根据以往的研究,硬脂酸因其优良的相变蓄热性能,而受到越来越多的关注。然而,硬脂酸导热性能较差,易发生液相泄露且相变温度单一,限制了其在较多领域的应用。通过分析现有文献,综述了导致硬脂酸热导率低和液相泄漏等问题的原因及解决方法,并指出各方法中的不足之处,总结了硬脂酸复合相变材料的优点,并对硬脂酸复合相变材料的未来发展做出了展望。
According to previous studies,stearic acid has attracted more and more attention due to its excellent phase change heat storage performance.However,the poor thermal conductivity,leakage and single phase transition temperature of stearic acid limit its application in many fields.By analyzing the existing literatures,the causes and solutions for the problems of stearic acid,such as low thermal conductivity and liquid leakage,were reviewed,and pointed out the shortcomings of each method.The advantages of the materials were summarized,and prospected the future development of such materials.
[1] Siraj Sabihuddin,Aristides E Kiprakis,Markus Mueller,et al.A numerical and graphical review of energy storage technologies[J].Energies,2014,8:172.
[2] Yan Q Y,Liu C,Zhang J.Experimental study on thermal conductivity of composite phase change material of fatty acid and paraffin[J].Materials Research Express,2019,6:065507.
[3] Shukla A,Buddhi D,Sawhney R L.Solar water heaters with phase change material thermal energy storage medium:a review[J].Renewable and Sustainable Energy Reviews,2009,13(8):2119-2125.
[4] Zahir M H,Rahman M M,Irshad K,et al.Shape-stabilized phase change materials for solar energy storage:MgO and Mg(OH)2 mixed with polyethylene glycol[J].Nanomaterials,2019,9(12):1173.
[5] Khan Z,Khan Z,Ghafoor A.A review of performance enhancement of PCM based latent heat storage system within the context of materials,thermal stability and compatibility[J].Energy Conversion & Management,2016,115(5):132-158.
[6] 崔娜,谢静超,刘加平,等.石膏基相变储能构件的数值模拟分析[J].化工学报,2014,65(S1):328-335.
[7] Shaikh S,Lafdi K.C/C composite,carbon nanotube and paraffin wax hybrid systems for the thermal control of pulsed power in electronics[J].Carbon,2010,48(3):813-824.
[8] Sharma A,Tyagi V V,Chen C R,et al.Review on thermal energy storage with phase change materials and applications[J].Renewable & Sustainable Energy Reviews,2009,13(2):318-345.
[9] Rathod M K,Banerjee J.Thermal stability of phase change materials used in latent heat energy storage systems:a review[J].Renewable & Sustainable Energy Reviews,2013,18:246-258.
[10] 顾庆军,费华,王林雅,等.脂肪酸相变储能材料热性能研究进展[J].化工进展,2019,38(6):2825-2834.
[11] 何媚质,杨鲁伟,张振涛.有机-无机复合相变材料的研究进展[J].化工进展,2018,37(12):4709-4718.
[12] Kylili A,Fokaides P A.Life cycle assessment (LCA) of phase change materials (PCMs) for building applications:a review[J].Journal of Building Engineering,2016,6:133-143.
[13] 张天驰,俞海云,冒爱琴,等.有机相变储能材料导热增强方法研究进展[J].过程工程学报,2017,17(1):201-208.
[14] Ma Z,Lin W,Sohel M I.Nano-enhanced phase change materials for improved building performance[J].Renewable and Sustainable Energy Reviews,2016,58:1256-1268.
[15] Masoumi H,Haghighi Khoshkhoo R,Mirfendereski S M.Modification of physical and thermal characteristics of stearic acid as a phase change materials using TiO2-nanoparticles[J].Thermochimica Acta,2019,DOI:10.1016/j.tca.2019.02.015.
[16] Li T X,Lee J H,Wang R Z,et al.Enhancement of heat transfer for thermal energy storage application using stearic acid nanocomposite with multi-walled carbon nanotubes[J].Energy,2013,55:752-761.
[17] Choi Da Hee,Lee Juhyuk,Hong Hiki,et al.Thermal conductivity and heat transfer performance enhancement of phase change materials (PCM) containing carbon additives for heat storage application[J].International Journal of Refrigeration,2014,42:112-120.
[18] Zhang Qi,Liu Jian.Sebacic acid/CNT sponge phase change material with excellent thermal conductivity and photo-thermal performance[J].Solar Energy Materials & Solar Cells An International Journal Devoted to Photovoltaic Photothermal & Photochemical Solar Energy Conversion,2018,179:217-222.
[19] Li C,Xie B,Chen J.Graphene-decorated silica stabilized stearic acid as a thermal energy storage material[J].RSC Advances,2017,7(48):30142-30151.
[20] Wang Y,Xia T D,Zheng H,et al.Stearic acid/silica fume composite as form-stable phase change material for thermal energy storage[J].Energy & Buildings,2011,43(9):2365-2370.
[21] 仵斯,李廷贤,闫霆,等.高性能定形复合相变储能材料的制备及热性能[J].化工学报,2015,66(12):5127-5134.
