环氧沥青改性材料研究及发展建议

曹雪娟1, 魏奎玲1*, 丁勇杰2, 单柏林2

化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 248 -253.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 248-253. DOI: 10.19817/j.cnki.issn1006-3536.2022.02.049
开发与应用

环氧沥青改性材料研究及发展建议

    曹雪娟1, 魏奎玲1*, 丁勇杰2, 单柏林2
作者信息 +

Study and development suggestion for modified material of epoxy asphalt

  • Cao Xuejuan1, Wei Kuiling1, Ding Yongjie2, Shan Bailin2
Author information +
文章历史 +
PDF

摘要

环氧沥青以优于普通沥青的物理和化学性能在诸多领域得到了广泛应用,为推动环氧沥青技术的开发应用,综述了国内外环氧沥青的研究进展。首先,介绍了热固性环氧沥青自身缺陷及面临的技术问题;然后,探讨了环氧沥青的组分、分子结构和工作机理,分析了冷拌、温拌和热拌环氧沥青的使用特点,进而从增韧、相容性和固化剂3个方面讨论了环氧沥青的主要改性形式,并总结了现有技术的应用情况;最后,提出了一种含可交换动态共价键的类玻璃高分子材料,该材料可代替热固性环氧树脂制备热塑性改性环氧沥青,使其具有更好的施工及使用性能并可实现再生。

Abstract

Epoxy asphalt has been widely used in many fields because of its better physical and chemical properties than ordinary asphalt.The research progress of epoxy asphalt material at home and abroad was reviewed to promote the development and application of epoxy asphalt technology.Firstly,the defects of thermosetting epoxy asphalt and the technical problems it face were introduced.Secondly,the composition,molecular structure and working mechanism of epoxy asphalt were discussed,and analyzed the use characteristics of cold,warm and hot mix epoxy asphalt.The main modified forms of epoxy asphalt were discussed from the three aspects of toughening,compatibility and curing agent,and summarized the application of the existing technology.Finally,a glass-like polymer with exchangeable dynamic covalent bonds was proposed,this material can replace thermosetting epoxy resin to prepare thermoplastic modified epoxy asphalt,so that it had better construction and use performance,and can be regenerated.

关键词

环氧沥青 / 综述 / 钢桥面铺装 / 再生性 / 类玻璃高分子 / 热塑性

Key words

epoxy asphalt / review / steel deck pavement / regenerability / vitrimer / thermoplasticity

引用本文

引用格式 ▾
环氧沥青改性材料研究及发展建议[J]. 化工新型材料, 2022, 50(2): 248-253 DOI:10.19817/j.cnki.issn1006-3536.2022.02.049

