化石基胶粘剂污染环境并会对人体产生危害,淀粉基胶粘剂作为一种低碳绿色环保的生物质胶粘剂成为研究热点。介绍了近几年淀粉基胶粘剂的改性方法,包括氧化、酯化、交联、接枝共聚和醚化等,综述了淀粉基胶粘剂在木材加工、医药、纺织、建筑和纸基材料等领域的应用研究现状,并对其未来发展进行了展望。
The problem of environmental pollution and harm to human body caused by fossil-based adhesives is becoming more and more serious.Starch-based adhesives,as a kind of low-carbon and green biomass adhesives,have become research hotspot.The modification methods of starch-based adhesives in recent years,including oxidation,esterification,crosslinking,graft copolymerization and etherification,were introduced.The application research status of the adhesives in the fileds of wood processing,medicine,textile,construction,and paper-based materials were reviwed,and prospected the future development of the adhesives.
[1] Nasiri A,Wearing J,A.Dubé M.Using lignin to modify starch-based adhesive performance[J].ChemEngineering,2020,4(1):3-14.
[2] Builders P F,Mbah C C,Adama K K,et al.Effect of pH on the physicochemical and binder properties of tigernut starch[J].Starch-Stärke,2014,66(3-4):281-293.
[3] Martens B M J,Gerrits W J J,Bruininx E M A M,et al.Amylopectin structure and crystallinity explains variation in digestion kinetics of starches across botanic sources in an in vitro pig model[J].Journal of Animal Science & Biotechnology,2019,10(1):119-131.
[4] 张朝辉,徐珍珍,李伟.季铵阳离子型接枝淀粉的制备及对纤维的粘合性能[J].高分子材料科学与工程,2018,34(9):171-175.
[5] Chen L,Xiong Z Y,Li Q,et al.Sodium dodecyl sulfate improves the properties of bio-based wood adhesive derived from micronized starch:microstructure and rheological behaviors[J].International Journal of Biological Macromolecules,2019,140:1026-1036.
[6] Zhang Y H,Ding L L,Gu J Y,et al.Preparation and properties of a starch-based wood adhesive with high bonding strength and water resistance[J].Carbohydrate Polymers,2015,115:32-37.
[7] Zhao X F,Peng L Q,Wang H L,et al.Environment-friendly urea-oxidized starch adhesive with zero formaldehyde-emission[J].Carbohydrate Polymers,2018,181:1112-1118.
[8] Carvalho L D,Nanci C,Chieregato M B,et al.Ozone processing of cassava starch[J].Ozone:Science & Engineering,2021,43(1):60-77.
[9] Chen Q,Yu H J,Wang L.et al.Recent progress in chemical modification of starch and its applications[J].RSC Advances,2015,5(83):67459-67474.
[10] Wang Z T,Luo H J,Zhang L,et al.Mechanical properties of basalt fiber improved by starch phosphates sizing agent[J].Applied Surface Science,2020,521:146196.
[11] Najafi S M,Baghaie M,Ashori A.Preparation and characterization of acetylated starch nanoparticles as drug carrier:ciprofloxacin as a model[J].International Journal of Biological Macromolecules,2016,87:48-54.
[12] Neto J C,Silva R D,Amaral P,et al.Extraction,chemical modification by octenyl succinic and characterization of cyperus esculentus starch[J].Polímeros,2018,28(4):319-322.
[13] Masina N,Choonara Y E,Kumar P,et al.A review of the chemical modification techniques of starch[J].Carbohydrate Polymers,2017,157(10):1226-1236.
[14] Kusumah S S,Jayadi,Wibowo D T,et al.Investigation of eco-friendly plywood bonded with citric acid-starch based adhesive[J].IOP Conference Series Earth and Environmental Science,2020,460:012009.
[15] Chen L,Wang Y J,Zia-ud-din,et al.Enhancing the performance of starch-based wood adhesive by silane coupling agent (KH570)[J].International Journal of Biological Macromolecules,2017,104:137-144.
[16] Yin H,Zheng P T,Zhang E B,et al.Improved wet shear strength in eco-friendly starch-cellulosic adhesives for woody composites[J].Carbohydrate Polymers,2020,250:116884.
[17] Li D H,Zhuang B R,Wang X D,et al.Chitosan used as a specific coupling agent to modify starch in preparation of adhesive film[J].Journal of Cleaner Production,2020,277:123210.
[18] Gu Y,Cheng L,Gu Z B,et al.Preparation,characterization and properties of starch-based adhesive for wood-based panels[J].International Journal of Biological Macromolecules,2019,134:247-254.
