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无机水合盐相变储能材料研究进展

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  • 中国科学院青海盐湖研究所,青海省盐湖资源化学重点实验室,西宁 810008
孙世平(1994-),男,硕士,主要从事新能源材料应用研究工作,E-mail:ssp1717@163.com。

收稿日期: 2021-12-29

  修回日期: 2022-11-17

  网络出版日期: 2023-04-27

基金资助

青海省科技成果转化专项项目—前补助—高新处(2020-GX-108)

Research progress of inorganic hydrated salt phase change energy storage materials

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  • Key Laboratory of Salt Lake Resource Chemistry of Qinghai Province,Qinghai Institute of Salt Lakes,Chinese Academy of Science,Xining 810008

Received date: 2021-12-29

  Revised date: 2022-11-17

  Online published: 2023-04-27

摘要

无机水合盐相变储能材料(PCMs)具有化学性质稳定、工作温度恒定、相变温度适中、相变潜热及导热系数大、潜热值高、成本低等优点,在实际的生产生活中具有广阔的使用前景和发展空间。然而,过冷、相分离、导热系数问题、循环稳定性差等问题限制了此材料的实际应用。主要介绍了无机水合盐相变储能材料最新的研究进展和成果、分类以及解决过冷度和相分离等问题的改性方法,最后,指出了目前水合盐相变储能材料存在的不足并对未来的重点研究方向做出了展望。

本文引用格式

孙世平, 李翔, 申月, 任秀峰, 曾金波, 孙艳霞, 海春喜 . 无机水合盐相变储能材料研究进展[J]. 化工新型材料, 2023 , 51(4) : 26 -31 . DOI: 10.19817/j.cnki.issn1006-3536.2023.04.005

Abstract

Inorganic hydrated salt phase change energy storage materials (PCMs) have the advantages of stable chemical properties,constant working temperature,moderate phase change temperature,large phase change latent heat and thermal conductivity,high latent heat value,and low cost,which have broad application prospects and development space in actual production and life.However,many problems,such as supercooling,phase separation,thermal conductivity,poor cycle stability,etc.,limit the practical application of this material.This article mainly introduced the latest research progress and achievements of inorganic hydrated salt phase change energy storage materials,as well as the classification and modification methods to solve the problems of subcooling and phase separation.Finally,it pointed out the shortcomings of hydrated salt phase change energy storage materials and the key research directions in the future.

