综述与专论

废弃生物质制备生物质基碳微球的研究进展

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  • 武汉科技大学化学与化工学院湖北省煤转化与新型炭材料重点实验室,武汉 430081
王荣(1996-),女,硕士研究生,主要从事清洁能源化工的研究。

收稿日期: 2019-05-28

  修回日期: 2020-07-01

  网络出版日期: 2020-10-20

基金资助

国家自然科学基金项目(21473126);湖北省教育厅项目(B2014094)

Progress in preparation of biomass-based carbon microspheres from waste biomass

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  • School of Chemistry and Chemical Engineering and Technology,Hubei Key Laboratory of Coal Conversion and New Carbon Material,Wuhan University of Science and Technology, Wuhan 430081

Received date: 2019-05-28

  Revised date: 2020-07-01

  Online published: 2020-10-20

摘要

碳微球由于具有优异的物化性能,在许多领域都有着不可取代的优势和应用前景。在资源日益紧缺,环境问题日益严峻的今天,为了降低不可再生资源的消耗速度和环境负担,加强对废弃生物质资源的利用成为各界学者关注的热点。就这两个方面综述了利用常见的废弃生物质,包括稻草、玉米芯、废纸盒等制备碳微球的方法及其应用。

关键词: 生物质; 碳微球; 制备; 应用

本文引用格式

王荣, 曾丹林, 杨媛媛, 王园园, 吴洁, 许可, 王光辉 . 废弃生物质制备生物质基碳微球的研究进展[J]. 化工新型材料, 2020 , 48(9) : 63 -67 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.09.014

Abstract

Carbon microspheres have irreplaceable advantages and application prospects in many fields due to their excellent physical and chemical properties.Nowadays,with the increasing shortage of resources and the increasingly severe environmental problems,in order to reduce the consumption rate and environmental burden of non-renewable resources,strengthening the utilization of waste biomass resources has become the focus of attention of scholars from all walks of life.The preparation methods and applications of carbon microspheres from common waste biomass,including straw,corncob and waste carton,were reviewed.

