综述与专论

高导热聚合物/石墨烯热界面材料研究进展

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  • 1.广州特种设备检测研究院,国家石墨烯产品质量检验检测中心(广东),广州 510663;
    2.首钢长治钢铁有限公司,长治 046000
郭华超(1992-),女,硕士研究生,工程师,主要从事聚合物基复合材料制备及性能检测工作,E-mail:862275547@qq.com。
王良旺(1990-),男,博士研究生,高级工程师,主要从事石墨烯材料及其制品研发与检测工作,E-mail:wanglw1990@163.com。

收稿日期: 2023-05-28

  修回日期: 2024-04-23

  网络出版日期: 2024-09-29

基金资助

广州市科技计划项目(202102080303);广东省市场监督管理局科技项目(2024CT16);广东省市场监督管理局科技项目(2021CT05);广州市市场监督管理局科技项目(2020kj23);广州市市场监督管理局科技项目(2021kj16)

Research progress of polymer/graphene thermal interface materials with high thermal conductivity

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  • 1. National Quality Inspection and Testing Center of Graphene Products (Guangdong), Guangzhou Academy of Special Equipment Inspection & Testing,Guangzhou 510663;
    2. Shougang Changzhi Steel & Iron Corporation Limited,Changzhi 046000)

Received date: 2023-05-28

  Revised date: 2024-04-23

  Online published: 2024-09-29

摘要

电子设备和器件的过热问题已严重影响其稳定性、可靠性和使用寿命,热界面材料对于降低电子设备和器件的工作温度至关重要。聚合物与石墨烯复合制备的高导热性能热界面材料广泛应用于消费电子产品、信息技术、医疗设备等方面。在阐述聚合物热界面材料导热机理的基础上,总结了石墨烯的本征特性对聚合物/石墨烯热界面材料导热性能的影响,重点介绍了提高聚合物/石墨烯热界面材料导热性能的方法,最后展望了该材料的发展方向。

本文引用格式

郭华超, 王良旺, 郭志强, 文芳, 何立粮, 熊磊 . 高导热聚合物/石墨烯热界面材料研究进展[J]. 化工新型材料, 2024 , 52(9) : 1 -6 . DOI: 10.19817/j.cnki.issn1006-3536.2024.09.013

Abstract

The overheating problem of electronic devices has seriously affected their stability,reliability,and service life.Thermal interface materials (TIM) are crucial for reducing the operation temperature of electronic devices.The high thermal conductivity TIM prepared by combining polymers with graphene is widely used in consumer electronics,information technology,medical equipment and other fields.In this paper,the thermal conductivity mechanism of polymer TIM was expounded,the influence of the intrinsic characteristics of graphene on the thermal conductivity of composites was summarized,and the methods to improve the thermal conductivity of polymer/graphene TIM were emphatically introduced.Finally,the development directions of TIM were prospected.

