二氧化钛光催化自清洁材料研究进展

丁晓红1,2, 刘瑞来1*, 赵瑨云1, 胡家朋1, 林皓1, 付兴平1, 刘俊劭1

化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 68 -73.

PDF
化工新型材料 ›› 2022, Vol. 50 ›› Issue (2) : 68-73. DOI: 10.19817/j.cnki.issn1006-3536.2022.02.014
综述与专论

二氧化钛光催化自清洁材料研究进展

    丁晓红1,2, 刘瑞来1*, 赵瑨云1, 胡家朋1, 林皓1, 付兴平1, 刘俊劭1
作者信息 +

Progress on photocatalytic TiO2 for self-cleaning

  • Ding Xiaohong1,2, Liu Ruilai1, Zhao Jinyun1, Hu Jiapeng1, Lin Hao1, Fu Xingping1, Liu Junshao1
Author information +
文章历史 +
PDF

摘要

自清洁材料可将表面附着的污染物在自然外力和外界能力的作用下,将材料表面的污染物去除。TiO2是一种半导体金属氧化物,且具有TiO2独特的光诱导超亲水性质以及光催化降解有机物的特性,是一种理想的光催化自清洁材料。介绍了基于TiO2的自清洁材料,包括TiO2光诱导自清洁、TiO2光催化自清洁和TiO2复合光催化材料并进行了总结和展望。

Abstract

Self-cleaning materials can wipe off surface stains under the natural power or external forces.As one of the semiconductors,TiO2 has unique photoinduced superhydrophilic property and photocatalytic property,and it is an ideal photocatalytic self-cleaning material.TiO2-based self-cleaning materials were introduced.These include photoinduced TiO2 self-cleaning materials,TiO2 photocatalytic self-cleaning materials,and TiO2 composite photocatalytic materials.Last,a conclusion and outlook were made.

关键词

二氧化钛 / 自清洁 / 光催化 / 超疏水性

Key words

titanium dioxide / self-cleaning / photocatalyticity / superhydrophobicity

引用本文

引用格式 ▾
二氧化钛光催化自清洁材料研究进展[J]. 化工新型材料, 2022, 50(2): 68-73 DOI:10.19817/j.cnki.issn1006-3536.2022.02.014

