有机小分子石墨烯(RGO)异质结是极具潜能的功能化材料,在具备石墨烯高比表面积特征的同时,良好的物理化学性能也得到了针对性的优化,从而在更多领域得以应用,因此有机小分子石墨烯异质结备受关注。综述了3种有机小分子石墨烯异质结的制备方法,包括羧基化石墨烯(G-COOH,CG)、磷酸化石墨烯(PG)及磺酸化石墨烯(G-SO3H,SG)。简要介绍了有机小分子石墨烯异质结材料在吸附、催化、防腐涂层、燃料电池等领域的应用近况,对有机小分子石墨烯异质结的发展方向进行了展望。
Organic small molecule graphene(RGO) heterojunctions are extremely potential functional materials that possess the characteristics of high specific surface area of RGO,and at the same time,good physical and chemical properties of RGO have been optimized in a targeted manner,so that these materials can be applied in more fields.Therefore,Organic small molecule RGO heterojunctions have attracted much attention.The preparation methods of three kinds of organic small molecule RGO heterojunctions were reviewed,including carboxylated graphene (G-COOH,CG),phosphorylated graphene (PG) and sulfonated graphene (G-SO3H,SG).The recent applications of these materials in adsorption,catalysis,anticorrosive coating and fuel cell were introduced briefly.Finally,the development direction of organic small molecule graphene heterojunctions was prospected.
[1] Singh V,Joung D,Zhai L,et al.Graphene based materials:past,present and future[J].Progress in Materials Science,2011,56(8):1178-1271.
[2] 郭敏.电子在金属-石墨烯异质结结构上的传输[D].太原:山西大学,2020.
[3] 朱景春.超声法合成纳米材料的原理及应用进展[J].科学技术创新,2018,(7):188-189.
[4] 吕莎莎,危晶,江峰,等.羧基化石墨烯对4种离子型染料的吸附脱色[J].应用化学,2013,30(10):1215-1221.
[5] Li Y S,Li J H,Li Y H,et al.Ultrasonic-assisted preparation of graphene oxide carboxylic acid polyvinyl alcohol polymer film and studies of thermal stability and surface resistivity[J].Ultrason Sonochem,2018,40:798-807.
[6] 赖双权,金勇,石亮杰,等.羧基化氧化石墨烯在聚丙烯酸酯皮革涂饰剂改性中的应用[J].皮革科学与工程,2017,27(5):17-23,53.
[7] Han G J,Liu S Y,Pan Z C,et al.Sulfonated chitosan and phosphorylated chitosan coated polylactide membrane by polydopamine-assisting for the growth and osteogenic differentiation of MC3T3-E1s[J].Carbohydrate Polymers,2020,229:115517.
[8] Li L,Ma R,Wen T,et al.Functionalization of carbon nanomaterials by means of phytic acid for uranium enrichment[J].Science of the Total Environment,2019,694:133697.
[9] Lian Q Y,Yao L G,Ahmad Z U,et al.Enhanced Pb(Ⅱ) adsorption onto functionalized ordered mesoporous carbon (OMC) from aqueous solutions:the important role of surface property and adsorption mechanism[J].Environmental Science and Pollution Research,2020,27(19):23616-23630.
[10] Wang W,Wang X,Pan Y.Synthesis of phosphorylated graphene oxides based multilayer coating:self-assembly method and application for improving the fire safety of cotton fabrics[J].Industrial & Engineering Chemistry Research,2017,56(23):6664-6670.
[11] 张志宾,张昊岩,邱燕芳,等.磷酸化石墨烯吸附铀的性能研究[J].中国科学:化学,2019,49(1):195-206.
[12] Goods J B,Sydlik S A,Walish J J,et al.Phosphate functionalized graphene with tunable mechanical properties[J].Advanced Materials,2014,26(5):718-723.
[13] Liu X,Li J X,Wang X X,et al.High performance of phosphate-functionalized graphene oxide for the selective adsorption of U(Ⅵ) from acidic solution[J].Journal of Nuclear Materials,2015,466:56-64.