参考文献

[1] Yang J W,Yu W,Zhang Y,et al.Graphene double cross-linked thermally conductive hydrogel with low thermal contact resistance,flexibility and self-healing performance[J].International Communications in Heat and Mass Transfer:A Rapid Communications Journal,2021,127:105537.
[2] An D,Cheng S S,Zhang Z Y,et al.A polymer-based thermal management material with enhanced thermal conductivity by introducing three-dimensional networks and covalent bond connections[J].Carbon,2019,155:258-267.
[3] 杜伯学,孔晓晓,肖萌,等.高导热聚合物基复合材料研究进展[J].电工技术学报,2018,33(14):3149-3159.
[4] Zhao H Y,Yu M Y,Liu J,et al.Efficient preconstruction of three-dimensional graphene networks for thermally conductive polymer composites[J].Nano-Micro Letters,2022,14:129.
[5] 刘少刚,王李波,王晓龙,等.高导热网络聚合物基复合材料的研究进展[J].中国塑料,2019,33(8):127-135.
[6] Feng C P,Chen L B,Tian G L,et al.Multifunctional thermal management materials with excellent heat dissipation and generation capability for future electronics[J].ACS Applied Materials & Interfaces,2019,11(20):18739-18745.
[7] 宋厚甫,康飞宇.石墨烯导热研究进展[J].物理化学学报,2022,38(1):1-16.
[8] Tarannum F,Muthaiah R,Danayat S,et al.Chemically edge-carboxylated graphene enhances thermal conductivity of polyetherimide-graphene nanocomposites[J].ACS Applied Materials & Interfaces,2022,14:14753-14763.
[9] 安盟,孙旭辉,陈东升,等.石墨烯基复合热界面材料导热性能研究进展[J].物理学报,2022,71(16):166501.
[10] Wu N,Che S,Li H W,et al.A review of three-dimensional graphene networks for use in thermally conductive polymer composites:construction and applications[J].New Carbon Materials,2021,36(5):911-929.
[11] 张冬丽.导热/介电聚合物基复合材料结构与性能研究[D].北京:北京科技大学,2018.
[12] 吴宇明,虞锦洪,曹勇,等.高导热低填量聚合物基复合材料研究进展[J].复合材料学报,2018,35(4):760-766.
[13] 葛瑛,杨东元,高超锋,等.高导热石墨烯复合材料研究进展[J].上海塑料,2022,50(5):1-7.
[14] Yang X T,Liang C B,Ma T B,et al.A review on thermally conductive polymeric composites:classification,measurement,model and equations,mechanism and fabrication methods[J].Advanced Composites and Hybrid Materials,2018,1:207-230.
[15] 郭华超,黄国家,杨波,等.石墨烯/聚苯乙烯复合材料的研究进展及应用[J].塑料,2020,49(1):139-143.
[16] 寇雨佳,周文英,侯倩文,等.聚合物/石墨烯导热复合材料研究进展[J].中国塑料,2018,32(11):1-6.
[17] Babenko D D,Dmitriev A S,Mikhailova I A.Active thermal interface graphene nanocomposites for thermal control of electronic and power devices[J].Journal of Physics:Conference Series,2022,2150(1):012008.
[18] 王欣,刘谨洋,杜赞纯,等.氟化石墨烯绝缘导热性能及其聚酰亚胺复合材料性能研究进展[J].绝缘材料,2023,56(2):11-18.
[19] 梁运民.聚合物基导热材料的设计、制备及性能分析与预测方法研究[D].武汉:华中科技大学,2021.
[20] 陈沛嘉,葛鑫,梁伟杰,等.聚合物基热界面材料与导热性能研究进展[J].化工进展,2022,41(S1):269-281.
[21] 温变英,崔云超.聚合物本征导热研究进展[J].高分子材料科学与工程,2022,38(7):175-182.
[22] 倪荣凤.导热绝缘聚合物基复合材料的制备与性能研究[D].南京:南京理工大学,2019.
[23] 符博支,高洋洋,冯予星,等.聚合物纳米石墨烯复合材料导热性能研究进展[J].功能材料,2019,50(8):8065-8075.
[24] Lv R C,Ren Y J,Guo H C,et al.Recent progress on thermal conductivity of graphene filled epoxy composites[J].Nano Materials Science,2022(3):4.
[25] 文芳,杨波,李悦,等.石墨烯导热硅橡胶的研究进展[J].化工新型材料,2020,48(7):38-42.
[26] Zhang F,Feng Y Y,Feng W.Three-dimensional interconnected networks for thermally conductive polymer composites:design,preparation,properties,and mechanisms[J].Materials Science & Engineering R,2020,142:10058.
[27] Huang X Y,Zhi C Y,Lin Y,et al.Thermal conductivity of graphene-based polymer nanocomposites[J].Materials Science & Engineering R,2020(142):100577.
[28] 李岳,李炯利,朱巧思,等.石墨烯导热材料研究进展[J].材料工程,2021,49(11):1-13.
[29] Guo Y Q,Ruan K P,Shi X T,et al.Factors affecting thermal conductivities of the polymers and polymer composites:a review[J].Composites Science and Technology,2020,193(16):108134.
