综述与专论

金属有机框架材料的制备及应用研究进展

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  • 1.华北理工大学材料科学与工程学院,河北省无机非金属材料实验室,唐山063210;
    2.河北省(唐山)陶瓷产业技术研究院,唐山063007
庆达(1999-),男,硕士研究生,主要从事光电化学阴极保护研究。

收稿日期: 2022-09-13

  修回日期: 2023-07-26

  网络出版日期: 2024-02-27

基金资助

唐山市科技局项目(21130211D,22130215H);河北省自然科学基金钢铁联合基金(E2021209002)

Research progress on preparation and application of metal-organic frameworks

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  • 1. Hebei Inorganic Nonmetallic Materials Laboratory,School of Materials Science and Engineering,North China University of Science and Technology,Tangshan 063210;
    2. Hebei (Tangshan) Ceramic Industry Technology Research Institute,Tangshan 063007

Received date: 2022-09-13

  Revised date: 2023-07-26

  Online published: 2024-02-27

摘要

金属-有机框架(MOFs)是一种由金属离子团簇和有机配体通过配位键桥连形成的多孔晶态材料,具有高孔隙率、高比表面积、易于功能化修饰等特点,在气体吸附、催化、传感、医药等方面都具有潜在的应用价值。然而,MOFs材料的不同合成方法往往会直接影响材料形貌并导致其性能差异,通过改变合成方法,能够显著改变材料性能并应用于不同领域。综述总结了近年来MOFs材料的多种合成方法及其典型应用进展,并探讨了不同合成方法的优缺点,最后对其未来发展趋势进行了展望。

本文引用格式

庆达, 王建省, 苏新悦, 赵英娜, 曾雄丰 . 金属有机框架材料的制备及应用研究进展[J]. 化工新型材料, 2024 , 52(1) : 65 -70 . DOI: 10.19817/j.cnki.issn1006-3536.2024.01.002

Abstract

Metal-organic frameworks (MOFs) are porous crystalline materials formed by metal ion clusters and organic ligands bridged by coordination bonds.With the characteristics of high porosity,high specific surface area and easy functional modification,they have potential application value in gas adsorption,catalysis,sensing,medicine and so on.Nevertheless,different synthesis methods of MOFs commonly directly affect the morphology of materials and lead to differences in their properties.By modifying the synthesis methods,the properties of materials can be greatly changed and applied in different fields.In this paper,various synthesis methods of MOFs and their typical applications in recent years were summarized,and the advantages and disadvantages of different synthesis methods of MOFs were discussed.Finally,the future development trend of MOFs materials was prospected.

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