[19] Wang Z J,Hua Z,Huang J N,et al.Improvement of the bonding properties of cassava starch-based wood adhesives by using different types of acrylic ester[J].International Journal of Biological Macromolecules,2019,126(1):603-611.
[20] Zia-ud-din,Xiong H G,Wang Z J,et al.Effects of sucrose fatty acid ester addition on the structural,rheological and retrogradation behavior of high amylose starch-based wood adhesive[J].International Journal of Adhesion & Adhesives,2019,89:51-58.
[21] Li W,Xu Z Z,Wang Z Q,et al.Double etherification of corn starch to improve its adhesion to cotton and polyester fibers[J].International Journal of Adhesion and Adhesives,2018,84:101-107.
[22] Li W,Wu J,Hou D Y.Deriving 3-propanesulfonic-2-hydroxy substituents in the molecular chains for overcoming the drawbacks of oxidized cassava starch[J].International Journal of Adhesion and Adhesives,2019,95:102441.
[23] 梁冬梅,莫福旺,黄志强,等.阳离子醚化淀粉改性脲醛树脂胶黏剂的研究[J].化工技术与开发,2020,49(8):17-19.
[24] Lamaming J,Heng N B,Owodunni A A,et al.Characterization of rubberwood particleboard made using carboxymethyl starch mixed with polyvinyl alcohol as adhesive[J].Composites Part B:Engineering,2020,183:107731.
[25] Xing J C,Li T T,Yu Y X,et al.Development and characterization of a new bio-adhesive for wood using cassava starch and bio-oil[J].International Journal of Adhesion and Adhesives,2018,87:91-97.
[26] Abdelghani B,Houssaine A E,Ait B A,et al.Valorization of Moroccan brown seaweeds:elaboration of formaldehyde-free particleboards based on sodium alginate-corn-starch-mimosa tannin wood adhesives[J].International Journal of Adhesion and Adhesives,2021,108:102894.
[27] Mao Y X,Li P,Yin J W,et al.Starch-based adhesive hydrogel with gel-point viscoelastic behavior and its application in wound sealing and hemostasis[J].Journal of Materials Science & Technology,2021,63:228-235.
[28] Zeng S,Zhang J Y,Zu G Q,et al.Transparent,flexible,and multifunctional starch-based double-network hydrogels as high-performance wearable electronics[J].Carbohydrate Polymers,267:118198.
[29] Liu J,Li J,Yu F,et al.In situ forming hydrogel of natural polysaccharides through Schiff base reaction for soft tissue adhesive and hemostasis[J].International Journal of Biological Macromolecules,2020,147:653-666.
[30] Li W,Wu Y K,Xu Z Z,et al.Blending caproylated starch with poly(acrylic acid)-g-protein-g-poly(methyl acrylate) as an adhesive material to improve the adhesion of starch to PLA fibers[J].International Journal of Adhesion and Adhesives,2020,102:102668.
[31] Zhu Z F,Song Y Z,Xu Z Z,et al.Introduction of octenylsuccinate and carboxymethyl onto starch for strong bonding to fiber and easy removal from sized yarn[J].Carbohydrate Polymers,2021,269:118249.
[32] Li W,Zhang Z Q,Wu L J,et al.Improving the adhesion-to-fibers and film properties of corn starch by starch sulfo-itaconation for a better application in warp sizing[J].Polymer Testing,2021,98:107194.
[33] Sam S S,Habib N Z,Choonaun N,et al.Encapsulation of oil-starch binder for the production of decorative floor tile[J].Waste and Resource Management,2019,172(4):1-16.
[34] 黄朗宁.磷酸酯化淀粉胶粘剂对建筑物混凝土梁的加固作用研究[J].中国胶粘剂,2020,29(9):53-57.
[35] 黄秀娟,李起潮.淀粉半干法复合改性生产墙胶粉的研究[J].化工新型材料,2008(12):102-103;109.
[36] Wu Q,Shao W L,Xia N N,et al.A separable paper adhesive based on the starch-lignin composite[J].Carbohydrate Polymers,2020,229:115488.
[37] 张永,胡荣柳,付华杰,等.环保壁纸胶粉用改性淀粉的应用研究[J].河南化工,2021,38(1):28-30.
[38] 付林林,于静,李敏贤,等.聚丙烯酸钠改性淀粉标签胶的研究[J].中国胶粘剂,2016,25(8):33-36.
基金资助
湖南省自然科学基金(2020JJ4095);湖南省企业科技创新创业团队项目(201918);湖南省高新技术产业科技创新引领计划项目(2021GK4040)