Cr掺杂尖晶石型LiMn2O4正极材料的研究进展

陶扬1,2, 罗宇旭1,2, 刘清1,2, 刘晓芳1,2*, 向明武1,2, 郭俊明1,2

化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 74 -80.

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化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 74-80. DOI: 10.19817/j.cnki.issn1006-3536.2022.02.015
综述与专论

Cr掺杂尖晶石型LiMn2O4正极材料的研究进展

    陶扬1,2, 罗宇旭1,2, 刘清1,2, 刘晓芳1,2*, 向明武1,2, 郭俊明1,2
作者信息 +

Research progress on Cr doped spinel LiMn2O4 cathode material

  • Tao Yang1,2, Luo Yuxu1,2, Liu Qing1,2, Liu Xiaofang1,2, Xiang Mingwu1,2, Guo Junming1,2
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文章历史 +
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摘要

尖晶石型LiMn2O4具有原料丰富、价格低廉,安全无毒等优点,因而受到研究者的广泛关注。综述了近20年来Cr掺杂尖晶石型LiMn2O4正极材料的研究进展,包括Cr掺杂尖晶石型LiMn2O4的机理、Cr掺杂量对LiMn2O4结构的影响、Cr单元掺杂及Cr与其他元素复合掺杂对LiMn2O4电化学性能的影响,并展望Cr掺杂LiMn2O4的发展前景。

Abstract

The spinel LiMn2O4 has attracted much attention for the advantages of abundant raw materials,low price,safety and non-toxic.The research progress of chromium (Cr) doped spinel LiMn2O4 cathode anode materials in recent 20 years was reviewed,including the mechanism of Cr doped spinel LiMn2O4,Influence of Cr doping amount on LiMn2O4 structure,the effects of single/complex Cr doping on the electrochemical performance.

关键词

锰酸锂 / Cr掺杂 / 正极材料 / 尖晶石型 / 锂离子电池

Key words

LiMn2O4 / chromium doping / anode doping / spinel type / lithium-ion battery

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Cr掺杂尖晶石型LiMn2O4正极材料的研究进展[J]. 化工新型材料, 2022, 50(2): 74-80 DOI:10.19817/j.cnki.issn1006-3536.2022.02.015

