某低温工程采用模块化的结构单元进行绝热保温处理,需采用具有良好耐低温性能与粘接性能的胶粘剂将绝热结构单元进行粘接,选用聚氨酯胶粘材料。通过人工加速老化的方法对所选用的聚氨酯胶粘材料进行加热老化实验,对材料的拉伸强度随老化时间、老化温度等因素的变化及性能退化趋势进行研究分析,并应用阿累尼乌斯图对聚氨酯胶粘材料进行寿命预测。研究结果表明,该材料满足设计所需的寿命要求。
A cryogenic engineering used modular structure unit as heat thermal insulation application.It was necessary to use the adhesive with good low temperature resistance and bonding performance for bonding the adiabatic structure unit.A polyurethane(PU) adhesive material was used.The heat aging tests of the material were carried out by the artificial accelerated aging.The variation and performance degradation trend of the material's tensile strength with aging time and aging temperature were studied and analyzed.The life prediction of the selected type of the material was made by using the Arrhenius diagram.The results shown that it can meet the design life requirements.
[1] 韩孝族,郭凤春.GH-01超低温胶粘剂的性能[J].中国胶粘剂,2000,9(5):13-15.
[2] 张在新.化工产品手册粘合剂[M].北京:化学工业出版社,1999:88.
[3] 陈根座.胶粘应用手册[M].北京:电子工业出版社,1994:390.
[4] 朱长春,吕国会.中国聚氨酯产业现状及“十三五”发展规划建议[J].聚氨酯工业,2015,30(3):1-25.
[5] 刘京丽,代德伟,路国忠.墙体保温材料及体系与政策分析[J].新型建筑材料,2013,40(12):46-51.
[6] 化工部合成材料研究院.聚合物防老化实用手册[M].北京:化学工业出版社,1999.
[7] 黄丽.高分子材料[M].北京:化学工业出版社,2009.
[8] Sirirat J B,Chusaksr,Pitt S,et al.Effects of thermal aging on properties and pyrolysis products of tire tread compound[J].Journal of Analytical and Applied Pyrolysis,2007,80(1):269-276.
[9] Wang Y M,LiuL,Luo Y F,et al.Aging behavior and thermal degradation of fluoric elastomeric reactive blend with polyphenol hydroxyl EPDM[J].Polymer Degradation and Stability,2009,94:443-449.
[10] 黄伟,黄大明,姚起宏.塑料老化性能及使用寿命预测的新方法[J].中国塑料,2003,17(6):56-58.
[11] 马丽婷,陈新文,苏彬.航空有机玻璃老化研究进展[J].材料工程,2004(8):57-59.
[12] Zhao Q L,Li X G,Gao J.Aging of ethylene-propylene-dine monomer (EPDM) in artificial weathering environment[J].Polymer Degradation and Stability,2007,92(10):1841-1846.
[13] Song D D,Gao J,Li X G,et al.Evaluation of aging behavior of poly propylene in natural environment by principal component analysis[J].Polymer Testing,2014,33:131-137.
[14] Davies P,Evrard G.Accelerated aging of polyurethanes for marine applications[J].Polymer Degradation and Stability,2007,92(8):1455-1466.
[15] Blanco L,Abate L,Antonelli M L.The regression of isothermal thermogravimetric data to evaluate degradation Ea values of polymers:a comparison with literature methods and an evaluation of lifetime predictions reliability.part Ⅱ[J].Polymer Degradation and Stability,2013,98(11):2291-2296.
[16] 余超,文庆珍,朱金华.特种氯丁橡胶在热空气及热海水中的老化与使用寿命预测[J].高分子材料科学与工程,2011,27(4):37-39.