综述与专论

三元正极材料LiNi0.8Co0.15Al0.05O2制备方法研究进展

展开
  • 青海师范大学物理与电子信息工程学院,西宁 810000
闫晓岑(1998-),女,硕士研究生,主要研究方向为锂离子电池正极材料,E-mail:ddssnzs@foxmail.com。
王甲泰(1984-),男,博士,副教授,主要研究方向为储能材料,E-mail:manvict@foxmail.com。

收稿日期: 2023-01-26

  修回日期: 2024-01-08

  网络出版日期: 2024-06-18

基金资助

青海师范大学中青年科研基金(KJQN2022001)

Research progress in the preparation methods of LiNi0.8Co0.15Al0.05O2 ternary cathode materials

Expand
  • College of Physics and Electronic Information Engineering, Qinghai Normal University, Xining 810000

Received date: 2023-01-26

  Revised date: 2024-01-08

  Online published: 2024-06-18

摘要

层状三元正极材料LiNi0.8Co0.15Al0.05O2(NCA815)具有较高的理论比容量、优异的循环性能和环境友好等优点,被认为是未来极具应用前景的正极材料之一。但是,三元正极材料NCA815在制备过程中存在合成工艺条件苛刻及不同的制备方法会导致材料形貌结构和电化学性能差异等问题。综述了近年来三元正极材料NCA815的制备方法,如高温固相法、化学共沉淀法、溶胶-凝胶法、喷雾热解法及其他新方法,分析了不同制备方法之间的差异以及对材料的影响,并展望了该材料未来的研究方向。

本文引用格式

闫晓岑, 杜成婷, 丁佳琪, 李健, 王甲泰 . 三元正极材料LiNi0.8Co0.15Al0.05O2制备方法研究进展[J]. 化工新型材料, 2024 , 52(6) : 44 -49 . DOI: 10.19817/j.cnki.issn1006-3536.2024.06.008

Abstract

Layered ternary cathode material LiNi0.8Co0.15Al0.05O2 (NCA815) has the advantages of high theoretical specific capacity,excellent cycling performance and environmental friendliness,and is considered as one of the cathode materials with great prospect of application in the future.However,ternary cathode material NCA815 is prepared under harsh synthesis conditions and different preparation methods may lead to differences in the morphological structure and electrochemical properties of the material.Considering this,the preparation methods of ternary cathode material NCA815 in recent years,such as high-temperature solid-phase method,chemical co-precipitation method,sol-gel method,spray pyrolysis method and other new methods,were reviewed in this paper.The differences between different preparation methods and the effects on the material were analyzed,and an outlook on future research direction for this material was discussed.

