近年来,金属有机骨架材料以其独特的结构及在多个领域的应用得到了人们的广泛关注,其中沸石咪唑酯类骨架材料(ZIF材料)是一类有特殊结构的有机金属骨架材料,多在较高的温度下合成,且具有较好的热稳定性。在室温条件下合成常见的ZIF材料(ZIF-8、ZIF-67、ZIF-90、ZIF-L)不仅可以减少环境污染,同时对ZIF材料的大规模生产应用具有很大的帮助。与此同时,在氮气氛围下对合成的ZIF材料在900℃下进行充分的热解,得到以ZIF材料为模板的衍生碳材料。
Metal-organic framework(MOF) material has attracted great attention because of its unique structures and various applications in many fields in recent years,and zeolite imidazolate framework (ZIF) is a special one of many kinds of MOF.ZIF is mainly synthesized at a pretty high temperature and possess better thermal stability.The synthesis of common ZIF materials (ZIF-8,ZIF-67,ZIF-90,ZIF-L) at room temperature can not only reduce environmental pollution,but also be of great help to the mass production and application of ZIF materials.At the same time,the synthesized ZIF was sufficiently pyrolyzed at 900℃ under the atmosphere of nitrogen,and the derived carbon material using ZIF materials as template was obtained.
[1] 袁艺,李泽晖,王亚玲,等.金属-有机骨架材料对环境中典型苯系物的吸附研究进展[J].化工新型材料,2019,47(8):18-22.
[2] Huang Yuanbiao,Wu Qiao,Liang Jun,et al.Unraveling the relationship between morphologies of metal-organic frameworks and properties of their derived carbon materials[J].Dalton Trans,2019,48(21):7211-7217.
[3] Schneemann A,Bon V,Schwedler I,et al.Flexible metal-organic frameworks[J].Chem Soc Rev,2014,43(16):6062-6096.
[4] 牛照栋,周玲玲,关清卿,等.双金属类MOF材料的制备及应用[J].化工新型材料,2019,47(8):5-8.
[5] Ribeiro,Erick L D,Seyyed A D,et al.Laser-induced synthesis of ZIF-67:a facile approach for the fabrication of crystalline MOFs with tailored size and geometry[J].Materials Chemistry Frontiers,2019,3(7):1302-1309.
[6] 吴雪艳,王开学,陈接胜.多孔碳材料的制备[J].化学进展,2011,24(2):262-274.
[7] Park K S,Ni Z,Cote A P,et al.Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J].PNAS,2006,103(27):10186-10191.
[8] 蒋绍阶,王洪武.磁性金属有机骨架Fe3O4@ZIF-8的制备及对偶氮染料刚果红的高效吸附[J].环境工程学报,2019,13(10):2347-2356.
[9] Zhang Huifeng,Liu Defei,Yao Ying,et al.Stability of ZIF-8 membranes and crystalline powders in water at room temperature[J].Journal of Membrane Science,2015,485:103-111.
[10] Jia Bingying,Cao Ping,Zhang Hua,et al.Mesoporous amorphous TiO2 shell-coated ZIF-8 as an efficient and recyclable catalyst for transesterification to synthesize diphenyl carbonate[J].J Mater Sci,2019,54(13):9466-9477.
[11] Mostafa E,Mohammadreza M.Rapid room temperature synthesis of zeolite imidazolate framework-7(ZIF-7) microcrystals[J].Materials Letters,2016,189:243-247.
[12] 姚显芳,李映伟.MOFs作为牺牲模板制备纳米多孔碳材料的方法及其应用[J].科学通报,2015,10(20):1906-1914.
[13] Shen Kui,Chen Xiaodong,Chen Junying,et al.Development of MOF-derived carbon-based nanomaterials for efficient catalysis[J].ACS Catalysis,2016,6(9):5887-5903.
[14] Song Jianping,Wu Liang,Dong Wenda,et al.MOF-derived nitrogen-doped core-shell hierarchical porous carbon confining selenium for advanced lithium-selenium battery[J].Nanoscale,2019,11(14):6970-6981.
[15] Zhang Wei,Jiang Xiangfen,Zhao Yanyi,et al.Hollow carbon nanobubbles:monocrystalline MOF nanobubbles and their pyrolysis[J].Chem Sci,2017,8(5):3538-3546.
[16] Zhao Changming,Dai Xinyao,Yao Tao,et al.Ionic exchange of metal-organic frameworks to access single nickel sites for efficient electroreduction of CO2[J].J Am Chem Soc,2017,139(24):8078-8081.
[17] Fatma $,Berna T,Halil K.Synthesis of ZIF-7,ZIF-8,ZIF-67 and ZIF-L from recycled mother liquors[J].Microporous and Mesoporous Materials,2018,261:259-267.
[18] Li Xiangyang,Zhou Jianqi,Li Xin.Collapse-resistant large-sized 2D MOF-derived nitrogen-doped porous ultrathin carbon nanosheets for high performance supercapacitors[J].Chem Electro Chem,2019,6(17):4653-4659.
[19] Khan I U,Othman M H D,Ismail A F,et al.Structure transition from two-dimensional ZIF-L to three-dimensional ZIF-8 nanoparticles in aqueous room temperature synthesis with improved CO2 adsorption[J].Materials Characterization,2018,136:407-416.
[20] Shieh F K,Wang S C,Leo S Y,et al.Water-based synthesis of zeolitic imidazolate framework-90(ZIF-90) with a controllable particle size[J].Chem Eur J,2013,19(34):11139-11142.
[21] 王春宇,张晶,张青云,等.ZIF-8基多孔碳的制备及吸附性能[J].化工进展,2017,36(1):299-304.
