柔性Cu基底生长金属氧化物负极材料的研究现状

乔盼盼, 解勤兴*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (5) : 235 -239.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (5) : 235-239. DOI: 10.19817/j.cnki.issn1006-3536.2022.05.048
开发与应用

柔性Cu基底生长金属氧化物负极材料的研究现状

    乔盼盼, 解勤兴*
作者信息 +

Research progress of metal oxide anchored on flexible Cu substrate as anode for Li-ion battery

  • Qiao Panpan, Xie Qinxing
Author information +
文章历史 +
PDF

摘要

随着人们对可弯曲且高性能锂离子电池需求的不断增加,急需探究在柔性基底上生长金属氧化物的锂离子电池负极材料。为此,总结了近年在Cu箔上生长金属氧化物并作为锂离子电池负极材料的研究进展。主要概括了以柔性Cu箔为导电基底,在Cu箔表面直接生长CuO及其他金属氧化物的各种制备方法,并将所制备的柔性材料作为负极,探究其对锂离子电池电化学性能的影响。另外,对在Cu箔上生长金属氧化物的制备方法推广到其他柔性导电基底,以及在Cu箔上生长金属氧化物和金属有机框架应用在其他领域做了展望。

Abstract

Metal oxides anchored on flexible substrate as anodes material for Li-ion batteries have been ongoing explored due to the rapidly growing demand for flexible Li-ion batteries with flexible and high-capacity.So,the recent work of metal oxides anchored on flexible Cu foils as anodes for Li-ion batteries were reviewed,which including the various preparation of CuO and other metal oxides grow on Cu foil and their influence of electrochemical performance in anodes of Li-ion batteries.In addition,the expansion of different preparation methods to other flexible conductive substrates,the growth of metal oxides and metal organic frameworks on Cu foil in other fields were prospected.

关键词

柔性Cu箔 / 金属氧化物 / 负极材料 / 锂离子电池

Key words

flexible Cu foil / metal oxide / anode material / Li-ion batterY

引用本文

引用格式 ▾
柔性Cu基底生长金属氧化物负极材料的研究现状[J]. 化工新型材料, 2022, 50(5): 235-239 DOI:10.19817/j.cnki.issn1006-3536.2022.05.048