参考文献

[1] Kang B,Ceder G.Battery materials for ultrafast charging and discharging[J].Nature,2009,458(7235):190-193.
[2] Tarascon J M,Armand M.Issues and challenges facing rechargeable lithium batteries[J].Nature,2001,414(6861):359-367.
[3] Gao Y,Pan Z,Sun J,et al.High-energy batteries:beyond lithium-ion and their long road to commercialisation[J].Nano-Micro Letters,2022,14(1):94.
[4] Berckmans G,Messagie M,Smekens J,et al.Cost projection of state of the art lithium-ion batteries for electric vehicles up to 2030[J].Energies,2017,10(9):1314.
[5] Purwanto A,Yudha C S,Ubaidillah U,et al.NCA cathode material:synthesis methods and performance enhancement efforts[J].Materials Research Express,2018,5(12):122001.
[6] 栗志展,秦金磊,梁嘉宁,等.高镍三元层状锂离子电池正极材料:研究进展、挑战及改善策略[J].储能科学与技术,2022,11(9):2900-2920.
[7] 李军,刘建军,李少芳,等.锂离子电池三元正极材料镍钴铝酸锂的研究进展[J].化工新型材料,2016,44(6):49-51.
[8] 王鼎,黄玥,张旭红,等.镍钴铝酸锂正极材料改性研究进展及展望[J].应用化工,2019,48(9):2180-2183.
[9] 冯海兰,陈彦彬,刘亚飞,等.高能量密度锂离子电池正极材料镍钴铝酸锂(NCA)技术及产业发展现状[J].新材料产业,2015(9):23-27.
[10] 陆俊杰.镍钴铝酸锂三元锂离子电池正极材料的合成及其性能研究[D].扬州:扬州大学,2019.
[11] 叶超.锂离子电池镍钴铝三元正极材料的制备及性能研究[D].广州:华南理工大学,2017.
[12] Ohzuku T,Makimura Y.Layered lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for lithium-ion batteries[J].Chemistry Letters,2001,30(7):642-643.
[13] 王鼎.镍钴铝酸锂(NCA)正极材料的合成与改性研究[D].荆州:长江大学,2020.
[14] 梁鸣.锂离子电池镍钴铝酸锂(NCA)正极材料的制备及改性研究[D].天津:天津理工大学,2018.
[15] Madhavi S,Rao G S,Chowdari B,et al.Effect of aluminium doping on cathodic behaviour of LiNi0.7Co0.3O2[J].Journal of Power Sources,2001,93(1/2):156-162.
[16] Cao H,Xia B,Xu N,et al.Structural and electrochemical characteristics of Co and Al co-doped lithium nickelate cathode materials for lithium-ion batteries[J].Journal of Alloys and Compounds,2004,376(1/2):282-286.
[17] 赵段.Al2O3和LiAlO2包覆LiNi0.8Co0.1Mn0.1O2正极材料的制备及电化学性能研究[D].西宁:青海师范大学,2022.
[18] 张占鹏.锂离子电池三元正极材料的改性及其电化学性能研究[D].哈尔滨:哈尔滨理工大学,2021.
[19] 陈荣.镍钴铝酸锂高镍正极材料的改性制备及性能研究[D].广州:广东工业大学,2019.
[20] 訚硕.镍钴铝三元正极材料的制备方法研究[J].化工管理,2020(18):129-130.
[21] 栾沂铭.锂离子电池正极材料镍钴铝酸锂前驱体制备工艺研究[D].天津:天津大学,2018.
[22] Qiu Z,Zhang Y,Dong P,et al.A ternary oxide precursor with trigonal structure for synthesis of LiNi0.80Co0.15Al0.05O2 cathode material[J].Journal of Solid State Electrochemistry,2017,21:3037-3046.
[23] Xia S,Liu J J,Li F,et al.Structure and morphology evolution in solid-phase synthesis lithium ion battery LiNi0.80Co0.15Al0.05O2 cathode materials with different micro-nano sizes of raw materials[J].Ceramics International,2018,44(8):9294-9302.
[24] Xia S,Li F,Cheng F,et al.Synthesis of spherical fluorine modified gradient Li-ion battery cathode material LiNi0.80Co0.15Al0.05O2 by simple solid phase method[J].Journal of the Electrochemical Society,2018,165(5):1019.
[25] Zhang H,Zhang X,Zeng T,et al.Conversion of residual lithium into fast ionic conductor coating to achieve one-step dou-ble modification strategy in LiNi0.8Co0.15Al0.05O2[J].Journal of Alloys and Compounds,2023,931:167638.
[26] Wu X,Lu J,Han Y,et al.Template-assisted synthesis of LiNi0.8Co0.15Al0.05O2 hollow nanospheres as cathode material for lithium ion batteries[J].Journal of Materials Science,2020,55:9493-9503.
[27] Nie Y,Xiao W,Miao C,et al.Effect of calcining oxygen pressure gradient on properties of LiNi0.8Co0.15Al0.05O2 cathode materials for lithium ion batteries[J].Electrochimica Acta,2020,334:135654.
[28] Seenivasan M,Yang C C,Wu S H,et al.Improving structural and thermal stability of LiNi0.8Co0.15Al0.05O2 by a fast-ionic-conductive LiAlSiO4 surface coating for Li-ion batteries[J].Electrochimica Acta,2021,387:138620.
[29] Ziraki S,Hashemi B,Janghorban K,et al.Effects of different conditions of LiNi0.8Co0.15Al0.05O2 synthesis by co-precipitation method on the microstructural parameters[J].Ionics,2022,28(10):4555-4567.
