开发与应用

改性胶原复合气凝胶的制备及其对Cr(Ⅵ)的吸附性能研究

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  • 1.陕西科技大学轻工科学与工程学院,西安 710021;
    2.陕西科技大学,轻化工程国家级实验教学示范中心,西安 710021;
    3.湖南文理学院,水处理功能材料湖南省重点实验室,常德 415000
周建华(1973-),女,博士,教授,主要从事功能高分子材料和复合气凝胶的制备及应用研究,E-mail:zhoujianhua@sust.edu.cn。

收稿日期: 2022-12-09

  修回日期: 2023-10-17

  网络出版日期: 2024-03-28

基金资助

水处理功能材料湖南省重点实验室开放基金课题(KFJJ2101);国家自然科学基金(21978162);咸阳市重点研发计划(2021ZDYF-GY-0037)

Study on preparation of modified collagen composite aerogel and its adsorption performance for Cr(Ⅵ)

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  • 1. College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science & Technology,Xi'an 710021;
    2. National Demonstration Center for Experimental Light Chemistry Engineering Education,Shaanxi University of Science & Technology,Xi'an 710021;
    3. Hunan Provincial Key Laboratory of Water Treatment Functional Materials,Hunan University of Arts and Science,Changde 415000

Received date: 2022-12-09

  Revised date: 2023-10-17

  Online published: 2024-03-28

摘要

采用冷冻干燥法制备了聚多巴胺修饰MXene和氧化海藻酸钠改性胶原(MPAC)复合气凝胶作为吸附剂处理水体中的Cr(Ⅵ)。通过透射电镜(TEM)和扫描电镜(SEM)对聚多巴胺修饰MXene(MXene@PDA)和MPAC复合气凝胶进行表征,并研究了氧化海藻酸钠(OSA)用量、胶原浓度、MXene@PDA用量、溶液pH、吸附温度和吸附时间对Cr(Ⅵ)吸附性能的影响。结果表明:通过PDA成功将MXene包覆,并制备出具有三维多孔网络结构的MPAC复合气凝胶。当MPAC复合气凝胶的OSA用量为10%、胶原浓度为5mg/mL、MXene@PDA用量为60%时,对Cr(Ⅵ)的吸附性能最佳。吸附过程在60min时达到平衡,且吸附容量随着pH和温度的增加而减小。

本文引用格式

周建华, 卢凯, 肖安国, 牛转丽, 刘秀青, 李楠, 陈潇雨 . 改性胶原复合气凝胶的制备及其对Cr(Ⅵ)的吸附性能研究[J]. 化工新型材料, 2024 , 52(3) : 289 -293 . DOI: 10.19817/j.cnki.issn1006-3536.2024.03.041

Abstract

Polydopamine-modified MXene and oxidized sodium alginate-modified collagen (MPAC) composite aerogel was prepared by a freeze-drying method and used as an adsorbent to treat Cr(Ⅵ) in water.The polydopamine-modified MXene (MXene@PDA) and MPAC composite aerogel were characterized by TEM and SEM.The effects of oxidized sodium alginate (OSA) dosage,collagen concentration,MXene@PDA dosage,solution pH,adsorption temperature,and adsorption time on the adsorption performance for Cr(Ⅵ) were studied.The results showed that MXene was successfully coated by PDA,and MPAC composite aerogel with a three-dimensional porous network structure was prepared.When the OSA dosage was 10%,the collagen concentration was 5mg/mL,and the MXene@PDA dosage was 60%,the adsorption performance for Cr(Ⅵ) was the best.The adsorption process reached equilibrium at 60 min,and the adsorption capacity decreased with the increase of pH and temperature.

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