综述与专论

煤沥青基高性能碳材料制备方法研究进展

  • 郭洁敏 ,
  • 刘永梅 ,
  • 胡晓婷 ,
  • 赵小雨 ,
  • 申曙光
展开
  • 太原理工大学化学工程与技术学院,太原 030024
郭洁敏(1997-),女,硕士研究生,主要从事煤沥青基高性能碳材料绿色高值化应用研究工作,E-mail:1394328847@qq.com。
申曙光(1969-),男,教授,从事能源环境化工研究工作,E-mail:shenshuguang@tyut.edu.cn。

收稿日期: 2024-04-17

  修回日期: 2024-12-13

  网络出版日期: 2025-05-21

基金资助

中央引导地方科技发展资金项目(YDZX20201400001783);山西省基础研究计划(20210302123179)

Research progress on preparation methods of high-performance coal tar pitch-based carbon materials

  • Guo Jiemin ,
  • Liu Yongmei ,
  • Hu Xiaoting ,
  • Zhao Xiaoyu ,
  • Shen Shuguang
Expand
  • College of Chemical Engineering and Technology,Taiyuan University of Technology, Taiyuan 030024

Received date: 2024-04-17

  Revised date: 2024-12-13

  Online published: 2025-05-21

摘要

煤沥青具有含碳量较高、产量较高和成本低廉的优点,是制备高性能碳材料的优良原料。介绍了煤沥青改性方法,综述了煤沥青基高性能碳材料如碳微球、针状焦和碳纤维的制备方法,总结了煤沥青改性方法对碳微球的粒径分布和收率、针状焦质量以及碳纤维纺丝性能的影响。

本文引用格式

郭洁敏 , 刘永梅 , 胡晓婷 , 赵小雨 , 申曙光 . 煤沥青基高性能碳材料制备方法研究进展[J]. 化工新型材料, 2025 , 53(5) : 6 -10 . DOI: 10.19817/j.cnki.issn1006-3536.2025.05.008

Abstract

Coal tar pitch has the advantages of high carbon content,high yield,and low cost,making it an excellent raw material for preparing high-performance carbon materials.This article introduced the modification methods of coal tar pitch,reviewed the preparation methods of coal tar pitch-based high-performance carbon materials,such as carbon microspheres,needle coke,and carbon fibers.The effects of coal tar pitch modification methods on the particle size distribution and yield of carbon microspheres,the quality of needle coke,and the spinning performance of carbon fibers were summarized.