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Luo S,Liu Z,Yang X,et al.Construction technology of warm and hot mix epoxy asphalt paving for long-span steel bridge[J].Journal of Construction Engineering and Management,2019,145(12):04019074.
[2] Alamri M,Lu Q,Xin C.Preliminary evaluation of hot mix asphalt containing reclaimed epoxy asphalt materials[J].Sustainability,2020,12(9):3531.
[3] Wang X,Wu R,Zhang L.Development and performance evaluation of epoxy asphalt concrete modified with glass fibre[J].Road Materials and Pavement Design,2019,20(3):715-726.
[4] Xiang Q,Xiao F.Applications of epoxy materials in pavement engineering[J].Construction and Building Materials,2020,235:117529.
[5] 周健,魏小皓,刘鎏,等.钢桥面铺装用热、温拌环氧沥青混凝土性能对比[J].公路,2018,63(11):1-7.
[6] Cheraghian G,Cannone Falchetto A,You Z,et al.Warm mix asphalt technology:an up to date review[J].Journal of Cleaner Production,2020,268:122128.
[7] Lin Y P,Li B.Research on pavement performance with warm mix asphalt concrete[J].Advanced Materials Research,2011,418-420:147-152.
[8] 秦耕,何翔,李璐,等.高温拌和型改性环氧沥青混合料的开发[J].山西建筑,2015,41(32):113-115.
[9] 袁智慧,牛永平,汪小伟,等.环氧树脂增韧机理及研究进展[J].热固性树脂,2019,34(6):65-70.
[10] 李永杰,安曼,田丛,等.国内外环氧树脂增韧的研究进展[J].信息记录材料,2016,17(5):36-40.
[11] Kavitha N,Balasubramanian M,Kennedy A X.Investigation of impact behavior of epoxy reinforced with nanometer- and micrometer-sized silicon carbide particles[J].Journal of Composite Materials,2012,47(15):1877-1884.
[12] 王冬华,付新.SiC纳米线/环氧树脂复合材料的力学性能研究[J].热固性树脂,2018,33(6):1-6.
[13] 方界凤,蔡澄霖,叶辛,等.端羧基丁腈橡胶增韧改性环氧树脂的研究[J].粘接,2019,40(5):92-95.
[14] 刘旭东,温勇,张文艺,等.聚丙二醇增韧环氧树脂及其性能研究[J].热固性树脂,2019,34(1):16-18.
[15] Su W,Han X,Gong J,et al.Toughening epoxy asphalt binder using core-shell rubber nanoparticles[J].Construction and Building Materials,2020,258:119716.
[16] Du X,Xu P,Cong P,et al.Compatibilization and toughness modification of linear aliphatic epoxy compound on paving epoxy asphalt[J].Materials and Structures,2020,53(2):42.
[17] 张争奇,张苛,李志宏,等.环氧沥青混凝土增柔增韧改性技术[J].长安大学学报(自然科学版),2015,35(1):1-7.
[18] Xue Y,Qian Z.Development and performance evaluation of epoxy asphalt concrete modified with mineral fiber[J].Construction and Building Materials,2016,102:378-383.
[19] Zhang Z,Sun J,Jia M,et al.Study on a thermosetting polyurethane modified asphalt suitable for bridge deck pavements:formula and properties[J].Construction and Building Materials,2020,241:118122.
[20] 晏永,封基良,郭荣鑫,等.环氧沥青相容性研究进展[J].化工新型材料,2017,45(7):42-44.
[21] 刘成,李志军,郭皎河,等.热固性环氧沥青相容性研究进展[J].中国胶粘剂,2019,28(4):58-62.
[22] 黄卫,陈志明,闵召辉.高速公路及道桥用环氧沥青材料及其制备方法[P].CN200310106597.X,2004-11-17.
[23] 周威,文俊,蔡芳昌,等.固化剂对环氧沥青固化反应动力学的影响研究[J].湖北大学学报(自然科学版),2016,38(2):97-102.
[24] 亢阳,陈志明,闵召辉,等.顺酐化在环氧沥青中的应用[J].东南大学学报(自然科学版),2006,36(2):308-311.
[25] 陆学敏,周威,赵辉,等.沥青接枝马来酸酐相容剂的制备及应用研究[J].胶体与聚合物,2011,29(4):168-170.
[26] 李款,潘友强,张辉,等.钢桥面铺装用环氧沥青相容性研究进展[J].材料导报,2018,32(9):1534-1540.
[27] 晏英,肖新颜,刘武,等.有机蒙脱土/环氧树脂复合改性沥青的性能[J].高分子材料科学与工程,2015,31(4):52-56.
[28] 丁齐齐,郭雅妮,郭蓓,等.基于桐油的环氧沥青增容剂的合成与表征[J].武汉工程大学学报,2018,40(2):180-185.
[29] 崔志强,饶秋华,李瑜,等.环氧树脂增韧固化剂的合成与性能研究[J].热固性树脂,2018,33(2):35-38.
[30] Hu K,Bao L,Chen X,et al.Synthesis of castor oil-derived decanediamide as a novel flexible asphalt-modified epoxy resin curing agent[J].Advances in Polymer Technology,2018,37(4):1092-1098.
[31] Jiang L,Hu K,Liu Z,et al.Aliphatic diamide as novel asphalt-modified epoxy curing agent for enhanced performance[J].Advances in Polymer Technology,2018,37(3):830-836.
[32] Zhou W,Xia Y,Tsai F C,et al.Effects of compound curing agent on the thermo-mechanical properties and structure of epoxy asphalt[J].International Journal of Pavement Engineering,2016,18(10):928-936.
[33] Gao M,Xue Y,Guan P,et al.Influence mechanism of epoxy resin and curing agent on high-temperature performance of asphalt[J].Sains Malaysiana,2020,49(3):661-669.
[34] Zeng G,Xu W,Huang H,et al.Study on the microstructure and properties of hot-mix epoxy asphalt[J].International Journal of Pavement Research and Technology,2019,12(2):147-153.
[35] 王朝辉,傅一,陈谦,等.环氧沥青混凝土桥面铺装材料研究与应用进展[J].材料导报,2018,32(17):2992-3009.
[36] 刘晓文,张肖宁.日本TAF环氧沥青混凝土在桥面铺装中的应用[J].筑路机械与施工机械化,2010,27(1):69-71.
[37] 李笑尘.短期固化环氧沥青材料的制备和性能研究[D].南京:东南大学,2015.
[38] 赵多能.聚氨酯—环氧树脂改性沥青制备及性能研究[D].西安:长安大学,2018.
[39] 杨洋.环氧树脂基类玻璃高分子(Vitrimer)复合材料[D].北京:清华大学,2017.
[40] 魏亭亭.热塑性聚酯/环氧Vitrimer共混物的制备及性能研究[D].北京:北京化工大学,2019.
[41] Denissen W,Winne J M,Du Prez F E.Vitrimers:permanent organic networks with glass-like fluidity[J].Chemical Science,2016,7(1):30-38.
[42] Yang Y,Xu Y,Ji Y,et al.Functional epoxy vitrimers and composites[J].Progress in Materials Science,2020:100710.

基金资助

材料工程重庆市研究生联合培养基地基金项目(201907)

AI Summary AI Mindmap
PDF

717

访问

0

被引

导航
相关文章

AI思维导图

/