开发与应用

多孔有机聚合物异相光催化研究现状及进展

展开
  • 苏州科技大学化学生物与材料工程学院,苏州 215009
刘雨(1997-),女,本科,主要研究方向为多孔材料的设计与催化应用。

收稿日期: 2019-06-13

  修回日期: 2020-06-27

  网络出版日期: 2020-10-20

基金资助

国家自然科学基金(21702143);江苏省自然科学基金项目(BK20170377);江苏省高校自然科学研究面上项目(17KJB150035);江苏省大学生创新创业训练计划项目(201810332041Y)资助

Progress and perspective of porous organic polymer as heterogeneous photocatalyst

Expand
  • School of Chemistry,Biology and Materials Engineering,Suzhou University of Science and Technology,Suzhou 215009

Received date: 2019-06-13

  Revised date: 2020-06-27

  Online published: 2020-10-20

摘要

异相催化方式相对于均相催化展现出优异的分离和回收性能,而被研究人员广泛开发和利用。多孔有机聚合物作为一种新型多孔高分子功能材料,因其稳定的共轭骨架、高比表面积和设计合成的高灵活性,广泛应用于气体吸附分离、检测和(光)催化等领域。材料的捕光及不溶特性亦使其在异相光催化领域展现了出色的催化能力,在能源和环境方面也显示出巨大的潜力。围绕此类材料在异相光催化领域的研究及发展现状,分析了光催化的优势和困境,并结合光催化方式提出多孔有机聚合物提高光催化效率的有效措施。

本文引用格式

刘雨, 俞润炜, 俞明浩, 窦越, 刘洁 . 多孔有机聚合物异相光催化研究现状及进展[J]. 化工新型材料, 2020 , 48(9) : 225 -230 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.09.049

Abstract

Heterogeneous catalysis has been developed and utilized as that of an excellent separation and recovery performance compared with homogeneous catalysis.Porous organic polymers,as a new type of porous functional materials,exhibit broad applications such as gas adsorption and separation,sensing and (photo)catalysis due to their stable conjugated skeleton framework,high surface area and flexible molecular design and synthesis.Their light harvest ability and insoluble nature allow them to show excellent catalytic properties in the field of heterogeneous photocatalysis,and also show great potential in energy resources and environment.The research status and development of heterogeneous photocatalysis regard to this kind of materials were focused.The advantages and difficulties of photocatalysis were also analyzed.Moreover,effective measures for improving photocatalytic efficiency and the prospective of porous organic polymers in the combination with photocatalytic methods were under work.

