水合盐相变储能材料具有化学性质稳定,无刺激性气味,材料来源广泛且价格低廉等优点,有望成为中低温热利用领域理想的储热材料,在实际生活与生产中具有重要的意义。详细介绍了水合盐相变材料的研究发展和最新研究成果,以及解决过冷度和相分离所需成核剂与增稠剂的研究现状,并对水合盐相变储能材料未来的研究重点与方向做出了展望。
Hydrated salt phase change energy storage material (PCM) has excellent properties such as stable chemical properties,no pungent odor,wide material sources and low price.It is expected to be an ideal heat storage material in the field of medium and low temperature thermal utilization,and has important significance in practical life and production.The research and development of hydrated salt PCM and the latest research results were introduced in detail,as well as the research status of nucleating agents and thickeners needed to solve the problem of supercooling and phase separation.The future research emphasis and direction of hydrated salt PCM were forecasted.
[1] Zahir M H,Mohamed S A,Saidur R,et al.Supercooling of phase-change materials and the techniques used to mitigate the phenomenon[J].Applied Energy,2019,240:793-817.
[2] 肖力光,李冰.相变材料在建筑节能领域的应用及研究[J].北方建筑,2019,4(4):51-55.
[3] Mehrali M,Latibari S T,Rosen M A,et al.From rice husk to high performance shape stabilized phase change materials for thermal energy storage[J].RSC Advances,2016,6(51):45595-45604.
[4] Zhu X,Wang Q,Kang S,et al.Coal-based ultrathin-wall graphitic porous carbon for high-performance form-stable phase change materials with enhanced thermal conductivity[J].Chemical Engineering Journal,2020,DOI:10.1016/j.cej.2020.125112.
[5] Rathod M K,Banerjee J.Thermal stability of phase change materials used in latent heat energy storage systems:a review[J].Renewable and Sustainable Energy Reviews,2013,18:246-258.
[6] 张爱军.膨润土基有机复合相变材料性能研究[D].苏州:苏州科技大学,2017.
[7] 王鑫,方建华,刘坪,等.相变材料的研究进展[J].功能材料,2019,50(2):2070-2075.
[8] Zhang Helei,Fang Xie,Zhao Yingjie.Progress in phase change materials and technologies[J].Materials Review,2014,28(7):26-32.
[9] 宗学刚.二氧化硅基复合相变储能材料的制备及热性能研究[D].济南:山东轻工业学院,2010.
[10] Meng Y,Zhao Y,Zhang Y,et al.Induced dipole force driven peg/ppegma form-stable phase change energy storage materials with high latent heat[J].Chemical Engineering Journal,2020,390:124618.
[11] Atinafu D G,Dong W,Berardi U,et al.Phase change materials stabilized by porous metal supramolecular gels:gelation effect on loading capacity and thermal performance[J].Chemical Engineering Journal,2020,394:124806.
[12] Ling T C,Poon C S.Use of phase change materials for thermal energy storage in concrete:an overview[J].Construction & Building Materials,2013,46(8):55-62.
[13] Zhou D,Zhao C Y,Tian Y.Review on thermal energy storage with phase change materials (PCMs) in building applications[J].Applied Energy,2012,92(4):593-605.
[14] Shin H K,Park M,Kim H Y.Thermal property and latent heat energy storage behavior of sodium acetate trihydrate composites containing expanded graphite and carboxymethyl cellulose for phase change materials[J].Applied Thermal Engineering,2015,75(1):978-983.
[15] Carlsson B.Phase change behaviour of some latent heat storage media based on calcium chloride hexahydrate[J].Solar Energy,2009,83(4):485-500.
[16] Huang J,Wang T Y,Zhu P P.Preparation characterization and thermal properties of the microencapsulation ofa hydrated salt as phase change energy storage materials[J].Thermochimica Acta,2013,557:1-6.
[17] Koleva V,Stefov V,Najdoski M.Thermal spectral and microscopic studies of water-rich hydrate of the type Mg2KH(PO4)2·15H2O.thermal transformations[J].Thermochimica Acta,2015,619:20-25.
[18] 朱洪宇.相变复合材料的制备及其导热性能研究[D].兰州:兰州理工大学,2018.
[19] Peng S,Hu Y,Huang J,et al.Surface free energy analysis for stable,supercooling of sodium thiosulfate pentahydrate with microcosmic-visualized methods[J].Solar Energy Materials and Solar Cells,2020,208:110390.
[20] Cabeza L,Castell A,Barreneche C.Materials used as PCM in thermal energy storage in buildings:a review[J].Renewable and Sustainable Energy Reviews,2011,15(3):1675-1695.
[21] Verma P,Singal S.Review of mathematical modeling on latent heat thermal energy storage systems using phase-change material[J].Renewable and Sustainable Energy Reviews,2008,12(4):999-1031.
[22] Farid M M,Khudhair A M,Razack S A K.A review on phase change energy storage:materials and applications[J].Energy Conversion and Management,2004,45(9):1597-1615.
[23] Torii T,Ossaka J.Antarcticite:a new mineral,calcium chloride hexahydrate,discovered in Antarctica[J].Science,1965,149(3687):975-977.