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参考文献

[1] Wu C,Wang Z,Wu F,et al.Spectroscopic studies on cation-doped spinel LiMn2O4 for lithium ion batteries[J].Solid State Ionics,2001,144(3-4):277-285.
[2] Molenda J,Marzec J,S′wiperczek K,et al.The effect of 3d substitutions in the manganese sublattice on the charge transport mechanism and electrochemical roperties of manganese spinel[J].Solid State Ionics,2004,171(3-4):215-227.
[3] Yoshio M,Xia Y,Kumada N,et al.Storage and cycling performance of Cr-modified spinel at elevated temperatures[J].Journal of Power Sources,2001,101:79-85.
[4] Kaneko M,Matsuno S,Miki T,et al.Local structural studies of LiCryMn2-yO4 cathode materials for Li-ion batteries[J].Journal of Physical Chemistry B,2003,107:1727-1733.
[5] Şahan H,Göktepe H,Patat Ş,et al.Effect of the Cr2O3 coating on electrochemical properties of spinel LiMn2O4 as a cathode material for lithium battery applications[J].Solid State Ionics,2010,181(31-32):1437-1444.
[6] Yu Y,Xiang M,Guo J,et al.Enhancing high-rate and elevated-temperature properties of Ni-Mg co-doped LiMn2O4 cathodes for Li-ion batteries[J].Journal of Colloid and Interface Science,2019,555:64-71.
[7] Duan Y,Guo J,Xiang M,et al.Single crystalline polyhedral LiNixMn2-xO4 as high-performance cathodes for ultralong cycling lithium-ion batteries[J].Solid State Ionics,2018,326:100-109.
[8] Du K,Xie J,Wang J,et al.LiMn2-xCrxO4 spinel prepared by a modified citrate route with combustion[J].Journal of Power Sources,2003,119-121:130-133.
[9] Wang S,Liu H,Xiang M,et al.Improved electrochemical properties and kinetics of an LiMn2O4-based cathode co-modified via Cu doping with truncated octahedron morphology[J].New Journal of Chemistry,2020,44(25):10569-10577.
[10] Liu J,Bai H,Guo J.Electrochemical performance evaluations of spinel LiAl0.15Mn1.85O4 cathode materials prepared by a solution combustion technique for lithium-ion batteries[J].International Journal of Electrochemical Science,2018,13:6373-6387.
[11] Sun Y,Xia Y,Noguchi H.The improved physical and electrochemical performance of LiNi0.35Co0.3-xCrxMn0.35O2 cathode materials by the Cr doping for lithium ion batteries[J].Journal of Power Sources,2006,159(2):1377-1382.
[12] Song H,Zhao Y,Niu Y,et al.Applications of LiCrxMn2-xO4 cathode material with high capacity and high rate in high-temperature battery[J].Solid State Ionics,2018,325:67-73.
[13] 梁慧新,张英杰,张雁南,等.尖晶石LiMn2O4的掺杂工艺研究进展[J].化工新型材料,2016,44(5):6-9.
[14] 郑子山,唐子龙,张中太,等.锂离子电池正极材料LiMn2O4的研究进展[J].无机材料学报,2003,18(2):257-263.
[15] 李峰,赵铭姝,宋晓平.尖晶石型锰酸锂掺镍研究进展[J].电池,2006,36(1):80-81.
[16] Yi T,Shu J,Zhu Y,et al.Advanced electrochemical performance of LiMn1.4Cr0.2Ni0.4O4 as 5V cathode material by citric-acid-assisted method[J].Journal of Physics & Chemistry of Solids,2009,70(1):153-158.
[17] Park S,Eoma W,Cho W,et al.Electrochemical properties of LiNi0.5Mn1.5O4 cathode after Cr doping[J].Journal of Power Sources,2006,159:679684.
[18] Xu W,Yuan A,Tian L,et al.Improved high-rate cyclability of sol-gel derived Cr-doped spinel LiCryMn2-yO4 in an aqueous electrolyte[J].Journal of Applied Electrochemistry,2011,41(4):453-460.
[19] Su Y,Zou Q,Wang Y,et al.Structure and electrochemical behavior of LiCryMn2-yO4 compositions[J].Materials Chemistry & Physics,2004,84(2-3):302-307.
[20] Taniguchi I.Physical and electrochemical properties of spherical nanostructured LiCrxMn2-xO4 particles synthesized by ultrasonic spray pyrolysis[J].Industrial & Engineering Chemistry Research,2005,44:6560-6565.
[21] Thirunakaran R,Kim K,Kang Y,et al.Adipic acid assisted,sol-gel route for synthesis of LiCrxMn2-xO4 cathode material[J].Journal of Power Sources,2004,137(1):100-104.
