UiO-66系列材料的制备及其吸附分离CO<sub>2</sub>/CO性能研究

黄兴, 钟瑞琴

doi:10.19817/j.cnki.issn 1006-3536.2020.07.050

化工新型材料 >

2020 , Vol. 48 >Issue 7: 221 - 224

DOI: https://doi.org/10.19817/j.cnki.issn 1006-3536.2020.07.050

科学研究

UiO-66系列材料的制备及其吸附分离CO₂/CO性能研究

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1.内江师范学院,内江641100;
2.中国石油大学(北京)重质油国家重点实验室,北京102249

黄兴(1988-),男,硕士,主要研究方向为纳米多孔骨架材料对气体的吸附与分离。

收稿日期: 2019-03-01

网络出版日期: 2022-11-01

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Study on preparation of UiO-66 series MOF and its gas adsorption and separation in CO₂/CO

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1. Neijiang Normal University,Neijiang 641100;
2. China University of Petroleum,State Key Laboratory of Heavy Oil,Beijing 102249

Received date: 2019-03-01

Online published: 2022-11-01

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摘要

在对苯二甲酸(H₂BDC)苯环上引入不同的取代基,通过与氯化锆(ZrCl₄)和冰乙酸在N,N-二甲基甲酰胺(DMF)中进行溶剂热反应合成UiO-66系列金属有机骨架材料,测试材料对合成气中CO₂,CO的吸附性能。结果表明UiO-66-NH₂对CO₂吸附量最高,为100.14cm³/g,对CO吸附量为17.69cm³/g,在CO₂/CO体系中对CO₂有较高的分离性能。

关键词： 金属有机骨架材料; 二氧化碳; 吸附与分离

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黄兴, 钟瑞琴 . UiO-66系列材料的制备及其吸附分离CO₂/CO性能研究[J]. 化工新型材料, 2020 , 48(7) : 221 -224 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.07.050

Abstract

UiO-66 series metal-organic frameworks(MOF) were synthesized with zirconium chloride (ZrCl₄) and 1,4-benzenedicarboxylic acid (H₂BDC) which different functional groups were employed in hydrothermal condition modified by acetic acid in dimethyl formamide (DMF) solution.The CO₂ and CO sorption was tested which indicated that the highest uptake of CO₂ belonged to UiO-66-NH₂ which the corresponding value was 100.14cm³/g,otherwise the uptake of CO was 17.69cm³/g,which had good adsorption property for CO₂.

Key words： metal-organic frameworks; CO₂; adsorption and separation

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