[30] Zhang F,Fu X,Wang C,et al.Which is the winner between the single-crystalline and polycrystalline LiNi0.80Co0.15Al0.05O2 cathode in the lithium-ion battery?[J].Materials Today Energy,2021,22:100873.
[31] Xiao P,Cao Y,Li W,et al.Simple strategy for synthesizing LiNi0.8Co0.15Al0.05O2 using CoAl-LDH nanosheet-coated Ni(OH)2 as the precursor:dual effects of the buffer layer and synergistic diffusion[J].ACS Applied Materials & Interfaces,2021,13(25):29714-29725.
[32] Zeng T,Zhang C.Influence of the total metal ions concentration and CTAB on the electrochemical properties of NCA cathode synthesized by using urea precipitant[J].Ionics,2020,26:127-139.
[33] Gao T P,Wong K W,Ng K M.High-quality LiNi0.8Co0.15Al0.05O2 cathode with excellent structural stability:suppressed structural degradation and pore defects generation[J].Nano Energy,2020,73:104798.
[34] Liu W,Qin M,Gao C,et al.Green and low-cost synthesis of LiNi0.8Co0.15Al0.05O2 cathode material for Li-ion batteries[J].Materials Letters,2019,246:153-156.
[35] Uygur C S,Pis#x0015f;kin B,Aydinol M.Synthesis of Lix(Ni0.80Co0.15Al0.05)O2 cathodes with deficient and excess lithium using an ultrasonic sound-assisted co-precipitation method for Li-ion batteries[J].Bulletin of Materials Science,2019,42:1-10.
[36] Feng D,Chen Q,Mei Y,et al.Preparation and characterization of LiNi0.8Co0.15Al0.05O2 cathode material from (NH4)2C2O4·2H2O precipitant[J].Journal of Materials Science:Materials in Electronics,2022,33(18):14711-14721.
[37] Dong P,Xia S,Zhang Y,et al.Influence of complexing agent on the structure and electrochemical properties of LiNi0.80Co0.15Al0.05O2 cathode synthesized by sol-gel method:a comparative study[J].Int J Electrochem Sci,2017,12(1):561-575.
[38] Wagner N P,Asheim K,Vullum-Bruer F,et al.Performance and failure analysis of full cell lithium ion battery with LiNi0.8Co0.15Al0.05O2 and silicon electrodes[J].Journal of Power Sources,2019,437:226884.
[39] Zhang F,Wang C,Zhao D,et al.Synergistic effect of sulfolane and lithium difluoro (oxalate) borate on improvement of compatibility for LiNi0.8Co0.15Al0.05O2 electrode[J].Electrochimica Acta,2020,337:135727.
[40] Xie Z,Zhang Y,Min X,et al.One-step bulk and surface co-modification of LiNi0.8Co0.15Al0.05O2 cathode material towards excellent long-term cyclability[J].Electrochimica Acta,2021,379:138124.
[41] Zhang J,Xu S,Hamad K I,et al.High retention rate NCA cathode powders from spray drying and flame assisted spray pyrolysis using glycerol as the solvent[J].Powder Technology,2020,363:1-6.
[42] Purwanto A,Yudha C S,Muhammad K I,et al.Synthesis of LiNi0.8Co0.15Al0.05O2 cathode material via flame-assisted spray pyrolysis method[J].Advanced Powder Technology,2020,31(4):1674-1681.
[43] Leng J,Wang J,Peng W,et al.Highly-dispersed submicrometer single-crystal nickel-rich layered cathode:spray synthesis and accelerated lithium-ion transport[J].Small,2021,17(14):2006869.
[44] Xi Z,Wang Z,Yan G,et al.Hydrometallurgical production of LiNi0.80Co0.15Al0.05O2 cathode material from high-grade nickel matte[J].Hydrometallurgy,2019,186:30-41.
[45] Hsieh C T,Hsu H H,Hsu J P,et al.Infrared-assisted synthesis of lithium nickel cobalt alumina oxide powders as electrode material for lithium-ion batteries[J].Electrochimica Acta,2016,206:207-216.
[46] 张鹏会,李艳春,胡怀生,等.生物炭基光催化剂的制备、性能及环境应用研究进展[J].化工进展,2022,41(1):1-16.
[47] Cheng X,Wang Y,Wang X,et al.Two-step solvothermal synthesis of high capacity LiNi0.8Co0.15Al0.05O2 cathode for Li-ion batteries[J].Journal of the Chinese Chemical Society,2021,68(5):849-857.
[48] Song Z,Cao X,Cui C,et al.Improved preparation efficiency and electrochemical performance of LiNi0.8Co0.15Al0.05O2 cathode material by oxalic acid and freeze-drying[J].Ionics,2021,27(11):4663-4672.
Options
文章导航

/