参考文献

[1] 唐新硕,王新平.催化科学发展及其理论[M].杭州:浙江大学出版社,2012.
[2] 李郑飞.甲醇羰基化制醋酸均相催化体系的研究[D].重庆:重庆大学,2011.
[3] 史振朋,王海洋,李佳哲,等.负载钯催化Suzuki偶联反应的研究进展[J].化学与粘合,2014,36(4):290-294.
[4] 支永峰,马思,刘晓明.多孔有机聚合物非均相光催化研究进展[J].高分子通报,2018(6):160-171.
[5] Mckeown N B,Budd P M.Exploitation of intrinsic microporosity in polymer-based materials[J].Macromolecules,2010,43(12):5163-5176.
[6] Wood C D,Tan B,Trewin A,et al.Hydrogen storage in microporous hypercrosslinked organic polymer networks[J].Chem Mater,2007,19(8):2034-2048.
[7] Xu Y,Jin S,Xu H,et al.Conjugated microporous polymers:design,synthesis and application[J].Chem Soc Rev,2013,42(20):8012-8031.
[8] Liu J,Yee K,Lo K K,et al.Selective Ag(I) binding,H2S sensing,and white-light emission from an easy-to-make porous conjugated polymer[J].J Am Chem Soc,2014,136(7):2818-2824.
[9] Liu J,Cui J,Vilela F,et al.In situ production of silver nanoparticles on an aldehyde-equipped conjugated porous polymer and subsequent heterogeneous reduction of aromatic nitro groups at room temperature[J].Chem Commun,2015,51(61):12197-12200.
[10] Liu J,Tobin J M,Xu Z,et al.Facile synthesis of a conjugated microporous polymeric monolith via copper-free sonogashira-hagihara cross-coupling in water under aerobic conditions[J].Polym Chem,2015,6(41):7251-7255.
[11] Tobin J M,Liu J,Hayes H,et al.BODIPY-based conjugated microporous polymers as reusable heterogeneous photosensitisers in a photochemical flow reactor[J].Polym Chem,2016,7:6662-6670.
[12] 何洪波.二氧化钛基纳米复合材料修饰阳极及其光催化辅助电解水制氢性能研究[D].上海:华东理工大学,2013.
[13] Cecconi B,Manfredi N,Ruffo R,et al.Tuning thiophene-based phenothiazines for stable photocatalytic hydrogen production[J].Chem Sus Chem,2015,8(24):4216-4228.
[14] Yang J,Wang M,Zhao S,et al.Petal-biotemplated synthesis of two-dimensional Co3O4 nanosheets as photocatalyst with enhanced photocatalytic activity[J].Int J Hydrogen Energy,2019,44(2):870-879.
[15] Schattka J H,Shchukin D G,Jia J,et al.Photocatalytic activities of porous titania and titania/zirconia structures formed by using a polymer gel templating technique[J].Chem Mater,2002,14(12):5103-5108.
[16] Sone Y,Ohgaki T,Nishio K,et al.Photocatalytic machining of organic polymer surface by use of porous titania micro wire[J].J Photopolym Sci Technol,2006,19(1):111-116.
[17] Dhanalaxmi K,Yadav R,Kundu S K,et al.MnFe2O4 nanocrystals wrapped in a porous organic polymer:a designed architecture for water-splitting photocatalysis[J].Chem Eur J,2016,22(44):15639-15644.
[18] Feng Y,Wei J,Ding Y.Mesoporous Mn1.8Fe1.2O4 nanocubes as robust catalysts for water oxidation[J].J Catal,2016,339:186-194.
[19] Li L,Ca Z i,Wu Q,et al.Rational design of porous conjugated polymers and roles of residual palladium for photocatalytic hydrogen production[J].J Am Chem Soc,2016,138(24):7681-7686.
[20] Wu P T,Ren G,Jenekhe S A.Crystalline random conjugated copolymers with multiple side chains:tunable intermolecular interactions and enhanced charge transport and photovoltaic properties[J].Macromolecules,2010,43(7):3306-3313.
[21] Yang J,Wang D,Han H,et al.Roles of cocatalysts in photocatalysis and photoelectrocatalysis[J].Acc Chem Res,2013,46(8):1900-1909.
[22] Xu Y,Mao N,Feng S,et al.Perylene-containing conjugated microporous polymers for photocatalytic hydrogen evolution[J].Macromolecular Chemistry & Physics,2017,218(14):1700049.
[23] 周文佩,陈俊,汪锋.基于螺二芴微孔聚合物光催化水制氢性能研究[J].山东化工,2018(5):48-50.
[24] Liu Q,Tang Z,Wu M,et al.Design,preparation and application of conjugated microporous polymers[J].Polym Int,2014,63(3):381-392.
[25] Das S K,Ghosh P,Ghosh I,et al.Adsorption of rhodamine B on Rhizopus oryzae:role of functional groups and cell wall components[J].Colloids and Surfaces B:Biointerfaces,2008,65(1):30-34.
[26] Dawson R,Cooper A I,Adams D J.Nanoporous organic polymer networks[J].Prog Polym Sci,2012,37(4):530-563.
[27] Ma D,Li B,Cui Z,et al.Multifunctional luminescent porous organic polymer for selectively detecting iron ions and 1,4-dioxane via luminescent turn-off and turn-on sensing[J].ACS Appl Mater Interfaces,2016,8(36):24097-24103.