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] Zhou P,Lv J,Xu H,et al.Functionalization of cotton fabric with bismuth oxyiodide nanosheets:applications for photodegrading organic pollutants,UV shielding and self-cleaning[J].Cellulose,2019,26(4):2873-2884.
[2] Peng S,Meng W,Guo J,et al.Photocatalytically stable superhydrophobic and translucent coatings generated from PDMS-grafted-SiO2/TiO2@PDMS with multiple applications[J].Langmuir,2019,35(7):2760-2771.
[3] Yang J,Wang G,Wang D,et al.A self-cleaning coating material of TiO2 porous microspheres/cement composite with high-efficient photocatalytic depollution performance[J].Materials Letters,2017,200:1-5.
[4] La Russa M F,Rovella N,Alvarez de Buergo M,et al.Nano-TiO2 coatings for cultural heritage protection:the role of the binder on hydrophobic and self-cleaning efficacy[J].Progress in Organic Coatings,2016,91:1-8.
[5] Banerjee S,Dionysiou D D,Pillai S C.Self-cleaning applications of TiO2 by photo-induced hydrophilicity and photocatalysis[J].Applied Catalysis B:Environmental,2015,176-177:396-428.
[6] Lu Yao,Sathasivam Sanjayan,Song Jinlong,et al.Robust self-cleaning surfaces that function when exposed to either air or oil[J].Science,2015,347(6226):1132-1135.
[7] Yuekun Lai Y T,Gong J J,Gong D G,et al.Transparent FAS superhydrophobic-superhydrophilic TiO2-based coatings for self-cleaning and anti-fogging[J].Journal of Materials Chemistry,2012,22:7420-7426.
[8] Quagliarini E,Bondioli F,Goffredo G B,et al.Self-cleaning and de-polluting stone surfaces:TiO2 nanoparticles for limestone[J].Construction & Building Materials,2012,37(3):51-57.
[9] Yin Y,Zhang Y,Ji X,et al.Facile fabrication of photoinduced superhydrophobic-superhydrophilic surfaces on cellulose substrate without strength loss[J].Textile Research Journal,2018,89(9):1807-1822.
[10] Drelich J,Chibowski E,Meng D D,et al.Hydrophilic and superhydrophilic surfaces and materials[J].Soft Matter,2011,7(21):9804-9828.
[11] Arturi K R,Jepsen H,Callsen J N,et al.Superhydrophilicity and durability of fluoropolymer-TiO2 coatings[J].Progress in Organic Coatings,2016,90:132-138.
[12] Wang S P,Wang Y C,Li X X,et al.A non-fluorine method for preparing multifunctional robust superhydrophobic coating with applications in photocatalysis,flame-retardance,and oil-water separation[J].New Journal Chemistry,2019,30:132-141.
[13] Lin J,Zheng C,Ye W J,et al.A facile dip-coating approach to prepare SiO2/fluoropolymer coating for superhydrophobic and superoleophobic fabrics with self-cleaning property[J].Journal of Applied Polymer Science,2015,132(1):912-918.
[14] Wang Y,Huang Z,Gurney R S,et al.Superhydrophobic and photocatalytic PDMS/TiO2 coatings with environmental stability and multifunctionality[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2019,561:101-108.
[15] Nobuaki Negishia Y M,Shigekazu Katob,Yang Yingnan.Effect of HCO-3 concentration in groundwater on TiO2 photocatalytic water purification[J].Applied Catalysis B:Environmental,2019,242:449-459.
[16] Pelaez M,Nolan N T,Pillai S C,et al.A review on the visible light active titanium dioxide photocatalysts for environmental applications[J].Applied Catalysis B:Environmental,2012,125:331-349.
[17] Hernandez-Alonso M D,Fresno F,Suarez S,et al.Development of alternative photocatalysts to TiO2:challenges and opportunities[J].Energy & Environmental Science,2009,2(12):1231-1257.
[18] Wang R,Hashimoto K,Fujishima A,et al.,Light-induced amphiphilic surfaces[J].Nature,1997,388(6641):431-432.
[19] Wang K H,Akira F,Makoto C,et al.Photogeneration of highly amphiphilic TiO2 surfaces[J].Advanced Materials,1998,20(2):135-138.
[20] Nakajima A,Koizumi S,Watanabe T,et al.Effect of repeated photo-illumination on the wettability conversion of titanium dioxide[J].Journal of Photochemistry and Photobiology A:Chemistry,2001,146(1):129-132.
[21] Wang R,Sakai N,Fujishima A,et al.Studies of surface wettability conversion on TiO2 single-crystal surfaces[J].The Journal of Physical Chemistry B,1999,103(12):2188-2194.
[22] Nobuyuki A F,Toshiya Watanabe,Kazuhito Hashimoto.Quantitative evaluation of the photoinduced hydrophilic conversion properties of TiO2 thin film surfaces by the reciprocal of contact angle[J].Journal of Physics and Chemistry B,2003,107:1028-1035.
[23] Nobuyuki A F,Toshiya W,Kazuhito H.Enhancement of the photoinduced hydrophilic conversion rate of TiO2 film electrode surfaces by anodic polarization[J].Journal of Physical Chemistry B,2001,105:3023-3026.
