MOFs衍生NPC/CoFe2O4二元复合材料的制备及其电磁波吸收性能的研究

江陈烨1,2, 罗驹华2*, 陈晓雯3, 孙彩红2

化工新型材料 ›› 2022, Vol. 50 ›› Issue (5) : 80 -86.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (5) : 80-86. DOI: 10.19817/j.cnki.issn1006-3536.2022.05.017
新材料与新技术

MOFs衍生NPC/CoFe2O4二元复合材料的制备及其电磁波吸收性能的研究

    江陈烨1,2, 罗驹华2*, 陈晓雯3, 孙彩红2
作者信息 +

Preparation of MOFs-derived NPC/CoFe2O4 and its electromagnetic wave absorption property

  • Jiang Chenye1,2, Luo Juhua2, Chen Xiaowen3, Sun Caihong2
Author information +
文章历史 +
PDF

摘要

采用两步法制备出氮掺杂多孔碳材料(NPC),通过水热法原位合成NPC/CoFe2O4复合材料。采用XRD、FT-IR、XPS和SEM等方法对样品结构及形貌进行表征,并采用VNA测试材料的电磁参数,计算出在2G~18GHz范围内样品对电磁波的吸收效果。结果表明,当CoFe2O4的添加量为15%时,样品具有最佳的吸波性能。当频率为10.24GHz时,最低反射损耗达到-19.09dB,此时样品的厚度为3.5mm,有效吸波带宽为4GHz。

Abstract

Nitrogen-doped porous carbon materials were firstly prepared by a two-step method,and then the nitrogen-doped porous carbon/cobalt ferrite composites were synthesized by the hydrothermal method.XRD,FT-IR,XPS,SEM were used to characterize the structure and morphology of the samples.The microwave electromagnetic parameters of the composites were measured by VNA and the frequency range from 2 GHz to 18 GHz,the absorbing properties were calculated by electromagnetic parameters.The results showed that when the cobalt ferrite content was 15%,the sample had the best absorption performance.The minimum reflection loss reached -19.09dB at the frequency of 10.24GHz with a matching thickness of 3.5mm,and the effective absorbing bandwidth was 4GHz.

关键词

金属有机框架结构 / 氮掺杂多孔碳 / 铁氧体 / 电磁性能

Key words

MOFs / N-doped porous carbon / CoFe2O4 / electromagnetic performance

引用本文

引用格式 ▾
MOFs衍生NPC/CoFe2O4二元复合材料的制备及其电磁波吸收性能的研究[J]. 化工新型材料, 2022, 50(5): 80-86 DOI:10.19817/j.cnki.issn1006-3536.2022.05.017

