综述与专论

等网状结构MOFs材料的制备及其对CO2捕集的研究进展

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  • 昆明理工大学化学工程学院,昆明 650500
唐一桐(1996-),男,硕士研究生,主要从事环境化工及资源化利用研究工作。

收稿日期: 2019-05-08

  修回日期: 2020-05-04

  网络出版日期: 2020-10-20

基金资助

国家自然科学基金(21666011)

Research progress on preparation of IRMOFs material and its application of CO2 capture

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  • Faculty of Chemical Engineering,Kunming University of Science and Technology, Kunming 650500

Received date: 2019-05-08

  Revised date: 2020-05-04

  Online published: 2020-10-20

摘要

化石燃料的大量燃烧导致全球CO2排放过度,给全球气候带来了严重的影响。金属-有机框架(MOFs)材料作为一种CO2物理吸附剂因吸附量大成为吸附CO2的主力军并展现了巨大的节能环保潜力。相较于其他MOFs材料,具有等网状结构的MOFs(IRMOFs)材料因特殊的结构表现出更出色的CO2吸附性能。从IRMOFs的结构性质出发,概述了目前合成IRMOFs的基本方法,介绍了IRMOFs吸附CO2的原理、吸附效果、吸附选择性、吸附产生的阶梯性现象,以及IRMOFs增强CO2吸附性能的改性方法并展望了IRMOFs未来的发展趋势。

本文引用格式

唐一桐, 李雪霏, 郝博, 赵文波 . 等网状结构MOFs材料的制备及其对CO2捕集的研究进展[J]. 化工新型材料, 2020 , 48(9) : 32 -37 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.09.008

Abstract

With the massive burning of fossil fuels lead to excessive global CO2 emissions and has a serious impact on the global climate.Due to its large adsorption capacity and its great potential for energy conservation and environmental protection,MOFs is the main method of adsorbing CO2.Due to their special structure,the isoreticular metal-organic frameworks (IRMOFs) has the better CO2 adsorption performance than other MOFs materials.The structural properties of IRMOFs were shown,and listed several basic methods for synthesizing IRMOFs.Secondly,the adsorption of CO2 by IRMOFs,the adsorption effect,the adsorption selectivity and the stepped behavior of CO2 adsorption in MOFs were listed.Finally,it listed several modification methods for IRMOFs to enhance CO2 adsorption performance.

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