综述与专论

黏土基催化剂降解环境激素类物质研究进展

展开
  • 兰州理工大学石油化工学院,兰州730050
白格(1994-),女,硕士研究生,从事环境催化研究工作。

网络出版日期: 2020-10-20

基金资助

国家自然科学基金(51302123);广东省重点实验室开放基金(KF2018001)

Research progress on degradation of environmental hormone by clay-based catalyst

Expand
  • College of Petrochemical Engineering,Lanzhou University of Technology,Lanzhou 730050

Online published: 2020-10-20

摘要

环境激素类物质已成为全球性污染物质,具有潜在的危险性,其处理方法主要包括生物法、物理法和化学法。高级氧化法是化学法的一种,具有选择性低、反应速度快、处理彻底、无二次污染等特点。介绍了Fenton氧化法、光催化氧化法、臭氧氧化法、电催化氧化法等高级氧化法用黏土基催化剂降解环境激素类物质研究进展,指出了催化剂使用过程中存在的问题,对黏土基催化剂未来的研究方向进行了展望。

本文引用格式

白格, 张婷, 钱春园, 董玲玉, 郭旗扬 . 黏土基催化剂降解环境激素类物质研究进展[J]. 化工新型材料, 2020 , 48(10) : 58 -63 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.10.013

Abstract

Environmental pollutants have become a global pollutant with potential risk.The treatment methods include biological method,physical method and chemical method.Advanced oxidation method is a chemical method,which has the characteristics of low selectivity,fast reaction speed,thorough treatment and no secondary pollution.Research advances on degradation of hormone pollutants in environment by clay-based catalysts using advanced oxidation methods such as Fenton oxidation,photocatalytic oxidation,ozonation and electrocatalytic oxidation were introduced.The existing problems of the catalyst were pointed out,and the future research direction of clay based catalyst was prospected.