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Balogun M S,Yang H,Luo Y,et al.Achieving high gravimetric energy density for flexible lithium-ion batteries facilitated by core-double-shell electrodes[J].Energy & Environmental Science,2018,11(7):1859-1869.
[2] Zhou M,Peng N,Liu Z,et al.Synthesis of sub-10nm copper sulphide rods as high-performance anode for long-cycle life Li-ion batteries[J].Journal of Power Sources,2016,306:408-412.
[3] Li C,Sarapulova A,Zhao Z,et al.Understanding the lithium storage mechanism in core-shell Fe2O3@C hollow nanospheres derived from metal-organic frameworks:an in operando synchrotron radiation diffraction and in operando X-ray absorption spectroscopy study[J].Chemistry of Materials,2019,31(15):5633-5645.
[4] Wang Y,Guo W,Yang Y,et al.Rational design of SnO2@C@MnO2 hierarchical hollow hybrid nanospheres for a Li-ion battery anode with enhanced performances[J].Electrochimica Acta,2018,262:1-8.
[5] Wu Y,Li X,Xiao Q,et al.The coaxial MnO2/CNTs nanocomposite freestanding membrane on SSM substrate as anode materials in high performance lithium ion batteries[J].Journal of Electroanalytical Chemistry,2019,834:161-166.
[6] Chen K,Song S,Xue D.Vapor-phase crystallization route to oxidized Cu foils in air as anode materials for lithium-ion batteries[J].Cryst Eng Comm,2013,15(1):144-151.
[7] Lamberti A,Destro M,Bianco S,et al.Facile fabrication of cuprous oxide nanocomposite anode films for flexible Li-ion batteries via thermal oxidation[J].Electrochimica Acta,2012,70:62-68.
[8] Yang Y,Wang K,Yang Z,et al.An efficient route to Cu2O nanorod array film for high-performance Li-ion batteries[J].Thin Solid Films,2016,608:79-87.
[9] Jia S,Wang Y,Liu X,et al.Hierarchically porous CuO nano-labyrinths as binder-free anodes for long-life and high-rate lithium ion batteries[J].Nano Energy,2019,59:229-236.
[10] Xiang J Y,Tu J P,Huang X H,et al.A comparison of anodically grown CuO nanotube film and Cu2O film as anodes for lithium ion batteries[J].Journal of Solid State Electrochemistry,2007,12(7-8):941-945.
[11] Inamdar A I,Chavan H S,Aqueel Ahmed A T,et al.Macroporous Cu(OH)2 nanorod network fabricated directly on Cu foil as binder-free Lithium-ion battery anode with ultrahigh capacity[J].Journal of Alloys and Compounds,2020,829:154593.
[12] Zhang W,Wang H,Zhang Y,et al.Facile microemulsion synthesis of porous CuO nanosphere film and its application in lithium ion batteries[J].Electrochimica Acta,2013,113:63-68.
[13] Zhang Y,Zhang W,Li M,et al.Cosurfactant-mediated microemulsion to free-standing hierarchical CuO arrays on copper substrates as anodes for lithium-ion batteries[J].Journal of Materials Chemistry A,2013,1(45):14368.
[14] Zhang W,Li M,Wang Q,et al.Hierarchical self-assembly of microscale cog-like superstructures for enhanced performance in lithium-ion batteries[J].Advanced Functional Materials,2011,21(18):3516-3523.
[15] Chen W,Zhang H,Ma Z,et al.Binder free Cu(OH)2/CuO electrodes fabricated directly on copper foils by facile large-scale production method[J].Journal of Alloys and Compounds,2018,762:565-573.
[16] Wei L,Li L,Zhao T,et al.MOF-derived lithiophilic CuO nanorod arrays for stable lithium metal anodes[J].Nanoscale,2020,12(17):9416-9422.
[17] Yin D,Huang G,Na Z,et al.CuO nanorod arrays formed directly on Cu foil from MOFs as superior binder-free anode material for lithium-ion batteries[J].ACS Energy Letters,2017,2(7):1564-1570.
[18] Wang L,Liu B,Ran S,et al.Nanorod-assembled Co3O4 hexapods with enhanced electrochemical performance for lithium-ion batteries[J].Journal of Materials Chemistry,2012,22(44):23541.
[19] Cao K,Jiao L,Liu H,et al.3D Hierarchical porous α-Fe2O3nanosheets for high-performance lithium-ion batteries[J].Advanced Energy Materials,2015,5(4):1401421.
[20] Wu H,Xu M,Wu H,et al.Aligned NiO nanoflake arrays grown on copper as high capacity lithium-ion battery anodes[J].Journal of Materials Chemistry,2012,22(37):19821-19825.
[21] Wang B,Wang G,Wang H.In situ synthesis of Co3O4/Cu electrode and its high performance for lithium-ion batteries[J].Materials Letters,2014,122:186-189.
[22] Huang Y,Xu Z,Mai J,et al.Revisiting the origin of cycling enhanced capacity of Fe3O4 based nanostructured electrode for lithium ion batteries[J].Nano Energy,2017,41:426-433.
[23] Li A,Song H,Chen X,et al.Lithiation confined in one dimensional nanospace of TiO2(anatase) nanotube to enhance the lithium storage property of CuO nanowires[J].ACS Appl Mater Interfaces,2015,7(40):22372.
[24] Li Q,Feng Y,Wang P,et al.Superior-capacity binder-free anode electrode for lithium-ion batteries:CoxMnyNizO nanosheets with metal/oxygen vacancies directly formed on Cu foil[J].Nanoscale,2019,11(11):5080-5093.
AI Summary AI Mindmap
PDF

585

访问

0

被引

导航
相关文章

AI思维导图

/