[14] Li H,Yuan J J,Zha L,et al.Soft conducting polymer hydrogels in situ doped by sulfonated graphene quantum dots for enhanced electrochemical activity[J].Journal of Materials Science:Materials in Electronics,2019,31(3):2153-2161.
[15] Kang Y,Obaid M,Jang J,et al.Sulfonated graphene oxide incorporated thin film nanocomposite nanofiltration membrane to enhance permeation and antifouling properties[J].Desalination,2019,470:114125.
[16] Upare P P,Hong D Y,Kwak J,et al.Direct chemical conversion of xylan into furfural over sulfonated graphene oxide[J].Catalysis Today,2019,324:66-72.
[17] Saraswathi M S S A,Rana D,Kaleekkal N J,et al.Investigating the efficacy of PVDF membranes customized with sulfonated graphene oxide nanosheets for enhanced permeability and antifouling[J].Journal of Environmental Chemical Engineering,2020,8(5):104426.
[18] Wei H M,Yang J,Liu W,et al.Effects of sulfonated graphene on lead sulfate negative electrode of Pb-C batteries[J].The Journal of Energy Storage,2021,34:102174.
[19] 张海静,周庆琼,林子豪,等.磺化还原氧化石墨烯的制备及其对碱性染料的吸附研究[J].现代食品科技,2019,35(7):145-151.
[20] He L,Wang L,Zhu H M,et al.A reusable Fe3O4/GO-COOH nanoadsorbent for Ca2+ and Cu2+ removal from oilfield wastewater[J].Chemical Engineering Research and Design,2021,166.
[21] Dutta R K,Shaida M A,Singla K,et al.Highly efficient adsorptive removal of uranyl ions by a novel graphene oxide reduced by adenosine 5'-monophosphate (RGO-AMP)[J].Journal of Materials Chemistry A,2019,7(2):664-678.
[22] Pourbeyram S.Effective removal of heavy metals from aqueous solutions by graphene oxide-zirconium phosphate (GO-Zr-P) nanocomposite[J].Industrial & Engineering Chemistry Research,2016,55(19):5608-5617.
[23] Song Y F,Sun Y K,Chen M Z,et al.Efficient removal and fouling-resistant of anionic dyes by nanofiltration membrane with phosphorylated chitosan modified graphene oxide nanosheets incorporated selective layer[J].Journal of Water Process Engineering,2020,34:101086.
[24] Wei M P,Chai H,Cao Y L,et al.Sulfonated graphene oxide as an adsorbent for removal of Pb2+ and methylene blue[J].Journal of Colloid and Interface Science,2018,524:297-305.
[25] Gu B E,Huang C Y,Shen T H,et al.Effects of multiwall carbon nanotube addition on the corrosion resistance and underwater acoustic absorption properties of polyurethane coatings[J].Progress in Organic Coatings,2018,121:226-235.
[26] El-Faham A,Atta A M,Osman S M,et al.Silver-embedded epoxy nanocomposites as organic coatings for steel[J].Progress in Organic Coatings,2018,123:209-222.
[27] Xie Yuhui,Chen Mingzhi,Xie Delong,et al.A fast,low temperature zinc phosphate coating on steel accelerated by graphene oxide[J].Corrosion Science,2017,128:1-8.
[28] Li J Y,Li X R,Zhu K,et al.Reinforcement of phosphorylated graphene oxide on the anticorrosive properties of waterborne acrylate-epoxy resin coatings[J].Journal of Macromolecular Science,Part A,2018,55(9):649-657.
[29] Wu Y T,Wen S G,Chen K M,et al.Enhanced corrosion resistance of waterborne polyurethane containing sulfonated graphene/zinc phosphate composites[J].Progress in Organic Coatings,2019,132:409-416.
[30] González I,Mestach D,Leiza J R,et al.Adhesion enhancement in waterborne acrylic latex binders synthesized with phosphate methacrylate monomers[J].Progress in Organic Coatings,2008,61(1):38-44.
