等网状结构MOFs材料的制备及其对CO<sub>2</sub>捕集的研究进展

唐一桐, 李雪霏, 郝博, 赵文波

doi:10.19817/j.cnki.issn 1006-3536.2020.09.008

化工新型材料 >

2020 , Vol. 48 >Issue 9: 32 - 37

DOI: https://doi.org/10.19817/j.cnki.issn 1006-3536.2020.09.008

综述与专论

等网状结构MOFs材料的制备及其对CO₂捕集的研究进展

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昆明理工大学化学工程学院,昆明 650500

唐一桐(1996-),男,硕士研究生,主要从事环境化工及资源化利用研究工作。

收稿日期: 2019-05-08

修回日期: 2020-05-04

网络出版日期: 2020-10-20

基金资助

国家自然科学基金(21666011)

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Research progress on preparation of IRMOFs material and its application of CO₂ capture

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Faculty of Chemical Engineering,Kunming University of Science and Technology, Kunming 650500

Received date: 2019-05-08

Revised date: 2020-05-04

Online published: 2020-10-20

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摘要

化石燃料的大量燃烧导致全球CO₂排放过度,给全球气候带来了严重的影响。金属-有机框架(MOFs)材料作为一种CO₂物理吸附剂因吸附量大成为吸附CO₂的主力军并展现了巨大的节能环保潜力。相较于其他MOFs材料,具有等网状结构的MOFs(IRMOFs)材料因特殊的结构表现出更出色的CO₂吸附性能。从IRMOFs的结构性质出发,概述了目前合成IRMOFs的基本方法,介绍了IRMOFs吸附CO₂的原理、吸附效果、吸附选择性、吸附产生的阶梯性现象,以及IRMOFs增强CO₂吸附性能的改性方法并展望了IRMOFs未来的发展趋势。

关键词： 二氧化碳; 等网状结构金属-有机框架材料; 吸附; 比表面积; 孔径

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唐一桐, 李雪霏, 郝博, 赵文波 . 等网状结构MOFs材料的制备及其对CO₂捕集的研究进展[J]. 化工新型材料, 2020 , 48(9) : 32 -37 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.09.008

Abstract

With the massive burning of fossil fuels lead to excessive global CO₂ emissions and has a serious impact on the global climate.Due to its large adsorption capacity and its great potential for energy conservation and environmental protection,MOFs is the main method of adsorbing CO₂.Due to their special structure,the isoreticular metal-organic frameworks (IRMOFs) has the better CO₂ adsorption performance than other MOFs materials.The structural properties of IRMOFs were shown,and listed several basic methods for synthesizing IRMOFs.Secondly,the adsorption of CO₂ by IRMOFs,the adsorption effect,the adsorption selectivity and the stepped behavior of CO₂ adsorption in MOFs were listed.Finally,it listed several modification methods for IRMOFs to enhance CO₂ adsorption performance.

Key words： carbon dioxide; isoreticular metal-organic frameworks material; adsorption; specific surface area; pore diameter