参考文献

[1] 侯爽, 隋倩.华东地区某市重点行业优控环境激素的筛选及分布特征[J].化工进展, 2019, 38(2):1140-1145.
[2] Russart K L G, Nelson R J.Light at night as an environmental endocrine disruptor[J].Physiol Behav, 2018, 190:82-89.
[3] 郎朗, 张光明.饮用水水源及水厂内分泌干扰物污染分析[J].环境工程, 2008, 26(S1):60-63.
[4] Williams G P, Darbre P D.Low-dose environmental endocrine disruptors, increase aromatase activity, estradiol biosynthesis and cell proliferation in human breast cells[J].Mol Cell Endocrinol, 2019, 486:55-64.
[5] Mezohegyi G, Erjavec B, Kaplan R, et al.Removal of bisphenol A and its oxidation products from aqueous solutions by sequential catalytic wet air oxidation and biodegradation[J].Industrial & Engineering Chemistry Research, 2013, 52(26):9301-9307.
[6] 高丰琴, 李雪莲, 蒋育澄.氯过氧化物酶催化降解环境激素西维因的研究[J].化学研究与应用, 2018, 30(5):701-705.
[7] 刘佳琦.含酚废水处理技术研究[J].环境科学与管理, 2018, 43(9):26.
[8] 李胜男, 伏迪, 李凤祥, 等.高级氧化降解环境内分泌干扰物双酚A研究进展[J].水处理技术, 2018, 44(12):1-6.
[9] 刘静, 李亚茹, 王杰, 等.高级催化氧化法去除水中邻苯二甲酸酯的研究进展[J].生态环境学报, 2014, 23(5):904-910.
[10] 张帆, 刘媛, 贺盛福, 等.处理含酚废水的研究进展[J].现代化工, 2015, 35(1):67-72.
[11] Fang F, Han H, Zhao Q, et al.Bioaugmentation of biological contact oxidation reactor (BCOR) with phenol-degrading bacteria for coal gasification wastewater (CGW) treatment[J].Bioresour Technol, 2013, 150:314-320.
[12] Khan J A, He X, Khan H M, et al.Oxidative degradation of atrazine in aqueous solution by UV/H2O2/Fe2+, UV/Fe2+ and UV/Fe2+ processes:a comparative study[J].Chemical Engineering Journal, 2013, 218:376-383.
[13] Nghiem L D, Manis A, Soldenhoff K, et al.Estrogenic hormone removal from wastewater using NF/RO membranes[J].Journal of Membrane Science, 2004, 242(1/2):37-45.
[14] Kimura K, Toshima S, Amy G, et al.Rejection of neutral endocrine disrupting compounds (EDCs) and pharmaceutical active compounds (PhACs) by RO membranes[J].Journal of Membrane Science, 2004, 245(1/2):71-78.
[15] Qiu X, Li N, Ma X, et al.Facile preparation of acrylic ester-based crosslinked resin and its adsorption of phenol at high concentration[J].Journal of Environmental Chemical Engineering, 2014, 2(1):745-751.
[16] Choi K J, Kim S G, Kim C W, et al.Effects of activated carbon types and service life on removal of endocrine disrupting chemicals:amitrol, nonylphenol, and bisphenol-A[J].Chemosphere, 2005, 58(11):1535-1545.
[17] Zhang Y, Zhou J L.Removal of estrone and 17beta-estradiol from water by adsorption[J].Water Res, 2005, 39(16):3991-4003.
[18] 孙怡, 于利亮, 黄浩斌, 等l.高级氧化技术处理难降解有机废水的研发趋势及实用化进展[J].化工学报, 2017, 68(5):1743-1756.
[19] Herney-Ramirez J, Vicente M A, Madeira L M.Heterogeneous photo-Fenton oxidation with pillared clay-based catalysts for wastewater treatment:a review[J].Applied Catalysis B:Environmental, 2010, 98(1/2):10-26.
[20] Muthuvel I, Krishnakumar B, Swaminathan M.Solar active fire clay based hetero-Fenton catalyst over a wide pH range for degradation of acid violet 7[J].Journal of Environmental Sciences, 2012, 24(3):529-535.
[21] Navalon S, Alvaro M, Garcia H.Heterogeneous Fenton catalysts based on clays, silicas and zeolites[J].Applied Catalysis B:Environmental, 2010, 99(1/2):1-26.
[22] Hassan H, Hameed B H.Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of reactive blue 4[J].Chemical Engineering Journal, 2011, 171(3):912-918.
[23] 廖丰, 龙明策.黏土负载型类Fenton催化剂的研究进展[J].化工进展, 2018, 37(9):3401-3409.
[24] 江传春, 肖蓉蓉, 杨平.高级氧化技术在水处理中的研究进展[J].水处理技术, 2011, 37(7):12-16;33.
[25] Wang G, Lu G, Zhao J, et al.Evaluation of toxicity and estrogenicity of the landfill-concentrated leachate during advanced oxidation treatment:chemical analyses and bioanalytical tools[J].Environ Sci Pollut Res Int, 2016, 23(16):16015-16024.
