光催化下载铜凝胶对水体中六价铬离子的吸附及原位还原

李晶昌1,2, 黄菊梅1,2, 党文文1,2, 邢建宇1,2*

化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 216 -221.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 216-221. DOI: 10.19817/j.cnki.issn1006-3536.2022.02.043
科学研究

光催化下载铜凝胶对水体中六价铬离子的吸附及原位还原

    李晶昌1,2, 黄菊梅1,2, 党文文1,2, 邢建宇1,2*
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Adsorption and in-situ reduction of Cr(Ⅵ) in water by copper-loaded hydrogel under the illumination

  • Li Jingchang1,2, Huang Jumei1,2, Dang Wenwen1,2, Xing Jianyu1,2
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摘要

分别以二水氯化铜(CuCl2·2H2O)和过硫酸铵(APS)为氧化剂,将聚吡咯(PPy)均匀地分散到明胶/壳聚糖(Gel/CS)基质中,制备出了Gel/CS/PPy-C和Gel/CS/PPy-A光敏感复合水凝胶,用扫描电子显微镜(SEM)、傅里叶变换红外光谱(FT-IR)和紫外-可见光谱(UV-Vis)对材料结构进行了表征,并考察了材料用于Cr(Ⅵ)的吸附及原位还原的能力。结果表明:经过NaBH4还原处理后,Gel/CS/PPy-C复合水凝胶对Cr(Ⅵ)表现出更高的吸附能力及原位还原率。此外,制备出的材料表现出优良的光敏感性,通过光照可增强材料对Cr(Ⅵ)的原位还原。

Abstract

The Gel/CS/PPy-C and Gel/CS/PPy-A composite hydrogels with light-sensitive performance were prepared by uniformly dispersing the polypyrrole (PPy) into the gelatin/chitosan (Gel/CS) matrix,and using copper chloride dihydrate (CuCl2·2H2O) and ammonium persulfate (APS) as oxidants.The structure of the hydrogels was characterized by scanning electron microscopy (SEM),fourier transform infrared spectroscopy (FT-IR) and ultraviolet visible spectroscopy (UV-Vis).The adsorbed and in situ reduction Cr(Ⅵ) ability of the hydrogels were also investigated.The results showed that after NaBH4 reduction treatment,Gel/CS/PPy-C composite hydrogel showed higher adsorption capacity and in-situ reduction rate of Cr (Ⅵ).In addition,the prepared materials showed excellent photosensitivity,and the in-situ reduction of Cr(Ⅵ) could be enhanced by illumination.

关键词

原位还原 / 光敏感 / 聚吡咯 / Cr(Ⅵ)

Key words

in situ reduction / light sensitive / polypyrrole / Cr(Ⅵ)

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光催化下载铜凝胶对水体中六价铬离子的吸附及原位还原[J]. 化工新型材料, 2022, 50(2): 216-221 DOI:10.19817/j.cnki.issn1006-3536.2022.02.043

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基金资助

陕西省自然科学基础研究计划资助项目(2020JM-226);中央高校基本科研业务费专项资金(310829161015)

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