[24] Yan X,Abe R,Ohno T,et al.Action spectrum analyses of photoinduced superhydrophilicity of titania thin films on glass plates[J].Thin Solid Films,2008,516(17):5872-5876.
[25] Zubkov T,Stahl D,Thompson T L,et al.Ultraviolet light-induced hydrophilicity effect on TiO2(110)(1×1).dominant role of the photooxidation of adsorbed hydrocarbons causing wetting by water droplets[J].The Journal of Physical Chemistry B,2005,109(32):15454-15462.
[26] Guan K.Relationship between photocatalytic activity,hydrophilicity and self-cleaning effect of TiO2/SiO2 films[J].Surface and Coatings Technology,2005,191(2-3):155-160.
[27] Emeline A V,Rudakova A V,Sakai M,et al.Factors affecting UV-induced superhydrophilic conversion of a TiO2 surface[J].The Journal of Physical Chemistry C,2013,117(23):12086-12092.
[28] Parkin I P,Palgrave R G.Self-cleaning coatings[J].Journal of Materials Chemistry,2005,15(17):1689-1695.
[29] Liu R L,Ye H Y,Xiong X P,et al.Fabrication of TiO2/ZnO composite nanofibers by electrospinning and their photocatalytic property[J].Materials Chemistry and Physics,2010,121(3):432-439.
[30] Qu Y,Duan X.Progress,challenge and perspective of heterogeneous photocatalysts[J].Chemical Society Reviews,2013,42(7):2568-2580.
[31] Sassoni E,D'Amen E,Roveri N,et al.Durable self-cleaning coatings for architectural surfaces by incorporation of TiO2 nano-particles into hydroxyapatite films[J].Materials,2018,11(2):177.
[32] Gole J L,Burda C,Fedorov A,et al.Highly efficient formation of TiO2-XNX-based photocatalysts-potential applications for active sites in microreactors,sensors,and photovoltaics[J].MRS Proceedings,2011,789:123-129.
[33] Pelaez M,Baruwati B,Varma R S,et al.Microcystin-LR removal from aqueous solutions using a magnetically separable N-doped TiO2 nanocomposite under visible light irradiation[J].Chemical Communications,2013,49(86):10118-10120.
[34] Huang Y,Ho W,Lee S,et al.Effect of carbon doping on the mesoporous structure of nanocrystalline titanium dioxide and its solar-light-driven photocatalytic degradation of NOx[J].Langmuir,2008,24(7):3510-3516.
[35] Mohapatra S K,Misra M,Mahajan V K,et al.Design of a highly efficient photoelectrolytic cell for hydrogen generation by water splitting:application of TiO2-xCx nanotubes as a photoanode and Pt/TiO2 nanotubes as a cathode[J].The Journal of Physical Chemistry C,2007,111(24):8677-8685.
[36] Hussain S T,Khan K,Hussain R.Size control synthesis of sulfur doped titanium dioxide (anatase) nanoparticles,its optical property and its photo catalytic reactivity for CO2+H2O conversion and phenol degradation[J].Journal of Natural Gas Chemistry,2009,18(4):383-391.
[37] Reszczynska J,Grzyb T,Sobczak J W,et al.Visible light activity of rare earth metal doped (Er3+,Yb3+ or Er3+/Yb3+) titania photocatalysts[J].Applied Catalysis B:Environmental,2015,163:40-49.
[38] Weng K W,Huang Y P.Preparation of TiO2 thin films on glass surfaces with self-cleaning characteristics for solar concentrators[J].Surface and Coatings Technology,2013,231:201-204.
[39] Linic S,Christopher P,Ingram D B.Plasmonic metal nanostructures for efficient conversion of solar to chemical energy[J].Nature Materials,2011,10(12):911-921.
[40] Cong Y,Zhang J,Chen F,et al.Preparation,photocatalytic activity,and mechanism of nano-TiO2 Co-doped with nitrogen and iron (Ⅲ)[J].The Journal of Physical Chemistry C,2007,111(28):10618-10623.
[41] Zhang M,Chen C,Ma W,et al.Visible-light-induced aerobic oxidation of alcohols in a coupled photocatalytic system of dye-sensitized TiO2 and TEMPO[J].Angewandte Chemie International,2008,47(50):9730-9733.
[42] Etacheri V,Michlits G,Seery M K,et al.A highly efficient TiO2-xCx nano-heterojunction photocatalyst for visible light induced antibacterial applications[J].ACS Applied Materials & Interfaces,2013,5(5):1663-1672.
[43] Shin S W,Kim B S,Choi G H,et al.Double-templated electrodeposition:simple fabrication of micro-nano hybrid structure by electrodeposition for efficient boiling heat transfer[J].Applied Physics Letters,2012,101(25):251909.1-251909.5.
[44] Lin M Y,Jeong H,Chang M,et al.Durable superhydrophilic coatings formed for anti-biofouling and oil-water separation[J].Journal of Membranes Science,2016,506:22-30.
[45] Novotna P,Zita J,Krysa J,et al.Two-component transparent TiO2/SiO2 and TiO2/PDMS films as efficient photocatalysts for environmental cleaning[J].Applied Catalysis B:Environmental,2008,79(2):179-185.