参考文献

[1] Kember M R,Williams C K.Efficient magnesium catalysts for the copolymerization of epoxides and CO₂;using water to synthesize polycarbonate polyols[J].Journal of the American Chemical Society,2012,134(38):15676-15679.
[2] Bustamante F,Orrego A F,Villegas S,et al.Modeling of chemical equilibrium and gas phase behavior for the direct synthesis of dimethyl carbonate from CO₂ and methanol[J].Ind Eng Chem Res,2012,51(26):8945-8956.
[3] Chang F,Yang H J,Jin J,et al.Solubilities and partial molar volumes of 1-methypropanedioate derivatives in supercritical carbon dioxide[J].Fluid Phase Equilibria,2012,334(334):43-50.
[4] Yu H,Xiang Q,Fang M,et al.Promoted CO₂ absorption in aqueous ammonia[J].Greenhouse Gases Science & Technology,2012,2(3):200-208.
[5] 赵倩,冯东,汪洋,等.配位不饱和金属-有机骨架材料吸附CO₂的研究进展[J].化工进展,2017,36(5):1771-1781.
[6] Zukal A,Dominguez I,Mayerová J,et al.Functionalization of delaminated zeolite ITQ-6 for the adsorption of carbon dioxide[J].Langmuir the ACS Journal of Surfaces & Colloids,2009,25(17):10314-10321.
[7] Xu X,Zhao X,Sun L,et al.Adsorption separation of carbon dioxide,methane,and nitrogen on Hβ and Na-exchanged β-zeolite[J].Journal of Natural Gas Chemistry,2008,17(4):391-396.
[8] Kim B J,Cho K S,Park S J.Copper oxide-decorated porous carbons for carbon dioxide adsorption behaviors[J].Journal of Colloid & Interface Science,2010,342(2):575-578.
[9] Yang Q,Zhong C,Chen,et al.Computational study of CO₂ storage in metal-organic frameworks[J].Journal of Physical Chemistry C,2008,112(5):1562-1569.
[10] Li J R,Kuppler R J,Zhou H C.Selective gas adsorption and separation in metal-organic frameworks[J].Cheminform,2009,38(5):1477-1504.
[11] Forgan R S,Smaldone R A,Gassensmith J J,et al.Nanoporous carbohydrate metal-organic frameworks[J].Journal of the American Chemical Society,2012,134(1):406-417.
[12] Babarao R,Hu Z,Jiang J,et al.Storage and separation of CO₂ and CH₄ in silicalite,C168 schwarzite,and IRMOF-1:a comparative study from monte carlo simulation[J].Langmuir the ACS Journal of Surfaces & Colloids,2007,23(2):659-666.
[13] Eddaoudi M.Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage[J].Science,2002,295(5554):469-472.
[14] Jic R,Millward A R,Park K S,et al.Hydrogen sorption in functionalized metal-organic frameworks[J].Journal of the American Chemical Society,2004,126(18):5666-5667.
[15] Jia C.Metal-organic frameworks (MOFs) as hydrogen storage materials[J].Progress in Chemistry,2009,21(9):1954-1962.
[16] Xu Q,Liu D,Yang Q,et al.Li-modified metal-organic frameworks for CO₂/CH₄ separation:a route to achieving high adsorption selectivity[J].Journal of Materials Chemistry,2010,20(4):706-714.
[17] Millward A R,Yaghi O M.Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature[J].Journal of the American Chemical Society,2005,127(51):17998-17999.
[18] Kim D,Lee T B,Sang B C,et al.A density functional theory study of a series of functionalized metal-organic frameworks[J].Chemical Physics Letters,2006,420(1):256-260.
[19] Babarao R,Jiang J.Molecular screening of metal-organic frameworks for CO₂ storage[J].Langmuir the ACS Journal of Surfaces & Colloids,2008,24(12):6270.
[20] Surblé S,Millange F,Serre C,et al.Synthesis of MIL-102,a chromium carboxylate metal-organic framework,with gas sorption analysis[J].Journal of the American Chemical Society,2006,128(46):14889-14896.
[21] 姜宁,邓志勇,王公应,等.金属有机框架材料的制备及在吸附分离CO₂中的应用[J].化学进展,2014,26(10):1645-1654.
[22] Mckinstry C,Cussen E J,Fletcher A J,et al.Effect of synthesis conditions on formation pathways of metal organic framework (MOF-5) crystals[J].Crystal Growth & Design,2013,13(12):5481-5486.