参考文献

[1] Wei Y,Chen J,Zhao H,et al.Pressure-strengthened carbon fibers from mesophase pitch carbonization processes[J].The Journal of Physical Chemistry Letters,2022,13(14):3283-3289.
[2] Zhang Y,Liu X,Tian M,et al.Generation and characterization of coal-based needle coke produced by the co-carbonization of coal liquefaction pitch and anthracene oil[J].RSC Advances,2022,12(40):25860-25871.
[3] Wu B,Wang Z,Gong Q M,et al.Fabrication and mechanical properties of in situ prepared mesocarbon microbead/carbon nanotube composites[J].Materials Science and Engineering:A,2008,487(1/2):271-277.
[4] Korkmaz SŞ,Bosnali W,Mülazιmoǧlu E,et al.Voltammetric determination of acrylamide using coal tar pitch modified pencil graphite electrode by SWV[J].Food Analytical Methods,2023,16(11):1738-1745.
[5] Xue H T,Sun Q,Lu R,et al.Pyrolysis of coal pitch-infused melamine foam to construct N-doped carbon anodes for high-performance sodium-ion battery[J].Journal of Electroanalytical Chemistry,2021,902:115809.
[6] Qin F,Tian X,Guo Z,et al.Asphaltene-based porous carbon nanosheet as electrode for supercapacitor[J].ACS Sustainable Chemistry & Engineering,2018,6(11):15708-15719.
[7] Lin X,Zhang Y,Sheng Z,et al.A new strategy for preparation of high-performance onion-like anode material from coal tar pitch residue[J].Journal of Analytical and Applied Pyrolysis,2022,166:105591.
[8] Chen S,Xie S,Fan C,et al.Microstructure and performance of carbonization products of component from soft coal pitch[J].Journal of Saudi Chemical Society,2018,22(3):316-321.
[9] Kim H G,Kim Y S,Kwac L K,et al.Characterization of toluene-and quinoline-insoluble extracted from pyrolysis fuel oil-derived pitch for manufacture of C/C composites[J].International Journal of Precision Engineering and Manufacturing,2018,19(7):1033-1037.
[10] Jiang M,Sun N,Soomro R A,et al.The recent progress of pitch-based carbon anodes in sodium-ion batteries[J].Journal of Energy Chemistry,2021,55:34-47.
[11] 牛泽世,王玉高,申峻,等.煤沥青溶解性及可溶物中的多环芳烃分布[J].煤炭学报,2017,42(5):1311-1318.
[12] 胡春燕,王方丽,闫桂林,等.煤沥青的改性工艺研究进展[J].中国化工贸易,2019,31(36):106.
[13] Sun C,Zhang X,Li C,et al.Recent advances in prelithiation materials and approaches for lithium-ion batteries and capacitors[J].Energy Storage Materials,2020,32:497-516.
[14] 熊杰明,陈潇,孙国娟,等.煤沥青原料性质和反应条件对中间相碳微球粒度分布和形貌的影响[J].清华大学学报(自然科学版),2014,54(3):314-319.
[15] 屈滨,郭明聪,刘书林,等.一种煤沥青基中间相碳微球的制备方法:中国,201410090818.7[P].2014-06-04.
[16] 李冬,郑金欣,田育成,等.以中低温煤焦油为原料生产中间相碳微球的方法:中国,201910250800.1[P].2021-01-12.
[17] 王富孟,邢国政,邢晓晗,等.纳米氧化锌对中间相碳微球粒径的影响[J].炭素技术,2018,37(5):21-25.
[18] Yang Y,Lin Q,Huang Y,et al.Efficient preparation of mesocarbon microbeads by pyrolysis of coal-tar pitch in the presence of rosin[J].Journal of Analytical and Applied Pyrolysis,2011,91(2):310-315.
[19] Li L,He J,Zhang Y,et al.Preparation of mesocarbon microbeads from coal tar pitch with blending of biomass tar pitch[J].Journal of Analytical and Applied Pyrolysis,2021,155:105039.
[20] Yan L,Fang Y,Deng J,et al.Preparation and characterization of mesocarbon microbeads by the Co-polycondensation of high-temperature coal tar pitch and coal pyrolytic extracts[J].Materials,2022,15(15):5136.
[21] 马豪,宋赛鹰,袁满,等.AlCl3催化中温煤沥青制备中间相碳微球的研究[J].炭素技术,2019,38(4):32-36.
[22] Xue Y,Yang C,Lu Y,et al.Modification mechanism of coal-tar pitch-based carbon microspheres by an emulsion method with petroleum pitch[J].New Carbon Materials,2008,23(1):75-80.
[23] Cheng Y,Li T,Li F,et al.Preparation of mesocarbon microbeads and subsequent heating treatment[J].International Journal of Chemical Reactor Engineering,2009,7(1):1-17.
[24] Liu C,Zheng H,Yu K,et al.Direct synthesis of P/O-enriched pitch-based carbon microspheres from a coordinated emulsification and pre-oxidation towards high-rate potassium-ion batteries[J].Carbon,2022,194:176-184.
