近年来,生物智能传感技术的发展和应用已经渗透到我们的生活中。但是,低机械性能,不灵活的信号传输和不灵敏的信号输出限制了它们作为传感器的发展。为了应对这些挑战,MXene由于其高电子迁移率和纳米片间能量存储的特性而被引入聚合物水凝胶中。同时,它还赋予水凝胶优异的力学性能,从而受到人们越来越多的关注。综述了基于MXene聚合物复合水凝胶的种类及其在传感器、超级电容器、抗菌敷料等方面的应用。
In recent years,the development and application of biological intelligent sensing technology have penetrated into our lives.However,low mechanical properties,nonflexible signal transmission,and insensitive signal output have restricted their development as sensors.To address these challenges,MXene has been introducing into polymer hydrogels due to its unique characteristics of high electron mobility and energy storage between sheets.Meanwhile,it also endows hydrogels with excellent mechanics properties,which has attracted more and more attention.The types of MXene based polymer composite hydrogels and their applications in sensors,supercapacitors and antibacterial dressing were reviewed.
[1] Nele V,Wojciechowski J P,Armstrong J P K,et al.Tailoring gelation mechanisms for advanced hydrogel applications[J].Advanced Functional Materials,2020,30:2002759.
[2] Liu X,Liu J,Lin S,et al.Hydrogel machines[J].Mater Today,2020,36:102-124.
[3] 许孟杰,陈华泉,周雪松.纤维素/海藻酸钠基双膜水凝胶的制备及其药物控释研究[J].应用化工,2019,48(9):2156-2161.
[4] Tong C,Wondergem J A J,Heinrich D,et al.Photopatternable,branched polymer hydrogels based on linear macromonomers for 3D cell culture applications[J].ACS Macro Letters,2020,9:882-888.
[5] Yin B S,Zhang S W,Ren Q Q,et al.Elastic soft hydrogel supercapacitor for energy storage[J].Journal of Materials Chemistry A,2017,5:24942-24950.
[6] Hu Y,Zhang M,Qin C,et al.Transparent,conductive cellulose hydrogel for flexible sensor and triboelectric nanogenerator at subzero temperature[J].Carbohydrate Polymers,2021,265:118078.
[7] 盛卉,薛斌,秦猛,等.可拉伸超韧水凝胶的制备和应用[J].高等学校化学学报,2020,41(6):1194-1207.
[8] 朱韵伊,彭伟,林泽慧,等.MXene基水凝胶复合材料的研究进展[J].复合材料学报,2021,38(7):2010-2024.
[9] 程培栋,陈卫华,艾云龙,等.新型二维层状材料MXene在超级电容器上的研究与应用进展[J].功能材料,2021,52(1):1091-1103.
[10] Riazi H,Nemani S K,Grady M C,et al.Ti3C2 MXene-polymer nanocomposites and their applications[J].Journal of Materials Chemistry A,2021,9:8051-8098.
[11] Zhang Y Z,El-Demellawi J K,Jiang Q,et al.MXene hydrogels:fundamentals and applications[J].Chemical Society Reviews,2020,49:7229-7251.
[12] 杨晨曦,王健,卢垟杰,等.新型二维材料MXenes的合成及其应用研究进展[J].化工新型材料,2021,49(7):52-55.
[13] 赵瑞正.MXene基复合材料的可控制备及其电化学储能研究[D].济南:山东大学,2020.
[14] Wang Q,Pan X,Wang X,et al.Fabrication strategies and application fields of novel 2D Ti3C2Tx (MXene) composite hydrogels:a mini-review[J].Ceramics International,2021,47:4398-4403.
[15] 王思恒,杨欣欣,刘鹤,等.导电水凝胶的制备及应用研究进展[J].化工进展,2021,40(5):1-22.
[16] Li X,He L,Li Y,et al.Healable,degradable,and conductive MXene nanocomposite hydrogel for multifunctional epidermal sensors[J].ACS Nano,2021,15:7765-7773.
[17] Wu K,Han H,Xu L,et al.The improvement of freezing-thawing resistance of concrete by cellulose/polyvinyl alcohol hydrogel[J].Construction and Building Materials,2021,291:123274.
[18] Zhang J,Wan L,Gao Y,et al.Highly stretchable and self-healable MXene/polyvinyl alcohol hydrogel electrode for wearable capacitive electronic skin[J].Advanced Electronic Materials,2019,5:1900285.
[19] Zhang Y Z,Lee K H,Anjum D H,et al.MXenes stretch hydrogel sensor performance to new limits[J].Science Advances,2018,4:eaat0098.
[20] Ai J,Li J,Li K,et al.Highly flexible,self-healable and conductive poly(vinyl alcohol)/Ti3C2Tx MXene film and it's application in capacitive deionization[J].Chemical Engineering Journal,2021,408:127256.
