科学研究

基于Nafion共聚还原氧化石墨烯/聚苯胺复合材料的H2O2电化学传感器

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  • 1.中国海洋大学化学化工学院,海洋化学理论与工程技术教育部重点实验室,青岛266100;
    2.中国海洋大学环境科学与工程学院,青岛266100;
    3.福建师范大学福清分校海洋与生化工程学院,福清350300
周瑶(1994-),男,硕士,主要研究方向为复合材料的电化学传感器,E-mail:zhouy5413@163.com。

网络出版日期: 2020-10-20

基金资助

国家自然科学基金(51131005)

H2O2 electrochemical sensor based on nafion/RGO/PANI composite

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  • 1.Key Laboratory of Marine Chemistry Theory and Engineering Technology,Ministry of Education,College of Chemistry and Chemical Engineering,Ocean University of China,Qingdao 266100;
    2.College of Environmental Science and Engineering,Ocean University of China, Qingdao 266100;
    3.Research Center of Oceans Micro Plastic Prevention and High Value,Fujian Key Laboratory of Measurement and Control System for offshore Environment,Fuqing Branch of Fujian Normal University,Fuqing 350300

Online published: 2020-10-20

摘要

为实现对低浓度H2O2的快速检测,以玻碳电极为基底,Nafion(NF)为分散剂、成膜剂,原位电化学还原氧化石墨烯(GO)、电化学聚合苯胺,得到还原氧化石墨烯/聚苯胺(ERGO/PANI)复合物,以ERGO/PANI为修饰物,构建了无酶电化学传感器PANI/ERGO-NF修饰电极(PANI/ERGO-NF/GCE),对H2O2进行检测。利用扫描电镜和拉曼光谱对修饰电极的表面形貌和分子结构进行表征;利用电化学阻抗谱和循环伏安法研究了修饰电极的电化学性能及对H2O2的响应性能。结果表明:PANI/ERGO-NF/GCE对H2O2的电化学氧化显示出较好的催化活性,具有较高的检测灵敏度、较宽的线性范围以及较好的重现性、稳定性和抗干扰能力,在线性范围1~500μmol/L内,检出限0.1μmol/L。

本文引用格式

周瑶, 万起展, 王燕华, 李瑾, 李世迁, 钟莲 . 基于Nafion共聚还原氧化石墨烯/聚苯胺复合材料的H2O2电化学传感器[J]. 化工新型材料, 2020 , 48(10) : 192 -196 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.10.041

Abstract

In order to achieve rapid detection of low concentration hydrogen peroxide (H2O2),a non-enzymatic H2O2 electrochemical sensor was constructed by using glassy carbon electrode as substrate,Nafion as selective coating material,electrochemical reduced graphene oxide and electrochemical polymerized polyaniline complex (ERGO/PANI)as modifier.The microstructure and molecular structure of the modified electrode was characterized by SEM and raman spectroscopy.The electrochemical properties of the modified electrode and its response to H2O2 were studied by electrochemical impedance spectroscopy (EIS) and cyclic voltammetry.Results shown that the constructed PANI/ERGO-NF/GCE electrode exhibited excellent electrocatalytic performance for the determination of H2O2.The proposed sensor displayed a wide linear range of 1.00~5.00μmol/L,a limit of detection (LOD) of 0.1μmol/L.Moreover,the sensor shown outstanding stability,reproducibility and anti-interference ability.

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