MOF及其衍生物复合MXene在储能领域的研究进展

靳彦岭, 耿家慧, 任鹏刚, 侯鑫, 陈争艳, 任芳, 孙振锋

doi:10.19817/j.cnki.issn1006-3536.2023.09.016

化工新型材料 >

2023 , Vol. 51 >Issue 9: 85 - 90

DOI: https://doi.org/10.19817/j.cnki.issn1006-3536.2023.09.016

综述与专论

MOF及其衍生物复合MXene在储能领域的研究进展

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1.西安理工大学印刷包装与数字媒体学院,西安 710048;
2.西安理工大学材料科学与工程学院,西安 710048

靳彦岭(1985-),女,博士,讲师,从事储能材料研究,E-mail:jinyl@xaut.edu.cn

收稿日期: 2023-04-05

修回日期: 2023-06-09

网络出版日期: 2023-09-25

基金资助

国家自然科学基金(52102303和52103095);中国博士后面上基金项目(2019M650268);高分子材料工程国家重点实验室(四川大学)开放课题(sklpme2021-05-09);西安市科技计划项目(22GXFW0092和22GXFW0097)

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Research progress of MOF and its derivatives compounding with MXene in energy storage

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1. Faculty of Printing,Packaging Engineering and Digital Media Technology,Xi'an University of Technology,Xi'an 710048;
2. School of Materials Science and Engineering,Xi'an University of Technology,Xi'an 710048

Received date: 2023-04-05

Revised date: 2023-06-09

Online published: 2023-09-25

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摘要

金属有机骨架(MOF)及其衍生物具有丰富的孔隙率、巨大的表面积和配位不饱和位点,在储能等多领域越来越受到关注。然而,大多数MOF固有的低电导率以及MOF衍生物在循环过程中体积变化限制了进一步发展。MXene具有二维结构,类金属的导电性,可调节的层间距,丰富的表面端基和优异的亲水性,已广泛应用于储能领域。然而,相邻纳米片之间的强范德华相互作用和氢键不可避免地造成MXene纳米片的堆叠,限制了电化学活性。近年来,研究人员综合了MOF及其衍生物与MXene的优势,其复合材料在储能领域表现出优异的性能,广受关注和研究。基于此,综述了MOF及其衍生物与MXene复合材料的制备方法,并介绍其在金属离子电池、超级电容器、锂硫电池等储能领域的应用现状,提出现阶段存在的主要问题并对未来的发展方向作了展望。

关键词： 金属有机骨架; MXene; 复合材料; 储能

本文引用格式

靳彦岭, 耿家慧, 任鹏刚, 侯鑫, 陈争艳, 任芳, 孙振锋 . MOF及其衍生物复合MXene在储能领域的研究进展[J]. 化工新型材料, 2023 , 51(9) : 85 -90 . DOI: 10.19817/j.cnki.issn1006-3536.2023.09.016

Abstract

Metal-organic framework (MOF) and its derivatives possess rich porosity,huge surface area and coordination unsaturated sites,and are attracting more and more attention in many fields such as energy storage.However,the inherent low conductivity of most MOF and the volume expansion of MOF derivatives during the cycle limit further development.With two-dimensional structure,metal-like conductivity,adjustable layer spacing,abundant surface end bases and excellent hydrophilicity,MXene has been widely used in the field of energy storage.However,strong van der Waals interactions and hydrogen bonds between adjacent nanosheets inevitably lead to stacking of MXene nanosheets,limiting the electrochemical activity.In recent years,researchers have combined the advantages of MOF and its derivatives with MXene,and their composites have shown excellent performance in the field of energy storage,which has attracted wide attention and research.Based on this,the preparation methods of MOF and its derivatives with MXene composites were reviewed,and their applications in metal-ion batteries,supercapacitors,lithium-sulfur batteries and other energy storage fields were introduced.The main existing challenges in the current stage and the future development directions were discussed.

Key words： metal-organic framework; MXene; composite; energy storage

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