[21] Ge G,Zhang Y Z,Zhang W,et al.Ti3C2Tx MXene-activated fast gelation of stretchable and self-healing hydrogels:a molecular approach[J].ACS Nano,2021,15:2698-2706.
[22] Wang Q,Pan X,Lin C,et al.Modified Ti3C2Tx (MXene) nanosheet-catalyzed self-assembled,anti-aggregated,ultra-stretchable,conductive hydrogels for wearable bioelectronics[J].Chemical Engineering Journal,2020,401:126-129.
[23] Zhang Y,Chen K,Li Y,et al.High-strength,self-healable,temperature-sensitive,MXene-containing composite hydrogel as a smart compression sensor[J].ACS Applied Materials & Interfaces,2019,11:47350-47357.
[24] Zhang P,Yang X J,Li P,et al.Fabrication of novel MXene (Ti3C2)/polyacrylamide nanocomposite hydrogels with enhanced mechanical and drug release properties[J].Soft Matter,2020,16:162-169.
[25] Guo J,Yu Y,Zhang D,et al.Morphological hydrogel microfibers with MXene encapsulation for electronic skin[J].Research,2021,2021:7065907.
[26] Pi M,Jiang L,Wang Z,et al.Robust and ultrasensitive hydrogel sensors enhanced by MXene/cellulose nanocrystals[J].Journal of Materials Science,2021,56:8871-8886.
[27] Liao H,Guo X,Wan P,et al.Conductive MXene nanocomposite organohydrogel for flexible,healable,low-temperature tolerant strain sensors[J].Advanced Functional Materials,2019,29:1904507.
[28] Wei Y,Xiang L,Ou H,et al.MXene-based conductive organohydrogels with long-term environmental stability and multifunctionality[J].Advanced Functional Materials,2020,30:2005135.
[29] Ling Z,Ren C E,Zhao M Q,et al.Flexible and conductive MXene films and nanocomposites with high capacitance[J].PNAS,2014,111(47):16676-16681.
[30] Zhou B,Zhang Z,Li Y,et al.Flexible,robust,and multifunctional electromagnetic interference shielding film with alternating cellulose nanofiber and MXene layers[J].ACS Applied Materials & Interfaces,2020,12:4895-4905.
[31] Mao L,Hu S,Gao Y,et al.Biodegradable and electroactive regenerated bacterial cellulose/MXene (Ti3C2Tx) composite hydrogel as wound dressing for accelerating skin wound healing under electrical stimulation[J].Advanced Healthcare Materials,2020,9:2000872.
[32] Chen S,Dong Y,Ma S,et al.Superstretching MXene composite hydrogel as a bidirectional stress response thixotropic sensor[J].ACS Applied Materials & Interfaces,2021,13:13629-13636.
[33] Yang C,Xu D,Peng W,et al.Ti3C2Tx nanosheets as photothermal agents for near-infrared responsive hydrogels[J].Nanoscale,2018,10:15387-15392.
[34] Zhang W,Ma J,Zhang W,et al.A multidimensional nanostructural design towards electrochemically stable and mechanically strong hydrogel electrodes[J].Nanoscale,2020,12:6637-6643.
[35] Wu X,Liao H,Ma D,et al.A wearable,self-adhesive,long-lastingly moist and healable epidermal sensor assembled from conductive MXene nanocomposites[J].Journal of Materials Chemistry C,2020,8:1788-1795.
[36] Sun X,Yao F,Li J.Nanocomposite hydrogel-based strain and pressure sensors:a review[J].Journal of Materials Chemistry A,2020,8:18605-18623.
[37] Cai Y,Shen J,Yang C W,et al.Mixed-dimensional MXene-hydrogel heterostructures for electronic skin sensors with ultrabroad working range[J].Science Advances,2020,6:eabb5367.
[38] Rasool K,Helal M,Ali A,et al.Antibacterial activity of Ti3C2Tx MXene[J].ACS Nano,2016,10:3674-3684.
[39] Rozmysłowska-Wojciechowska A,Karwowska E,Gloc M,et al.Controlling the porosity and biocidal properties of the chitosan-hyaluronate matrix hydrogel nanocomposites by the addition of 2D Ti3C2Tx MXene[J].Materials,2020,13:4587.
[40] 刘永超,张志,张焕焕,等.二维MXene材料在超级电容应用的研究进展[J].功能材料,2020,51(4):4061-4067.
[41] 李雪雨,钱刘意,陆少杰,等.MXene/聚合物复合材料研究进展[J].合成橡胶工业,2021,44(1):63-69.
[42] Zhu Y,Liu J,Guo T,et al.Multifunctional Ti3C2Tx MXene composite hydrogels with strain sensitivity toward absorption-dominated electromagnetic-interference shielding[J].ACS Nano,2021,15:1465-1474.
基金资助
青海省科技厅项目(2020-ZJ-729)