[22] Dao T D,Jeong,Mo H.Novel stearic acid/graphene core-shell composite microcapsule as a phase change material exhibiting high shape stability and performance[J].Solar Energy Materials and Solar Cells,2015,137:227-234.
[23] Peng K,Fu L,Li X,et al.Stearic acid modified montmorillonite as emerging microcapsules for thermal energy storage[J].Applied Clay Science,2017,138:100-106.
[24] 陈丹丹,陈志能,吴淑英.硬脂酸填充碳纳米管相变胶囊材料的热性质研究[J].化工新型材料,2020,48(3):109-113,124.
[25] 汪意,杨睿,张寅平,等.定形相变材料的研究进展[J].储能科学与技术,2013,2(4):362-368.
[26] Wang G,Xu W,Hou Q,et al.A simple sonochemical method for fabricating poly(methyl methacrylate)/stearic acid phase change energy storage nanocapsules[J].Ultrasonics-Sonochemistry,2015,27:403-407.
[27] Sari A,Kaygusuz K.Studies on poly(vinyl chloride)/fatty acid blends as shape-stabilized phase change material for latent heat thermal energy storage[J].Indian Journal of Engineering and Materials Sciences,2006,13(3):253-258.
[28] Sari A,Kaygusuz K.Poly(vinyl alcohol)/fatty acid blends for thermal energy storage[J].Energy Sources,2007,29(9-12):873-883.
[29] 王静静,徐小亮,梁凯彦,等.多孔基定形复合相变材料传热性能提升研究进展[J].工程科学学报,2020,42(1):26-38.
[30] Liu S,Yang H.Stearic acid hybridizing coal-series kaolin composite phase change material for thermal energy storage[J].Applied Clay Science,2014,101:277-281.
[31] Fu Zhenjin,Dai Li,Yi Yong,et al.Structure and thermal properties of stearic acid/silica composites as form-stable phase change materials[J].Journal of Sol-Gel Science and Technology,2018,87:419-426.
[32] Yu Haitao,Gao Jianmin,Chen Yao,et al.Preparation and properties of stearic acid/expanded graphite composite phase change material for low-temperature solar thermal application[J].Journal of Thermal Analysis & Calorimetry,2016,124(1):87-92.
[33] Li B,Liu T,Hu L,et al.Facile preparation and adjustable thermal property of stearic acid-graphene oxide composite as shape-stabilized phase change material[J].Chemical Engineering Journal,2013,215:819-826.
[34] Zhang T,Chen M,Zhang Y,et al.Microencapsulation of stearic acid with polymethylmethacrylate using iron(Ⅲ) chloride as photo-initiator for thermal energy storage[J].Chinese Journal of Chemical Engineering,2017(25):1532.
[35] Latibari S T,Mehrali M,Mehrali M,et al.Facile synthesis and thermal performances of stearic acid/titania core/shell nanocapsules by sol-gel method[J].Energy,2015,85:1-10.
[36] Subramanian A,Appukuttan S.Microencapsulation of stearic acid into strontium titanate shell by sol-gel approach for thermal energy storage[J].ChemistrySelect,2019,4(27):7818-7823.
[37] Li B X,Wang Y F,Zhu B.Fabrication and characterization of nanoencapsulated stearic-acid/SiO2 phase change material[J].Materials Science Forum,2011,694:123-127.
[38] Mei D,Zhang B,Liu R,et al.Preparation of stearic acid/halloysite nanotube composite as form-stable PCM for thermal energy storage[J].International Journal of Energy Research,2011,35(9):828-834.
[39] Yi H,Ai Z,Zhao Y,et al.Design of 3D-network montmorillonite nanosheet/stearic acid shape-stabilized phase change materials for solar energy storage[J].Solar Energy Materials and Solar Cells,2020,204:110233.
[40] 柯惠珍,李永贵.脂肪酸多元低共熔物的共晶质量比例、储热性能及其应用[J].材料科学与工程学报,2018,36(1):82-86.
[41] Li M,Kao H,Wu Z,et al.Study on preparation and thermal property of binary fatty acid and the binary fatty acids/diatomite composite phase change materials[J].Applied Energy,2011,88(5):1606-1612.
[42] Sari A,Sari H,Oenal A.Thermal properties and thermal reliability of eutectic mixtures of some fatty acids as latent heat storage materials[J].Energy Conversion and Management,2004,45(3):365-376.
[43] Karaipekli A,Sari A,Kaygusuz K.Thermal properties and thermal reliability of capric acid/stearic acid mixture for latent heat thermal energy storage[J].Energy Sources,2009,31(1-4):199-207.
[44] 于文艳,王慧娟,田瑞.石蜡-硬脂酸/石墨复合相变材料的储热性能研究[J].功能材料,2019,50(4):4104-4107.
[45] 刘旻瑞,孙志高,李成浩,等.硬脂酸-十八醇二元复合相变材料性能研究[J].太阳能学报,2019,40(6):1553-1559.