[22] Thirunakaran R,Kim K,Kang Y,et al.Cr3+ modified LiMn2O4 spinel intercalation cathodes through oxalic acid assisted sol-gel method for lithium rechargeable batteries[J].Materials Research Bulletin,2005,40(1):177-186.
[23] 雷建清,徐华蕊,朱归胜,等.Cr3+掺杂锰酸锂薄膜电极的溶胶-凝胶制备方法[J].中国科技论文,2017,12(16):1866-1870.
[24] Fu Y,Su Y,Lin C.Comparison of microwave-induced combustion and solid-state reaction for synthesis of LiMn2-xCrxO4 powders and their electrochemical properties[J].Journal of Materials Science,2006,166(1-2):137-146.
[25] 崔永丽,庞娟,王秋分,等.掺Cr尖晶石LiCrxMn2-xO4材料EIS研究[J].电池工业,2010,15(5):279-283.
[26] Jiang J,Li W,Deng H,et al.Research on improving the electrochemical performance of LiMn2O4 via Cr-doping[J].Journal of Nanoence and Nanotechnology,2019,19(1):125-129.
[27] 周巧,李学良,尤亚华,等.铬掺杂锰酸锂的正极材料离子热法制备及其性能[J].无机盐工业,2015,47(4):62-64.
[28] Amarilla J,Rojas R,Pico F,et al.Nanosized LiMyMn2-yO4(M=Cr,Co and Ni) spinels synthesized by a sucrose-aided combustion method Structural characterization and electrochemical properties[J].Journal of Power Sources,2007,174(2):1212-1217.
[29] Gu H,Wang G,Zhu C,et al.Correlating cycle performance improvement and structural alleviation in LiMn2-xMxO4 spinel cathode materials:a systematic study on the effects of metal-ion doping[J].Electrochimica Acta,2018,298:806-817.
[30] 罗学英,张国欣,向明武,等.燃烧温度对尖晶石型LiCr0.05Mn1.95O4正极材料电化学性能的影响[J].化工新型材料,2020,48(11):147-151,157.
[31] Jiang Q,Hu G,Peng Z,et al.Preparation of spherical spinel LiCr0.04Mn1.96O4 cathode materials based on the slurry spray drying method[J].Rare Metals,2009,6(28):618-623.
[32] Song G,Wang Y,Zhou Y.Synthesis and electrochemical performance of LiCrxMn2-xO4 powders by mechanical activation and rotary heating[J].Journal of Power Sources,2004,128(2):270-277.
[33] Iqbal A,Iqbal Y,Khan A,et al.Low content Ni and Cr co-doped LiMn2O4 with enhanced capacity retention[J].Ionics,2017,23(8):1995-2003.
[34] Kulova T,Karseeva E,Skundin A,et al.Structure and electrochemical behavior of lithium-manganese spinels doped with chromium and nickel[J].Russian Journal of Electrochemistry,2004,40(5):494-499.
[35] 罗学英,李燕,郭俊明,等.熔盐燃烧合成LiNi0.01CrxMn1.99-xO4(x≤0.07)正极材料及电化学性能[J].高校化学工程学报,2020,34(4):1060-1068.
[36] Sakunthala A,Reddy M,Selvasekarapandian S,et al.Synthesis of compounds,Li(MMn11/6)O4(M=Mn1/6,Co1/6,(Co1/12Cr1/12),(Co1/12Al1/12),(Cr1/12Al1/12)) by polymer precursor method and its electrochemical performance for lithium-ion batteries[J].Electrochimica Acta,2010,55(15):4441-4450.
[37] Iqbal A,Iqbal Y,Khan A,et al.Effect of bication (Cu-Cr) substitution on the structure and electrochemical performance of LiMn2O4 spinel cathodes at low and high current rates[J].Journal of Saudi Chemical Society,2018,22(4):449-458.
[38] Peng Z,Jiang Q,Du K,et al.Effect of Cr-sources on performance of Li1.05Cr0.04Mn1.96O4 cathode materials prepared by slurry spray drying method[J].Journal of Alloys & Compounds,2010,493(1-2):640-644.
[39] Liang X,Zeng S,Liu Y,et al.Enhance cycling performance of LiMn2O4 cathode by Sr2+ and Cr3+ doping[J].Materials Science & Technology,2015,31(4):443-447.
[40] Xie Y,Yang R,Yan L,et al.Synthesis and electrochemical characterization of Li1.05SrxCryMn2-x-yO4 spinel as cathode material for rechargeable Li-battery[J].Journal of Power Sources,2007,168(1):272-277.
[41] Bao S,Zhou W,Liang Y,et al.Enhancement of the electrochemical properties of LiMn2O4 through chemical substitution[J].Materials Chemistry & Physics,2006,95(1):188-192.
[42] 姚耀春,戴永年,杨斌,等.F-Cr复合掺杂LiMn2O4的合成及性能研究[J].电池,2005(6):411-413.
[43] 禹筱元,余仕禧,周武艺,等.复合掺杂改性LiMn2-xCrxO4-3xF3x正极材料的制备及性能[J].硅酸盐学报,2010,38(6):1053-1058.

基金资助

国家自然科学基金(U1602273和51972282)

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