[23] Tranchemontagne D J,Hunt J R,Yaghi O M.Room temperature synthesis of metal-organic frameworks:MOF-5,MOF-74,MOF-177,MOF-199,and IRMOF-0[J].Tetrahedron,2008,64(36):8553-8557.
[24] Rodríguez N A,Parra R,Grela M A.Structural characterization,optical properties and photocatalytic activity of MOF-5 and its hydrolysis products:implications on their excitation mechanism[J].RSC Advances,2015,5(89):73112-73118.
[25] Tranchemontagne D J,Park K S,Furukawa H,et al.Hydrogen storage in new metal-organic frameworks[J].The Journal of Physical Chemistry C,2012,116(24):13143-13151.
[26] Yang Q,Zhong C.Molecular simulation of carbon dioxide/methane/hydrogen mixture adsorption in metal-organic frameworks[J].The Journal of Physical Chemistry B,2006,110(36):17776-17783.
[27] 张所瀛,刘红,刘朋飞,等.金属有机骨架材料在CO₂/CH₄吸附分离中的研究进展[J].化工学报,2014,65(5):1563-1570.
[28] Furukawa H,Ko N,Go Y B,et al.Ultrahigh porosity in metal-organic frameworks[J].Science,2010,329(5990):424-428.
[29] 梁倩,赵震.金属有机骨架材料储存CO₂的研究进展[J].工业催化,2010,18(7):1.
[30] Keskin S,Sholl D S.Screening metal-organic framework materials for membrane-based methane/carbon dioxide separations[J].The Journal of Physical Chemistry C,2007,111(38):14055-14059.
[31] Sarkisov L,Düren T,Snurr R Q.Molecular modelling of adsorption in novel nanoporous metal-organic materials[J].Molecular Physics,2004,102(2):211-221.
[32] Jiang J,Sandler S I.Monte carlo simulation for the adsorption and separation of linear and branched alkanes in IRMOF-1[J].Langmuir,2006,22(13):5702-5707.
[33] Dubbeldam D,Frost H,Walton K S,et al.Molecular simulation of adsorption sites of light gases in the metal-organic framework IRMOF-1[J].Fluid Phase Equilibria,2007,261(1):152-161.
[34] Santos K M C,Santos R J O,Alves M M D A,et al.Effect of high pressure CO₂ sorption on the stability of metalorganic framework MOF-177 at different temperatures[J].Journal of Solid State Chemistry,2019,269:320-327.
[35] Xue C,Zhong C.Molecular simulation study of hexane diffusion in dynamic metal-organic frameworks[J].Chinese Journal of Chemistry,2010,27(3):472-478.
[36] Dubbeldam D,Walton K S,Ellis D E,et al.Exceptional negative thermal expansion in isoreticular metal-organic frameworks[J].Angewandte Chemie International Edition,2007,46(24):4496-4499.
[37] Walton K S,Millward A R,Dubbeldam David,et al.Understanding inflections and steps in carbon dioxide adsorption isothermsin metal-organic frameworks[J].Journal of the American Chemical Society,2008,130(2):406-407.
[38] Yang Qingyuan,Zhong Chongli.Electrostatic-field-induced enhancement of gas mixture separation in metal-organic frameworks:a computational study[J].Chemphyschem,2006,7(7):1417-1421.
[39] 安晓辉,刘大欢,仲崇立.二氧化碳在金属-有机骨架材料中吸附的阶梯现象[J].物理化学学报,2011,27(3):553-558.
[40] Kaye S S,Dailly A,Yaghi O M,et al.Impact of preparation and handling on the hydrogen storage properties of Zn₄O(1,4-benzenedicarboxylate) 3 (MOF-5)[J].Journal of the American Chemical Society,2007,129(46):14176-14177.
[41] Greathouse J A,Allendorf M D.The interaction of water with MOF-5 simulated by molecular dynamics[J].Journal of the American Chemical Society,2006,128(33):10678-10679.
[42] Yang J,Grzech A,Mulder F M,et al.Methyl modified MOF-5:a water stable hydrogen storage material[J].Chemical Communications,2011,47(18):5244-5246.
[43] Flaig R W,Osborn Popp T M,Fracaroli A M,et al.The chemistry of CO₂ capture in an amine-functionalized metal-organic framework under dry and humid conditions[J].Journal of the American Chemical Society,2017,139(35):12125-12128.

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