开发与应用

MOFs催化剂的设计合成与应用研究进展

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  • 1.贵州大学化学与化工学院,贵阳,550025;
    2.贵州中烟工业有限责任公司技术中心,贵阳,550009;
    3.贵州大学药学院,贵阳,550025
张荣(1992-),男,硕士研究生,主要从事催化剂的合成。

收稿日期: 2019-09-03

  修回日期: 2020-10-03

  网络出版日期: 2021-01-27

基金资助

国家自然科学基金(21562014)

Research progress of design,synthesis and application of MOFs catalyst

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  • 1. School of Chemistry and Chemical Engineering,Guizhou University,Guiyang 550025;
    2. Technology Center,China Tobacco Guizhou Industrial Co.,Ltd.,Guiyang 550009;
    3. School of Medicine,Guizhou University,Guiyang 550025

Received date: 2019-09-03

  Revised date: 2020-10-03

  Online published: 2021-01-27

摘要

根据金属有机框架材料(MOFs)催化剂活性位点的来源不同,将MOFs催化剂分为三大类:(1)MOFs上本身具有配位不饱和的活性金属节点,能够促进反应的进行;(2)形成MOFs的有机配体或者后合成修饰到MOFs上的官能团具有催化活性;(3)MOFs本身不起催化作用,只作为催化剂的载体,起到携带催化剂和阻止催化剂团聚和流失的作用。分别叙述了上述三类MOFs催化剂的合成方法,并对它们在有机反应中的催化活性、重复使用性和选择性等进行总结。

本文引用格式

张荣, 谢有超, 喻昌木, 彭黔荣, 杨敏 . MOFs催化剂的设计合成与应用研究进展[J]. 化工新型材料, 2021 , 49(1) : 223 -228 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.01.049

Abstract

According to the sources of active sites of MOFs,MOFs catalysts are divided into three categories.1.The unsaturated metal nodes on the MOFs is activity,and could promote the reaction;2.The organic formation of MOFs and the functional groups modified in MOFs by post-synthesis have catalytic activity;3.MOFs themselves do not have a catalytic activity,and only serve as a carrier for the catalyst,and function to carry the catalyst and prevent the catalyst losing from MOFs.The synthesis methods of three types of MOFs catalysts were described separately,and summarized their catalytic activities,reusability and selectivity in organic reactions.

参考文献

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