[26] Gong Y, Tian H, Wang L, et al.An integrated approach combining chemical analysis and an in vivo bioassay to assess the estrogenic potency of a municipal solid waste landfill leachate in Qingdao[J].PLOS One, 2014, 9(4):95597.
[27] 侯昌成, 赵玲, 尹平河, 等.垃圾渗滤液中典型内分泌干扰物质(EDCs)细胞毒性分析[J].生态毒理学报, 2017, 12(3):327-335.
[28] Ma C, He Z, Jia S, et al.Treatment of stabilized landfill leachate by Fenton-like process using Fe3O4 particles decorated Zr-pillared bentonite[J].Ecotoxicol Environ Saf, 2018, 161:489-496.
[29] 陈维雨思, 张宇峰, 姚佳晔, 等.膨润土负载Fe0处理高效氟氯氰菊酯模拟废水[J].现代化工, 2018, 38(3):161-164;166.
[30] Cao C Y, Meng L K, Zhao Y H.Fe-pillared bentonite, a stable Fenton catalyst for treatment of petroleum refinery wastewater[J].Toxicological & Environmental Chemistry, 2013, 95(5):747-756.
[31] Dong Z, Zhang Q, Hong J.Effective benzalkonium chloride degradation by Fenton oxidation with iron-carbon-bentonite-alginate beads[J].Desalination and Water Treatment, 2018, 123:119-128.
[32] Ayodele O B, Lim J K, Hameed B H.Pillared montmorillonite supported ferric oxalate as heterogeneous photo-Fenton catalyst for degradation of amoxicillin[J].Applied Catalysis A:General, 2012, 413-414:301-309.
[33] Chen J, Zhu L.Heterogeneous UV-Fenton catalytic degradation of dyestuff in water with hydroxyl-Fe pillared bentonite[J].Catalysis Today, 2007, 126(3/4):463-470.
[34] 洪浩峰, 潘湛昌, 许磊, 等.臭氧催化氧化处理苯酚废水研究[J].环境科学与技术, 2010, 33(S1):301-304.
[35] 杨婷婷, 李亮, 梁曼丽, 等.镍铁层状双金属氢氧化物催化臭氧去除双酚A的试验[J].净水技术, 2019, 38(2):22-28.
[36] 郝彦龙, 侯永江, 国洁, 等.MnO2/膨润土催化臭氧化氯苯废水[J].工业水处理, 2014, 34(1):47-50.
[37] 王力, 姚旭, 尹东光, 等.臭氧氧化偏二甲肼生成二甲基亚硝胺的量子化学计算[J].火炸药学报, 2017, 40(2):79-83.
[38] Shahidi D, Moheb A, Abbas R, et al.Total mineralization of sulfamethoxazole and aromatic pollutants through Fe2+-montmorillonite catalyzed ozonation[J].J Hazard Mater, 2015, 298:338-50.
[39] Hassani A, Khataee A, Fathinia M, et al.Photocatalytic ozonation of ciprofloxacin from aqueous solution using TiO2/MMT nanocomposite:nonlinear modeling and optimization of the process via artificial neural network integrated genetic algorithm[J].Process Safety and Environmental Protection, 2018, 116:365-376.
[40] Khataee A, KranAs5an M, Karaca S, et al.Photocatalytic ozonation of metronidazole by synthesized zinc oxide nanoparticles immobilized on montmorillonite[J].Journal of the Taiwan Institute of Chemical Engineers, 2017, 74:196-204.
[41] Martini J, Orge C A, Faria J L, et al.Sulfam ethoxazole degradation by combination of advanced oxidation processes[J].Journal of Environmental Chemical Engineering, 2018, 6(4):4054-4060.
[42] 龚敏, 余铁萍, 李芬芳, 等.TiO2/磁性海泡石光催化处理复合废水性能[J].水处理技术, 2015, 41(6):43-45;51.
[43] Martínez-Costa J I, Rivera-Utrilla J, Leyva-Ramos R, et al.Individual and simultaneous degradation of antibiotics sulfam ethoxazole and trimethoprim by UV and solar radiation in aqueous solution using bentonite and vermiculite as photocatalysts[J].Applied Clay Science, 2018, 160:217-225.
[44] Jafari S, Nezamzadeh-Ejhieh A.Supporting of coupled silver halides onto clinoptilolite nanoparticles as simple method for increasing their photocatalytic activity in heterogeneous photodegradation of mixture of 4-methoxy aniline and 4-chloro-3-nitro aniline[J].J Colloid Interface Sci, 2017, 490:478-487.
[45] 焦旭阳, 张新妙, 栾金义.电催化氧化技术处理含盐有机废水研究进展[J].化工环保, 2019, 39(1):6-10.
[46] 汤海峰, 王海玲, 魏朋, 等.电催化氧化降解对乙酰氨基酚的实验研究[J].现代化工, 2019, 39(4):166-169;171.
[47] 赵媛媛, 王德军, 赵朝成.电催化氧化处理难降解废水用电极材料的研究进展[J].材料导报, 2019, 33(7):1125-1132.
[48] 李国华, 杨威, 佟明兴, 等.WC/MMT纳米复合材料制备及其对PNP的电催化活性[J].化工学报, 2015, 66(9):3776-3781.
Options
文章导航

/