[30] Hu L,Desai T,Keblinski P.Thermal transport in graphene-based nanocomposite[J].Journal of Applied Physics,2011,110(3):33517.
[31] 余浩斌,张婧婧,何穗华,等.石墨烯微片的尺寸和形态对聚丙烯基纳米复合材料导电导热性能的影响[J].中国塑料,2018,32(3):51-58.
[32] 方明.石墨烯基纳米复合材料的制备及性能[D].上海:复旦大学,2011.
[33] Clausi M,Bayer I S.In-situ graphene alignment in self-sealing stretchable films for efficient thermal interface materials[J].Nano Select,2021,2(2):1-14.
[34] Colonna S,Battegazzore D,Eleuteri M,et al.Properties of graphene-related materials controlling the thermal conductivity of their polymer nanocomposites[J].Nanomaterials,2020,10(11):2167.
[35] Li M Y,Zhou H,Zhang Y,et al.Effect of defects on thermal conductivity of graphene/epoxy nanocomposites[J].Carbon,2018,130:295-303.
[36] Zhang Y,Heo Y J,Son Y R,et al.Recent advanced thermal interfacial materials:a review of conducting mechanisms and parameters of carbon materials[J].Carbon,2018,142:445-460.
[37] Mohamed M,Omar M N,Ishak M S A,et al.Comparison between CNT thermal interface materials with graphene thermal interface material in term of thermal conductivity[J].Materials Science Forum,2020,1010:160-165.
[38] Feng C P,Bai L,Bao R Y,et al.Superior thermal interface materials for thermal management[J].Composites Communications,2019,12:80-85.
[39] 陈海斌,陈瑞,刘美琪,等.基于外力诱导取向的高导热聚合物基复合材料研究进展[J].复合材料学报,2022,39(4):1486-1497.
[40] 黄飞,秦文波,舒登峰,等.碳基填料填充型热界面材料的研究现状[J].高分子材料科学与工程,2023,39(1):160-167.
[41] Chen F Q,Yu P X,Mao L,et al.Simple large-scale method of recycled graphene films vertical arrangement for superhigh through-plane thermal conductivity of epoxy composites[J].Composites Science and Technology,2021,215(1):109026.
[42] Guo Y Q,Pan L L,Yang X T,et al.Simultaneous improvement of thermal conductivities and electromagnetic inter-ference shielding performances in polystyrene composites via constructing interconnection oriented networks based on electrospinning technology[J].Composites Part A:Applied Science and Manufacturing,2019,124:105484.
[43] An F,Li X F,Min P,et al.Vertically aligned high-quality graphene foams for anisotropically conductive polymer compo-sites with ultrahigh through-plane thermal conductivities[J].ACS Applied Materials & Interfaces,2018,10(20):17383-17392.
[44] Barani Z,Mohammadzadeh A,Geremew A,et al.Thermal properties of the binary-filler hybrid composites with graphene and copper nanoparticles[J].Advanced Functional Materials,2020(8):30.
[45] 刘家源,唐波,吉利,等.三维石墨烯制备方法及其导热复合材料应用进展[J].化工新型材料,2022,50(8):19-24.
[46] 何静.不同维度导热材料的结构设计及其复合材料的制备与性能研究[D],合肥:中国科学技术大学,2021.
[47] Liu Z D,Chen Y P,Li Y F,et al.Graphene foam-embedded epoxy composites with significant thermal conductivity enhancement[J].Nanoscale,2019,11(38):17600-17606.
[48] Min P,Liu J,Li X F,et al.Thermally conductive phase change composites featuring anisotropic graphene aerogels for real-time and fast-charging solar-thermal energy conversion[J].Advanced Functional Materials,2018,28:1805365.
[49] Liu P F,Li X F,Min P,et al.3D lamellar-structured graphene aerogels for thermal interface composites with high through-plane thermal conductivity and fracture toughness[J].Nano-Micro Letters,2021,13:22-37.
[50] 张振,赵俊,曹明,等.双逾渗结构PVDF/(PA6/BN/AlN)导热复合材料的制备及性能研究[J].化工新型材料,2020,48(7):60-68.
[51] 欧阳泽宇,王珂珂,饶琼,等.石墨烯纳米片/(酚酞聚芳醚酮-环氧树脂)双逾渗导热复合材料的制备和性能[J].复合材料学报,2021,38(3):722-731.
[52] Huang J,Zhu Y,Xu L,et al.Massive enhancement in the thermal conductivity of polymer composites by trapping graphene at the interface of a polymer blend[J].Composites Science and Technology,2016,129:160-165.
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