科学研究

UiO-66系列材料的制备及其吸附分离CO2/CO性能研究

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  • 1.内江师范学院,内江641100;
    2.中国石油大学(北京)重质油国家重点实验室,北京102249
黄兴(1988-),男,硕士,主要研究方向为纳米多孔骨架材料对气体的吸附与分离。

收稿日期: 2019-03-01

  网络出版日期: 2022-11-01

Study on preparation of UiO-66 series MOF and its gas adsorption and separation in CO2/CO

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  • 1. Neijiang Normal University,Neijiang 641100;
    2. China University of Petroleum,State Key Laboratory of Heavy Oil,Beijing 102249

Received date: 2019-03-01

  Online published: 2022-11-01

摘要

在对苯二甲酸(H2BDC)苯环上引入不同的取代基,通过与氯化锆(ZrCl4)和冰乙酸在N,N-二甲基甲酰胺(DMF)中进行溶剂热反应合成UiO-66系列金属有机骨架材料,测试材料对合成气中CO2,CO的吸附性能。结果表明UiO-66-NH2对CO2吸附量最高,为100.14cm3/g,对CO吸附量为17.69cm3/g,在CO2/CO体系中对CO2有较高的分离性能。

本文引用格式

黄兴, 钟瑞琴 . UiO-66系列材料的制备及其吸附分离CO2/CO性能研究[J]. 化工新型材料, 2020 , 48(7) : 221 -224 . DOI: 10.19817/j.cnki.issn 1006-3536.2020.07.050

Abstract

UiO-66 series metal-organic frameworks(MOF) were synthesized with zirconium chloride (ZrCl4) and 1,4-benzenedicarboxylic acid (H2BDC) which different functional groups were employed in hydrothermal condition modified by acetic acid in dimethyl formamide (DMF) solution.The CO2 and CO sorption was tested which indicated that the highest uptake of CO2 belonged to UiO-66-NH2 which the corresponding value was 100.14cm3/g,otherwise the uptake of CO was 17.69cm3/g,which had good adsorption property for CO2.

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