参考文献

[1] Zhou H,Wang D,Fu A,et al.Mesoporous carbon spheres with tunable porosity prepared by a template-free method for advanced lithium-sulfur batteries[J].Materials Science and Engineering:B,2018,227:9-15.
[2] Liu S,Zhao Y,Zhang B,et al.Nano-micro carbon spheres anchored on porous carbon derived from dual-biomass as high rate performance supercapacitor electrodes[J].Journal of Power Sources,2018,381:116-126.
[3] Inada M,Enomoto N,Hojo J,et al.Structural analysis and capacitive properties of carbon spheres prepared by hydrothermal carbonization[J].Advanced Powder Technology,2017,28(3):884-889.
[4] Mohseni M,Peters B.An attempt to study conversion of biomass spheres in a stove using a DEM-CFD approach[J].Energy Procedia,2017,120:657-664.
[5] Moreno-Castilla C.Colloidal and micro-carbon spheres derived from low-temperature polymerization reactions[J].Advances in Colloid and Interface Science,2016,236:113-141.
[6] Wang G,Peng H,Qiao X,et al.Biomass-derived porous heteroatom-doped carbon spheres as a high-performance catalyst for the oxygen reduction reaction[J].International Journal of Hydrogen Energy,2016,41(32):14101-14110.
[7] Donar Y O,Caglar E,Sinag A.Preparation and characterization of agricultural waste biomass based hydrochars[J].Fuel,2016,183(1):366-372.
[8] Sun H,Li S.Preparation of novel ordered macroporous carbon spheres by chemical vapor deposition method and their characterization[J].Chemistry & Bioengineering,2018,35(9):22-24,29.
[9] Simsir H,Eltugral N,Karagoz S.Hydrothermal carbonization for the preparation of hydrochars from glucose,cellulose,chitin,chitosan and wood chips via low-temperature and their characterization[J].Bioresource Technology,2017,246.
[10] Liu S,Sun J,Huang Z.Carbon spheres/activated carbon composite materials with high Cr(Ⅵ) adsorption capacity prepared by a hydrothermal method[J].Journal of Hazardous Materials,2010,173(1-3):377-383.
[11] 陈秀娟,余国云,王安耸,等.微米级碳微球载体的制备[J].兰州理工大学学报,2018,44(1):6-10.
[12] Zhang H J,Ye F,Xu H F,et al.Synthesis of carbon hollow particles by a simpleinverse-emulsion method[J].Mater Lett,2010;64:1473-1475.
[13] 杨阳,朱玲.软模板催化法合成石墨化碳微球及其吸附性能研究[J].材料导报,2015,29(8):17-21.
[14] 鲁丹.金属氧化物空心微球与金属氧化物碳核壳微球的制备及表征[D].上海:华东理工大学,2015.
[15] 李春艳,刘其城,刘鹏.中间相碳微球的制备与性能[J].长沙理工大学学报(自然科学版),2013,10(2):89-92.
[16] Hou H Q,Schaper A K,Weller F,et al.Carbon nanotubes and spheres produced by modified ferrocene pyrolysis[J].Chemistry of Materials,2002,14(9):3990-3994.
[17] 任斌.超声悬浮共聚法制备聚合物微球及其形态[J].功能高分子学报,2011,24(3):292-296.
[18] Yoon S,Park Y.Preparation of carbonaceous spheres from suspensions of pitch materials[J].Carbon,1992,30(5):781-786.
[19] 许并杜,罗秋苹.银/碳微球复合材料的制备和表征[J].中国材料进展,2009,2(1):23-25.
[20] Qiu J S,Lia Y F,Wang Y P,et al.A novel form of carbon micro-ballsfrom coal[J].Carbon,2003,41:767-772.
[21] 卫英慧,林丽霞,侯利锋,等.一种用球墨铸铁制备碳微球的方法:中国,CN200810055382.2[P].2008-07-05.
[22] 吴倩芳.水热炭化废弃生物质的研究进展[J].环境污染与防治,2012,1(7):70-75.
[23] Zhao X,Li Wi,Kong FGet al.Carbon spheres derived from biomass residue via ultrasonic spray pyrolysis for supercapacitors[J].Materials Chemistry and Physics,2018,219.
[24] Lee J K,Park Y K,Kim H Y,et al.Fabrication of mesoporous carbon materials from non-mesoporous silica spheres templates[J].Bull Korean Chemical Society,2005,26:709-710.
[25] Pol Vi G,Motiei M,Gedanken A,et al.Carbon spherules:synthesis,properties and mechanistic elucidation[J].Carbon,2004,42(1):111-116.
[26] Luo T,Gao L,Liu J,et al.Olivary particles:unique carbon microstructure synthesized by catalytic pyrolysis of acetone[J].The Journal of Physical Chemistry B,2005,109(32):15272-15277.
[27] Qiu J,Li Y,Wang Y,et al.A novel form of carbon micro-balls from coal[J].Carbon,2003,41(4):767-772.
[28] Kodama M,Fujiura T.Preparation of mesocarbon microbeads with an arrow size distribution[J].Carbon,1988,26(4):595-598.
[29] 刘亦陶,魏佳,李军.废弃生物质水热炭化技术及其产物在废水处理中的应用进展[J].化学与生物工程,2019(1):1-10.
[30] 乔娜.玉米芯和松子壳的水热碳化及其产物吸附性能研究[D].辽宁:大连理工大学,2015.
[31] 乔娜,姚冬梅,王栋,等.金属离子对松子壳水热碳化固体产物的影响[J].环境工程学报,2016,10(7): - .
[32] 徐智,郭朝晖,韩自玉,等.芦竹水热炭的制备及重金属分离机制研究[J].环境工程,2018,36(8):118-123.
[33] 杜亚雷.玉米芯制备碳微球的基础研究[D].长春:吉林大学,2012.
[34] 陈磊山,王存景,苗郁,等.麦秸秆为原料新绿色工艺制备碳微球[J].化工新型材料,2015,43(2):69-70,96.
[35] 史晟.利用废旧棉纤维制备碳微球的研究[D].太原:太原理工大学,2012.
[36] 凌晨,张素英,侯文生,等.pH值对废旧棉纤维水热碳化的影响[J].纺织导报,2018(3):40-42,44.
[37] Han J,Zhang G,Zhou L,et al.Waste carton-derived nanocomposites for efficient removal of hexavalent chromium[J].Langmuir,2018,34(21):5955-5963.
[38] 魏梅霞.废旧棉织物制备活性炭纤维及其吸附性能的研究[D].太原:太原理工大学,2017.
[39] 庄海峰,刘万鹏,单胜道,等.一种茭白废弃物制备水热炭微球的方法和应用:中国,201610385936.X[P].2016-06-03.
[40] 杨秀英,方志,张德庆.水热法碳化废旧棉织物制备碳微球的研究[J].齐齐哈尔大学学报:自然科学版,2015(2):5-7.
[41] Wang L,Guo Y,Zhu Y,et al.A new route for preparation of hydrochars from rice husk[J].Bioresource Technology,2010,101(24):9807-9810.
[42] 林松竹,韩枫安,张晓君,等.原位合成法制备稻草生物质基碳微球[J].东北电力大学学报,2018,38(2):78-82.
[43] 谭晓华.木质纤维全组分微球的制备与应用[D].广州:华南农业大学,2016.
[44] Sevilla Solís,Marta,Fuertes Arias A B.The production of carbon materials by hydrothermal carbonization of cellulose[J].Carbon,2009,47(9):2281-2289.
[45] Fan Y,Yang X,Zhu B,et al.Micro-mesoporous carbon spheres derived from carrageenan as electrode material for supercapacitors[J].Journal of Power Sources,2014,268:584-590.
[46] 马文天,郭会琴,刘宇,等.油茶籽壳磁性碳微球的制备及其对PFOS的吸附性能[J].环境工程,2017(11):119-124.
[47] 刘宇,李晶,曾春城,等.热改性生物质炭微球及对水中结晶紫的吸附[J].江西化工,2016(2):123-126.
[48] 付文秀,魏菊.棉纤维制得的碳微球结构及吸附性能研究[J].棉纺织技术,2017,45(11):5-8.
[49] 薛曲.生物质基炭微球的制备、表征及性能研究[D].大连:辽宁师范大学,2012.
[50] 李可心,刘淑芬,郭会琴,等.一种生物基单分散碳微球固体酸催化剂的制备方法及其在合成生物燃料中的应用:中国,201610354547.0[P].2016-07-19.
[51] Wang L,Zhao L,Yu P,et al.Silica direct evaporation:a size-con-trolled approach to SiC/carbon nanosheet composites as Pt catalyst supports for superior methanol electrooxidation[J].J Mater Chem A,2015,3(47):24139-24147.
[52] 王勇.植物麻杆基和胶原基生物质多孔炭的制备、表征及性能研究[D].北京:北京化工大学,2015.
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