,2018,46(12):112-114.

基金资助

江西省教育厅科学技术研究项目(GJJ209803)

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