独特的微观结构使二维材料展现出许多奇特的性质,并且其层状结构提供了可扩展的二维空间,便于客体材料(如离子、分子、纳米颗粒和聚合物链等)的插入,由此产生的插层材料表现出不同于原始二维材料与客体的性质。通过调控插层方法与过程,可以优化二维插层材料的结构与性能。综述了二维插层材料与插层化学领域的创新,较全面地介绍了二维插层材料的插层机理、方法和应用,讨论了二维插层材料的潜在应用、挑战和未来的机遇。
The unique microstructure allows 2D materials to exhibit many peculiar properties,and their layered structure provides scalable 2D space for the insertion of guest materials (e.g.,ions,molecules,nanoparticles,and polymer chains),resulting in intercalated materials that exhibit properties different from those of the original 2D materials and guests.By tuning the intercalation method and process,the structure and properties of 2D intercalated materials can be optimized.The innovations in the field of 2D intercalation materials and intercalation chemistry were reviewed,and provided more comprehensive overview of the intercalation mechanisms,methods and applications of 2D intercalation materials The potential applications,challenges and future opportunities of 2D intercalation materials were.discussed.
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基金资助
国家自然科学基金面上项目(51978352);山东省自然科学基金面上项目(ZR2019MEM041)