[25] Yuan M,Cao B,Meng C,et al.Preparation of pitch-based carbon microbeads by a simultaneous spheroidization and stabilization process for lithium-ion batteries[J].Chemical Engineering Journal,2020,400:125948.
[26] Wang X,Guo J,Yang X,et al.Monodisperse carbon microspheres synthesized from asphaltene[J].Materials Chemistry and Physics,2009,113(2/3):821-823.
[27] 宋涛.煤系针状焦生产原理及几种典型生产工艺[J].化工管理,2023(20):144-148.
[28] Zhu Y,Liu H,Xu Y,et al.Preparation and characterization of coal-pitch-based needle coke (part Ⅲ):the effects of quinoline insoluble in coal tar pitch[J].Energy & Fuels,2020,34(7):8676-8684.
[29] Cao Q,Xie X,Li J,et al.A novel method for removing quinoline insolubles and ash in coal tar pitch using electrostatic fields[J].Fuel,2012,96:314-318.
[30] 叶煌,姜秋,孙虹,等.一种用于生产针状焦的原料沥青预处理工艺[J].燃料与化工,2020,51(4):39.
[31] 田亚飞,高峰,马明明,等.煤基精制沥青组成对制备针状焦的影响[J].化工科技,2022,30(2):12-18.
[32] Wei W,Jiang C.Optimizing the preparation process of refined asphalt based on the response surface and preparation of needle coke[J].ACS Omega,2024,9(11):13239-13251.
[33] Tian Y,Huang Y,Yu X,et al.Co-carbonization of medium- and low-temperature coal tar pitch and coal-based hydrogenated diesel oil prepare mesophase pitch for needle coke precursor[J].Advanced Engineering Materials,2021,23(10):2001523.
[34] Xu X,Cui L,Shi J,et al.Effects of co-carbonization of medium and low temperature refined pitch and high temperature refined pitch on the structure and properties of needle coke[J].Journal of Analytical and Applied Pyrolysis,2023,169:105783.
[35] Gao L,Wang Y,Zhao Y,et al.The effect of n-heptane soluble content on the composition and structure of coal tar pitch and the preparation of needle coke[J].Journal of Analytical and Applied Pyrolysis,2023,175:106201.
[36] Li L,Lin X,Zhang Y,et al.Characteristics of the mesophase and needle coke derived from the blended coal tar and biomass tar pitch[J].Journal of Analytical and Applied Pyrolysis,2020,150:104889.
[37] 刘金昌,严作贤,王欣雨,等.沥青基碳纤维的制备工艺、反应机理及调控方法[J].洁净煤技术,2024,30(1):110-123.
[38] Liu Y,Kumar S.Recent progress in fabrication,structure,and properties of carbon fibers[J].Polymer Reviews,2012,52(3):234-258.
[39] Mora E,Blanco C,Prada V,et al.A study of pitch-based precursors for general purpose carbon fibers[J].Carbon,2002,40(14):2719-2725.
[40] Zuo P,Leistenschneider D,Kim Y,et al.Asphaltene thermal treatment and optimization of oxidation conditions of low-cost asphaltene-derived carbon fibers[J].Journal of Industrial and Engineering Chemistry,2021,104:427-436.
[41] Zuo P,Leistenschneider D,Kim Y,et al.The effect of thermal pretreatment temperature on the diameters and mechanical properties of asphaltene-derived carbon fibers[J].Journal of Materials Science,2021,56(27):14964-14977.
[42] Yoo M J,Ko H J,Lim Y S,et al.Modification of isotropic coal-tar pitch by acid treatments for carbon fiber melt-spinning[J].Carbon Letters,2014,15(4):247-254.
[43] Guo J,Li Z,Li B,et al.Hydrogenation of coal tar pitch for improved mesophase pitch molecular orientation and carbon fiber processing[J].Journal of Analytical and Applied Pyrolysis,2023,174:106146.
[44] Mishra A,Saha M,Bhatia G,et al.A comparative study on the development of pitch precursor for general-purpose carbon fibres[J].Journal of Materials Processing Technology,2005,168(2):316-320.
[45] Guo J,Li X,Xu H,et al.Molecular structure control in mesophase pitch via co-carbonization of coal tar pitch and petroleum pitch for production of carbon fibers with both high mechanical properties and thermal conductivity[J].Energy & Fuels,2020,34(5):6474-6482.
[46] Yang Y,Liu X,Xu B,et al.Preparation of vapor-grown carbon fibers from deoiled asphalt[J].Carbon,2006,44(9):1661-1664.
[47] Liu X,Ji W,Zhang Y,et al.The morphology and electrical resistance of long oriented vapor-grown carbon fibers synthesized from coal pitch[J].Carbon,2008,46(1):154-158.
Options
文章导航

/