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Liang Z,Huan X,Su G X,et al.Tunable electromagnetic and broadband microwave absorption of SiO2-coated FeSiAl absorbents[J].Journal of Alloys and Compounds,2020,24,157966.
[2] Bai N F,Zhong F X,Shen J X,et al.A thermal-insensitive ultra-broadband metamaterial absorber[J].Journal of Physics D:Applied Physics,2020,54,9,095101.
[3] Qiao M T,Li J X,Wei D,et al.Chain-like Fe3O4@void@mSiO2@MnO2 composites with multiple porous shells toward highly effective microwave absorption application[J].Microporous and Mesoporous Materials,2021,314,110867.
[4] Gao Y,Wang Z,Shi R M,et al.Electromagnetic and microwave absorption properties of Ti doped Li-Zn ferrites[J].Journal of Alloys and Compounds,2019,805:934-941.
[5] Huang L X,DuanY P,Yang X,et al.Ultra-flexible composite metamaterials with enhanced and tunable microwave absorption performance[J].Composite Structures,2019,229,111469.
[6] Chen C,BaoS Z,Zhang B S,et al.Coupling Fe@Fe3O4 nanoparticles with multiple-walled carbon nanotubes with width band electromagnetic absorption performance[J].Applied Surface Science,2019,467-468:836-843.
[7] Ma T,Cui Y,Sha Y L,et al.Facile synthesis of hierarchically porous rGO/MnZn ferrite composites for enhanced microwave absorption performance[J].Synthetic Metals,2020,265,116407.
[8] Zhu X L,Wang X P,Liu K L,et al.Microwave absorption characteristics of carbon foam decorated with BaFe12O19 and Ni0.5Co0.5Fe2O4 magnetic composite in X-band frequency[J].Journal of Magnetism and Magnetic Materials,2020,513,167258.
[9] Ma T,Cui Y,Sha Y L,et al.Facile synthesis of hierarchically porous rGO/MnZn ferrite composites for enhanced microwave absorption performance[J].Synthetic Metals,2020,265,116407.
[10] Shang Q,Feng H X,Liu J P,et al.Constructing and optimizing hollow ZnxFe3-xO4@polyaniline composites as high-performance microwave absorbers[J].Journal of colloid andInterface Science,2020,584:80-91.
[11] Xu X Q,Ran F T,Fan Z M,et al.Acidified bimetallic MOFs constructed Co/N co-doped low dimensional hybrid carbon networks for high-efficiency microwave absorption[J].Carbon,2021,171:211-220.
[12] Li Z N,Han X J,Ma Y,et al.MOFs-derived hollow Co/C microspheres with enhanced microwave absorption performance[J].ACS Sustainable Chemistry & Engineering,2018,6:8904-8913.
[13] Jiao Y Z,Li J J,Xie A M,et al.Confined polymerization strategy to construct polypyrrole/zeoliticimidazolate frameworks (PPy/ZIFs) nanocomposites for tunable electrical conductivity and excellent electromagnetic absorption[J].Composites Science and Technology,2019,174:232-240.
[14] Yu J H,Yu J Y,Ying T P,et al.Zeoliticimidazolate framework derived Fe-N/C for efficient microwave absorbers[J].Journal of Alloys and Compounds,2020,838,155629.
[15] 袁野.轻质多功能多孔碳材料的制备及性能研究[D].哈尔滨:尔滨工业大学,2018.
[16] 郑方才.基于金属有机框架化合物合成多孔碳基纳米材料及其在锂电池负极材料中的应用[D].合肥:中国科学技术大学,2015.
[17] 吴小雨,李松梅,刘建华,等.CoFe2O4-石墨烯纳米复合材料的制备及微波吸收性能[J].无机材料学报,2014,29(8):845-850.
[18] 刘沛江.石墨烯/铁氧体/聚酰亚胺三元复合材料的制备及其电磁性能研究[D].南京:南京航空航天大学,2018.
[19] Zeng Q W,Wang L,Li X,et al.Double ligand MOF-derived pomegranate-like Ni@C microspheres as highperformance microwave absorber[J].Applied Surface Science,2021,538,148051.
[20] Zhang F,Zhang W D,Zhu W F,et al.Core-shell nanostructured CS/MoS2a promising material for microwave absorption[J].Appl Surf Sci,2019,463:182-189.
[21] Su X G,Wang J,Zhang X X,et al.One-step preparation of CoFe2O4/FeCo/graphite nanosheets hybrid composites with tunable microwave absorption performance[J].Ceramics International,2020,46:12353-12363.
[22] Huang L,Li J J,Wang Z J,et al.Microwave absorption enhancement of porous C@CoFe2O4 nanocomposites derived from eggshell membrane[J].Carbon,2019,143:507-516.
[23] Zhang M,Zhang J H,Lin H,et al.Designable synthesis of reduced graphene oxide modified using CoFe2O4nanospheres with tunable enhanced microwave absorption performances between the whole X and Ku bands[J].Composites Part B,2020,190,107902.
[24] Zhang M,Chen L,Yang Y,et al.Cabon nanofiber supported cobalt ferrite composites with tunable microwave absorption properties[J].Ceramics International,2020.
[25] 刘佳良,陈平,徐东卫,等.磁性多孔RGO@Ni复合材料的制备和吸波性能[J].材料研究学报,2020,34(9):641-649.
[26] Zhou M,Zhang X,Wei J M,et al.Morphology-controlled synthesis and novel microwave absorption properties of hollow urchin-like α-MnO2 nanostructures[J].JPhysChem,2011,115C,1398.
[27] Sun Q Y,Zhang X F,Liu R N,et al.Nickel-assisted synthesis of magnetic bamboo-shaped N-doped carbon nanostructure for excellent microwaves absorption[J].Synthetic Metals,2021,272,116644.
[28] Li Z X,Li X H,Zong Y,et al.Solvothermal synthesis of nitrogendoped graphene decorated by superparamagnetic Fe3O4 nanoparticles and their applications as enhanced synergistic microwave absorbers[J].Carbon,2017,115:493.
[29] Qiu B C,Xing M Y,Zhang J L.Recent advances in three-dimen-sionalgraphene based materials for catalysis applications[J].Chem Soc Rev,2018,47:2165.
[30] Meng Z,Tian C H,Xu C L,et al.Multi-spectral functional metasurface simultaneously with visible transparency,low infrared emissivity and wideband microwave absorption[J].Infrared Physics and Technology,2020,110,103469.
[31] Chen F,Luo H,Cheng Y Z,et al.Nickel/Nickel phosphide composite embedded in N-doped carbon with tunable electromagnetic properties toward high-efficiency microwave absorption[J].Composites Part A,2021,140,106141.

基金资助

江苏省研究生科研实践创新项目(rant No.SJCX18-0886)

AI Summary AI Mindmap
PDF

625

访问

0

被引

导航
相关文章

AI思维导图

/