[28] Song Y,Zhang J,Yang L,et al.Photocatalytic activity of TiO2 based composite films by porous conjugated polymer coating of nanoparticles[J].Mater Sci Semicond Process,2015,42(1):54-57.
[29] Adjimi S,Sergent N,Roux J C,et al.Photocatalytic paper based on sol-gel titania nanoparticles immobilized on porous silica for VOC abatement[J].Applied Catalysis B:Environmental,2014,154-155:123-133.
[30] Ollis D.Photocatalyzed and photosensitized conversion of organic dyes on porous and non-porous air-solid surfaces:kinetic models reconsidered[J].Applied Catalysis B:Environmental,2015,165:111-116.
[31] Li Y,Zhang W,Wang J,et al.Light-induced synthesis of triazine N-oxide-based cross-linked polymers for effective photocatalytic degradation of methyl orange[J].RSC Adv,2017,7(15):9309-9315.
[32] Chu S,Wang Y,Guo Y,et al.Facile green synthesis of crystalline polyimide photocatalyst for hydrogen generation from water[J].J Mater Chem,2012,22(31):15519-15521.
[33] Liu P,Xing L,Lin H,et al.Construction of porous covalent organic polymer as photocatalysts for RhB degradation under visible light[J].Science Bulletin,2017,62(13):931-937.
[34] Ding S Y,Dong M,Wang Y W,et al.Thioether-based fluorescent covalent organic framework for selective detection and facile removal of mercury(Ⅱ)[J].J Am Chem Soc,2016,138(9):3031-3037.
[35] Chong J H,Sauer M,Patrick B O,et al.Highly stable keto-enamine salicylideneanilines[J].Org Lett,2003,5(21):3823-3826.
[36] Jiang S Q,Zhou Z Y,Zhuo S P,et al.Rational design of a highly sensitive and selective “turn-on”fluorescent sensor for PO34-detection[J].Dalton Trans,2015,44(48):20830-20833.
[37] Li Y,Liu M,Chen L.Polyoxometalates built-in conjugated microporous polymers for visible-light heterogeneous photocatalysis[J].J Mater Chem A,2017,5(26):13757-13762.
[38] Liras M,Iglesias M,Sánchez F.Conjugated microporous polymers incorporating BODIPY moieties as light-emitting materials and recyclable visible-light photocatalysts[J].Macromolecules,2016,49(5):1666-1673.
[39] Xie Z,Wang C,Dekrafft K E,et al.Highly stable and porous cross-linked polymers for efficient photocatalysis[J].J Am Chem Soc,2011,133(7):2056-2059.
[40] Wang J L,Wang C,Dekrafft K E,et al.Cross-linked polymers with exceptionally high Ru(bipy)2+3 loadings for efficient heterogeneous photocatalysis[J].ACS Catal,2012,2(3):417-424.
[41] Condie A G,González-Gómez J C,Stephenson C R J.Visible-light photoredox catalysis:aza-henry reactions via C—H functionalization[J].J Am Chem Soc,2010,132(5):1464-1465.
[42] Wang C A,Li Y W,Cheng X L,et al.Eosin Y dye-based porous organic polymers for highly efficient heterogeneous photocatalytic dehydrogenative coupling reaction[J].RSC Adv,2017,7(1):408-414.
[43] Neumann M,Füldner S,König B,et al.Metal-free,cooperative asymmetric organophotoredox catalysis with visible light[J].Angew Chem In Ed,2011,50(4):951-954.
[44] Zhang K,Kopetzki D,Seeberger P H,et al.Surface area control and photocatalytic activity of conjugated microporous poly(benzothiadiazole) networks[J].Angew Chem,2013,125(5):1472-1476.
[45] Li R,Wang Z J,Wang L,et al.Photocatalytic selective bromination of electron-rich aromatic compounds using microporous organic polymers with visible light[J].ACS Catal,2016,6(2):1113-1121.
[46] Ohkubo K,Mizushima K,Iwata R,et al.Selective photocatalytic aerobic bromination with hydrogen bromidevia an electron-transfer state of 9-mesityl-10-methylacridinium ion[J].Chem Sci,2011,2(4):715-722.
[47] Jiang J X,Li Y,Wu X,et al.Conjugated microporous polymers with Rose Bengal dye for highly efficient heterogeneous organo-photocatalysis[J].Macromolecules,2013,46(22):8779-8783.
[48] Cooper A I.Conjugated microporous polymers[J].Adv Mate,2009,21(12):1291-1295.
[49] Pan Y,Kee C W,Chen L,et al.Dehydrogenative coupling reactions catalysed by Rose Bengal using visible light irradiation[J].Green Chemistry,2011,13(10):2682-2685.
[50] Trewin A,Cooper A I.Porous organic polymers:distinction from disorder?[J].Angew Chem Int Ed,2010,49(9):1533-1535.
[51] Schwab M G,Fassbender B,Spiess H W,et al.Catalyst-free preparation of melamine-based microporous polymer networks through Schiff base chemistry[J].J Am Chem Soc,2009,131(21):7216-7217.
Options
文章导航

/