[46] Younas H,Bai H,Shao J,et al.Super-hydrophilic and fouling resistant PVDF ultrafiltration membranes based on a facile prefabricated surface[J].Journal of Membrane Science,2017,541:529-540.
[47] Kapridaki C,Maravelaki-Kalaitzaki P.TiO2-SiO2-PDMS nano-composite hydrophobic coating with self-cleaning properties for marble protection[J].Progress in Organic Coatings,2013,76(2-3):400-410.
[48] Li Q,Shang J K.Composite photocatalyst of nitrogen and fluorine codoped titanium oxide nanotube arrays with dispersed palladium oxide nanoparticles for enhanced visible light photocatalytic performance[J].Environmental Science & Technology,2010,44(9):3493-3499.
[49] Asahi R,Morikawa T,Ohwaki T,et al.Visible-light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293(5528):269-276.
[50] Qu Y,Song S,Jing L,et al.Effects of the co-addition of Zn2+ and sodium dodecylbenzenesulfonate on photocatalytic activity and wetting performance of anatase TiO2 nanoparticle films[J].Thin Solid Films,2010,518(12):3177-3181.
[51] Russa M F,Ruffolo S A,Rovella N,et al.Multifunctional TiO2 coatings for cultural heritage[J].Progress in Organic Coatings,2012,74(1):186-191.
[52] Xu F,Wang T,Bohling J,et al.Extended hydrophobicity and self-cleaning performance of waterborne PDMS/TiO2 nanocomposite coatings under accelerated laboratory and outdoor exposure testing[J].Journal of Coatings Technology and Research,2018,15(5):1025-1034.
[53] Ding X,Pan S,Lu C,et al.Hydrophobic photocatalytic composite coatings based on nano-TiO2 hydrosol and aminopropyl terminated polydimethylsiloxane prepared by a facile approach[J].Materials Letters,2018,21:123-129.
[54] Xu Q F,Liu Y,Lin F J,et al.Superhydrophobic TiO2-polymer nanocomposite surface with UV-induced reversible wettability and self-cleaning properties[J].ACS Applied Materials and Interfaces,2013,5(18):8915-24.
[55] Crick C R,Bear J C,Kafizas A,et al.Superhydrophobic photocatalytic surfaces through direct incorporation of titania nanoparticles into a polymer matrix by aerosol assisted chemical vapor deposition[J].Advanced Materials,2012,24(26):3505-3508.
[56] Crick C R,Ismail S,Pratten J,et al.An investigation into bacterial attachment to an elastomeric superhydrophobic surface prepared via aerosol assisted deposition[J].Thin Solid Films,2011,519(11):3722-3727.
[57] Tettey K E,Dafinone M I,Lee D.Progress in superhydrophilic surface development[J].Materials Express,2011,1(2):89-104.
[58] Crick C R,Parkin I P.Superhydrophobic polymer films via aerosol assisted deposition-taking a leaf out of nature's book[J].Thin Solid Films,2010,518(15):4328-4335.
[59] Jiang C,Liu W,Yang M,et al.Robust fabrication of superhydrophobic and photocatalytic self-cleaning cotton textiles for oil-water separation via thiol-ene click reaction[J].Journal of Materials Science,2019,54(9):7369-7382.
[60] Jia S,Lu Y,Luo S,et al.Thermally-induced all-damage-healable superhydrophobic surface with photocatalytic performance from hierarchical BiOCl[J].Chemical Engineering Journal,2019,366:439-448.
[61] Jiang C,Liu W,Yang M,et al.Robust multifunctional superhydrophobic fabric with UV induced reversible wettability,photocatalytic self-cleaning property,and oil-water separation via thiolene click chemistry[J].Applied Surface Science,2019,463:34-44.
[62] Zhang X,Liu S,Salim A,et al.Hierarchical structured multifunctional self-cleaning material with durable superhydrophobicity and photocatalytic functionalities[J].Small,2019,15(34):e1901822.
[63] Tian X,Chen Q,Song L,et al.Formation of alkali resistant PDMS-TiO2-SiO2 hybrid coatings[J].Materials Letters,2007,61(22):4432-4434.
[64] Kamegawa T,Shimizu Y,Yamashita H.Superhydrophobic surfaces with photocatalytic self-cleaning properties by nanocomposite coating of TiO2 and polytetrafluoroethylene[J].Advanced Materials,2012,24(27):3697-700.
[65] Sanghyuk Wooh N E,Doris Vollmer,Hans-Jürgen Butt.Stable hydrophobic metal-oxide photocatalysts via grafting polydimethylsiloxane brush[J].Advanced Materials,2017,29:1604637.
[66] Ahmed S,Rasul M G,Martens W N,et al.Advances in heterogeneous photocatalytic degradation of phenols and dyes in wastewater:a review[J].Water Air and Soil Pollution,2011,215(1-4):3-29.

基金资助

福建省自然科学基金项目(2019J01829、2019J01830和2018J01518);福建省教育厅项目(JT180550);南平市基金项目(2019J06);武夷学院基金项目(XD201804)

AI Summary AI Mindmap
PDF

520

访问

0

被引

导航
相关文章

AI思维导图

/