水系锌离子电池钒基氧化物正极材料研究进展

刘超群; 崔心蕾; 王哲禹; 白晓波; 迟彩霞

doi:10.19817/j.cnki.issn1006-3536.2025.05.014

化工新型材料 >

2025 , Vol. 53 >Issue 5: 55 - 60

DOI: https://doi.org/10.19817/j.cnki.issn1006-3536.2025.05.014

综述与专论

水系锌离子电池钒基氧化物正极材料研究进展

刘超群 ,
崔心蕾 ,
王哲禹 ,
白晓波 ,
迟彩霞

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绥化学院黑龙江省环境催化与储能材料重点实验室,绥化 152000

刘超群(1991-),男,助教,硕士,研究方向为功能材料制备与应用,E-mail:liuchaoqun1104@163.com。

迟彩霞(1981-),女,教授,博士,研究方向为功能材料制备与应用,E-mail:chicaixia617@163.com。

收稿日期: 2024-04-15

修回日期: 2024-12-17

网络出版日期: 2025-05-21

基金资助

黑龙江省省属本科高校基本科研业务费项目(YWK10236210237);黑龙江省自然科学基金(LH2020B016);绥化学院科研创新团队项目(SIT05001);绥化学院大学生创新创业训练项目(shxy202318)

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Recent advances on vanadium-based oxide cathode materials for aqueous zinc-ion batteries

Liu Chaoqun ,
Cui Xinlei ,
Wang Zheyu ,
Bai Xiaobo ,
Chi Caixia

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Heilongjiang Province Key Laboratory of Environmental Catalysis and Energy Storage Materials,Suihua University,Suihua 152000

Received date: 2024-04-15

Revised date: 2024-12-17

Online published: 2025-05-21

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摘要

水系锌离子电池因具有高能量密度、安全和价格低廉等优势而受到广泛关注。正极材料是限制水系锌离子电池发挥优异电化学性能的关键。在正极材料中,钒基氧化物以丰富的电子价态及利于储能的层状结构所带来的高容量和优异的倍率性能而备受关注。但钒基材料较差的动力学和不稳定的晶体结构降低了电极材料的容量性能和循环稳定性。介绍了钒基氧化物正极材料的储能机理,综述了嵌入工程、缺陷工程以及合成复合材料等提高钒基氧化物正极材料电化学性能的方法,并展望了其未来的发展前景。

关键词： 水系锌离子电池; 正极材料; 钒基氧化物; 改性

本文引用格式

刘超群 , 崔心蕾 , 王哲禹 , 白晓波 , 迟彩霞 . 水系锌离子电池钒基氧化物正极材料研究进展[J]. 化工新型材料, 2025 , 53(5) : 55 -60 . DOI: 10.19817/j.cnki.issn1006-3536.2025.05.014

Abstract

Aqueous Zinc-ion batteries(AZIBs)have attracted considerable attentions because of their high energy density,inherent safety and low cost.The cathode material is the key to limit the excellent electrochemical performance of aqueous zinc-ion batteries.Among diverse array of cathode materials,vanadium-based oxides have garnered wide concern on account of unique advantages such as high capacity and excellent rate capability,which can be attributed to their abundant electronic valence state and intrinsic layered structure.However,sluggish kinetics and unstable crystal structure lead to poor capacity and cyclic stability.The energy storage mechanism of vanadium-based oxide cathode materials was introduced.The methods of embedding engineering,defect engineering and composite materials to improve the electrochemical performance of vanadium-based oxide cathode materials were reviewed.Its future development prospects was also discussed.

Key words： aqueous zinc-ion batteries; cathode material; vanadium-based oxides; modification

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