[24] Duan Z J,Zhang H Z,Sun L X.CaCl2·6H2O/expanded graphite composite as form-stable phase change materials for thermal energy storage[J].Journal of Thermal Analysis and Calorimetry,2014,115:111-117.
[25] Dannemand M,Dragsted J,Fan J,et al.Experimental investigations on prototype heat storage units utilizing stable supercooling of sodium acetate trihydrate mixtures[J].Applied Energy,2016,169:72-80.
[26] 张寅平,胡汉平,孔祥冬.相变贮能-理论和应用[M].合肥:中国科学技术大学出版社,1996,138.
[27] 胡起柱,皮启铎,阮德水.Na2SO4·10H2O-NaCl贮热体系的DSC研究[J].太阳能学报,1985,13(1):35-40.
[28] 章旭明.无机盐溶液相变蓄冷特性及系统研究[D].杭州:浙江工业大学,2007.
[29] 陆学善.相图与相变[M].合肥:中国科学技术大学出版社,1990,28.
[30] 郭志强.低温高潜热无机相变材料及其热红外示假性能的研究[D].长沙:国防科学技术大学,2007.
[31] Ryu H W,Woo S W,Shin B C.Prevention of supercooling and stabilization of inorganic salt hydrates as latent heat storage materials[J] Solar Energy Materials and Solar Cells,1992,27(92):161-172.
[32] 何宇.三水醋酸钠过冷度及传热性能的同步优化研究[D].成都:西南交通大学,2018.
[33] Adachi T,Daudah D,Tanaka G.Effects of supercooling degree and specimen size on supercooling duration of erythritol[J].ISIJ International,2014,54:2790-2795.
[34] Dukek W,Grayson M.Kirk-othmer encyclopedia of chemical technology Vol.3[M].New York:John Wiley,1978,328-351.
[35] Fu W,Zou T,Liang X,et al.Thermal properties and thermal conductivity enhancement of composite phase change material using sodium acetate trihydrate-urea/expanded graphite for radiant floor heating system[J].Applied Thermal Engineering,2018,138:618-626.
[36] Xiao Q,Fan J,Li L,et al.Solar thermal energy storage basedon sodium acetate trihydrate phase change hydrogels with excellent light-tothermal conversion performance[J].Energy,2018,165:1240-1247.
[37] Huang R,Feng J,Ling Z,et al.A sodium acetate trihydrateformamide/expanded perlite composite with high latent heat and suitable phase change temperatures for use in building roof[J].Construction and Building Materials,2019,226:859-867.
[38] Fashandi M,Leung S N.Sodium acetate trihydrate-chitin nanowhisker nanocomposites with enhanced phase change performance for thermal energy storage[J].Solar Energy Materials and Solar Cells,2018,178:259-265.
[39] 杨宜凡,顾晓滨,刘鹏.添加剂对三水醋酸钠的储热性能影响研究[J].广州化工,2017,45(19):84-86,92.
[40] 肖力光,李冰.纳米氧化锌改性无机水合盐三元相变材料的研究[J].硅酸盐通报,2020,39(2):616-620.
[41] Lin L,Xi C.Preparation and thermal properties of eutectic hydrate salt phase change thermal energy storage material[J].International Journal of Photoenergy,2018,2018:1-9.
[42] Zhang Y C,Zhang X L,Xu X F.Preparation and characterization of sodium sulfate pentahydrate/sodium pyrophosphate composite phase change energy storage materials[J].Journal of Molecular Liquids,2019,280:360-366.
[43] 孟令然,郭立.水合盐相变储能材料的研究进展[J].储能科学与技术,2017,6(4):623-632.
[44] 杨绪强,潘毅,封银平.十水硫酸钠低共熔混合物储热的实验研究[J].太阳能学报,1982,3(2):212-215.
[45] Elder J P.Thermal energy storage materials-a DSC study[J].Thermochimica Acta,1980,36(1):67-77.
[46] Telkes M.Thixotropic mixture and method of making same[P].US,US3986969,1979-06-12.
[47] Lane G A.Solar heat storage:latent heat material[J].Solar Energy,1984,33(5):476.
[48] Ryu H W,Woo S W,Shin B C,et al.Prevention of supercooling and stabilization of inorganic salt hydrates as latent heat storage materials[J].Solar Energy Materials and Solar Cells,1992,27:161-172.
[49] Cabeza L F,Svensson G,Hiebler S.Thermal performance ofsodium acetate trihydrate thickened with different materials as phasechange energy storage material[J].Applied Thermal Engineering,2003,23(13):1697-1704.
[50] Lan X Z,Tan Z C,Shi Q A.novel gelling method for stabilization of phase change material Na2HPO4·12H2O with sodium alginate grafted sodium acrylate[J].Thermochimica Acta,2007,463(1):18-20.
[51] 谢全安,郑丹星,武向红.Na2SO4·10H2O共晶盐的热化学研究[J].太阳能学报,2002,23(1):70-75.
[52] 陈军.共晶盐蓄冷材料的研制及特性研究[D].上海:上海理工大学,2009.
基金资助
“十三五”国家重点研发计划(2018YFD11010019)
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