[31] Li Z W,Li J,Cui J C,et al.Dispersion and parallel assembly of sulfonated graphene in waterborne epoxy anticorrosion coatings[J].Journal of Materials Chemistry A,2019,7(30):17937-17946.
[32] Gaidukevič J,Barkauskas J,Malaika A,et al.Modified graphene-based materials as effective catalysts for transesterification of rapeseed oil to biodiesel fuel[J].Chinese Journal of Catalysis,2018,39:1633-1645.
[33] Gao P,Ng K,Sun D D.Sulfonated graphene oxide-ZnO-Ag photocatalyst for fast photodegradation and disinfection under visible light[J].Journal of Hazardous Materials,2013,262:826-835.
[34] Alamelu K,Jaffar Ali B M.Ag nanoparticle-impregnated sulfonated graphene/TiO2 composite for the photocatalytic removal of organic pollutants[J].Applied Surface Science,2020,512:145629.
[35] Wu X H,Chen F Y,Wang X F,et al.In situ one-step hydrothermal synthesis of oxygen-containing groups-modified g-C3N4 for the improved photocatalytic H2-evolution performance[J].Applied Surface Science,2018,427:645-653.
[36] Liu Y X,Yang D Z,Shi Y Z,et al.Silver phosphate/graphene oxide aerogel microspheres with radially oriented microchannels for highly efficient and continuous removal of pollutants from wastewaters[J].ACS Sustainable Chemistry & Engineering,2019,7(13):11228-11240.
[37] 王苹,李海涛,曹艳洁,等.羧基功能化石墨烯增强TiO2光催化产氢性能(英文)[J].物理化学学报,2021,37(6):127-135.
[38] Pramanik M,Li C L,Kaneti Y V,et al.A mesoporous tin phosphate-graphene oxide hybrid toward the oxygen reduction reaction[J].Chem Commun(Camb),2017,53(42):5721-5724.
[39] Begum H,Ahmed M S,Jeon S.δ-MnO2 nanoflowers on sulfonated graphene sheets for stable oxygen reduction and hydrogen evolution reaction[J].Electrochimica Acta,2019,296:235-242.
[40] Wang L W,Wu S G,Shi T Y,et al.Electrocatalytic oxidation of calcium folinate on carboxyl graphene modified CuxO/Cu electrode[J].Chinese Journal of Chemical Physics,2016,29(6):729-734.
[41] Peressut B A,Latorrata S,Stampino P G,et al.Development of self-assembling sulfonated graphene oxide membranes as a potential proton conductor[J].Materials Chemistry and Physics,2021,257:123768.
[42] Ahmed S,Cai Y B,Ali M,et al.One-step phosphorylation of graphene oxide for the fabrication of nanocomposite membranes with enhanced proton conductivity for fuel cell applications[J].Journal of Materials Science:Materials in Electronics,2019,30(14):13056-13066.
[43] Shukla G,Pandey R P,Shahi V K.Temperature resistant phosphorylated graphene oxide-sulphonated polyimide composite cation exchange membrane for water desalination with improved performance[J].Journal of Membrane Science,2016,520:972-982.
[44] Aziz M A,Shanmugam S.Sulfonated graphene oxide-decorated block copolymer as a proton-exchange membrane:improving the ion selectivity for all-vanadium redox flow batteries[J].Journal of Materials Chemistry A,2018,6(36):17740-17750.
[45] Ahmed S,Cai Y,Ali M,et al.One-step phosphorylation of graphene oxide for the fabrication of nanocomposite membranes with enhanced proton conductivity for fuel cell applications[J].Journal of Materials Science:Materials in Electronics,2019,30(14):13056-13066.
基金资助
江苏省基础研究计划(自然科学基金)青年基金项目(BK20160359);浙江省公益技术研究计划项目(LGF19B070008);江苏省研究生实践创新计划(SJCX20-1123)
PDF