参考文献

[1] 房满庭,章学来,纪珺,等.水合盐复合相变材料的研究进展[J].储能科学与技术,2019(4):709-717.
[2] 周园,李翔,海春喜,等.水合盐相变储能材料研究[J].盐湖研究,2018,26(2):9-15,47.
[3] Farid M M,Khudhair A M,Razack S,et al.A review on phase change energy storage:materials and applications[J].Energy Conversion and Management,2004,45(9-10):1597-1615.
[4] Wang H,Chen Y,Li J,et al.Review of encapsulated salt hydrate core-shell phase change materials[J].Powder and Particle,2020,37:85-96.
[5] Sogutoglu L C,Donkers P,Fischer H R,et al.In-depth investigation of thermochemical performance in a heat battery:cyclic analysis of K2CO3,MgCl2 and Na2S[J].Applied Energy,2018,215:159-173.
[6] 赵有璟,时历杰,康为清,等.相变温度可调的无机混盐体系相变储能材料[J].材料科学与工程学报,2014,32(1):6.
[7] Lele A F,Kuznik F,Opel O,et al.Performance analysis of a thermochemical based heat storage as an addition to cogeneration systems[J].Energy Conversion & Management,2015,106:1327-1344.
[8] 王晨羽,闫全英,孙相宇,等.二元混合无机水合盐的制备方法研究[J].化工新型材料,2019,47(s1):73-76.
[9] Rammelberg H U,Osterland T,Priehs B,et al.Thermochemical heat storage materials-performance of mixed salt hydrates[J].Solar Energy,136:571-589.
[10] Hasila J,Devrim A,Zhang Y,et al.Review on the recent progress of thermochemical materials and processes for solar thermal energy storage and industrial waste heat recovery[J].International Journal of Low-Carbon Technologies,2018(1):1.
[11] Deng Y,Li J,Nian H.Polyethylene glycol-enwrapped silicon carbide nanowires network/expanded vermiculite composite phase change materials:form-stabilization,thermal energy storage behavior and thermal conductivity enhancement[J].Solar Energy Materials & Solar Cells,2018,174:283-291.
[12] Yi H,Zhan W,Zhao Y,et al.Design of MtNS/SA microencapsulated phase change materials for enhancement of thermal energy storage performances:effect of shell thickness[J].Solar Energy Materials and Solar Cells,2019,200:109935.
[13] Yi H,Ai Z,Zhao Y,et al.Design of 3D-network montmorillonite nanosheet/stearic acid shape-stabilized phase change materials for solar energy storage[J].Solar Energy Materials and Solar Cells,2020,204:110233.
[14] 王佩,曾德军,王波,等.无机盐/莫来石复合相变储能材料的制备与性能研究[J].冶金与材料,2020(4):10-12.
[15] 周龙祥,刘咏,张利珍,等.SiO2包覆CaCl2·2H2O相变纳米复合材料的制备及表征[J].现代化工,2020,40(1):115-119.
[16] Wang X L,Li B,Qu Z G,et al.Effects of graphite microstructure evolution on the anisotropic thermal conductivity of expanded graphite/paraffin phase change materials and their thermal energy storage performance[J].International Journal of Heat and Mass Transfer,2020,155:119853.
[17] Cheng J,Zhou Y,Ma D,et al.Preparation and characterization of carbon nanotube microcapsule phase change materials for improving thermal comfort level of buildings[J].Construction and Building Materials,2020,244:118388.
[18] Li C,Xie B,Chen D,et al.Ultrathin graphite sheets stabilized stearic acid as a composite phase change material for thermal energy storage[J].Energy,2019,166:246-255.
[19] 李文琛,蔡一凡,严泰森,等.三水合醋酸钠/膨胀石墨复合相变材料的制备及其储热性能[J].上海交通大学学报,2020,54(10):9.
[20] Xiao Q,Yuan W,Li L,et al.Fabrication and characteristics of composite phase change material based on Ba(OH)2·8H2O for thermal energy storage[J].Solar Energy Materials and Solar Cells,2018,179:339-345.
[21] Zhang Y N,Wang R Z,Li T X.Thermochemical characterizations of high-stable activated alumina/LiCl composites with multistage sorption process for thermal storage[J].Energy,2018,156:240-249.
[22] Xu S Z,Wang R Z,Wang L W,et al.Performance characterizations and thermodynamic analysis of magnesium sulfate-impregnated zeolite 13X and activated alumina composite sorbents for thermal energy storage[J].Energy,2019,167:889-901.
[23] 陈颖,姜庆辉,辛集武,等.相变储能材料及其应用研究进展[J].材料工程,2019,47(7):1-10.
[24] Cunha J.Thermal energy storage for low and medium temperature applications using phase change materials-a review[J].Applied Energy,2016,177:227-238.
[25] Yd A,Drr A,Nbs B,et al.A review on phase-change materials:mathematical modeling and simulations[J].Renewable and Sustainable Energy Reviews,2011,15(1):112-130.
[26] Liu Y,Liu W,Zhang S,et al.Preparation and characterization of new nano-particle mixed as thermal storage material[J].Applied Thermal Engineering,2019,163:114386.
[27] Li X,Zhou Y,Nian H.Phase change behavior of latent heat storage media based on calcium chloride hexahydrate composites containing strontium chloride hexahydrate and oxidation expandable graphite[J].Applied Thermal Engineering,2016,102:38-44.
[28] Fang Y,Su J,Tang Y,et al.Form-stable Na2SO4 center dot 10H2O-Na2HPO4 center dot 12H2O eutectic/hydrophilic fumed silica composite phase change material with low supercooling and low thermal conductivity for indoor thermal comfort improvement[J].Journal of Energy Research,2020,44(4):3171-3182.
[29] Peng S,Huang J,Wang T,et al.Effect of fumed silica additive on supercooling,thermal reliability and thermal stability of Na2HPO4·12H2O as inorganic PCM[J].Thermochimica Acta,2019,675:1-8.
[30] 邓燕,丁云飞.不同成核剂对Na2HPO4·12H2O相变过冷性能的影响[J].应用化工,2018,47(3):534-536,540.
[31] Fashandi M,Leung S N.Sodium acetate trihydrate-chitin nanowhisker nanocomposites with enhanced phase change performance for thermal energy storage[J].Solar Energy Materials & Solar Cells,2018,178:259-265.
[32] 华维三,章学来,刘锋,等.相变材料复合八水氢氧化钡的制备及热性能[J].化工进展,2018,37(11):269-274.
[33] 丁红雨,李慧星,冯国会.基于相变材料三水醋酸钠蓄热性能实验研究[J].建筑节能,2014(10):42-45.
[34] Xu X,Cui H,Memon S A,et al.Development of novel composite PCM for thermal energy storage using CaCl2 center dot 6H2O with graphene oxide and SrCl2 center dot 6H2O[J].Energy & Buildings,2017,156:163-172.
[35] 杨宜凡,顾晓滨,刘鹏.添加剂对三水醋酸钠的储热性能影响研究[J].广州化工,2017,45(19):84-86,92.
[36] 杜晓冬,章学来,丁锦宏,等.纳米成核剂对三水醋酸钠蓄热性能的影响[J].建筑节能,2017,45(9):25-28,59.
[37] Fu W,Zou T,Liang X,et al.Characterization and thermal performance of microencapsulated sodium thiosulfate pentahydrate as phase change material for thermal energy storage[J].Solar Energy Materials and Solar Cells,2019,193:149-156.
[38] Zhang Z,Lian Y,Xu X,et al.Synthesis and characterization of microencapsulated sodium sulfate decahydrate as phase change energy storage materials[J].Applied Energy,2019,255:113830.
[39] Huang J,Wang T,Zhu P,et al.Preparation,characterization,and thermal properties of the microencapsulation of a hydrated salt as phase change energy storage materials[J].Thermochimica Acta,2013,557:1-6.
[40] Li M,Wang W,Zhang Z,et al.Monodisperse Na2SO4·10H2O@SiO2 microparticles against supercooling and phase separation during phase change for efficient energy storage[J].Industrial & Engineering Chemistry Research,2017,56(12):3297-3308.
[41] Liu Z,Chen Z,Yu F.Preparation and characterization of microencapsulated phase change materials containing inorganic hydrated salt with silica shell for thermal energy storage[J].Solar Energy Materials and Solar Cells,200:110004.
[42] 李玉婷,周永全,葛飞,等.无机水合盐相变储能材料的过冷及相分离研究进展[J].盐湖研究,2018,26(1):81-86.
[43] 郑涛杰,陈志莉,刘强,等.水合盐相变储能材料的增稠剂优选研究[J].太阳能学报,2018,39(7):1781-1787.
[44] Bao X,Yang H,Xu X,et al.Development of a stable inorganic phase change material for thermal energy storage in buildings[J].Solar Energy Materials and Solar Cells,2020,208:110420.
[45] 周鑫晨,章学来,华维三,等.增稠剂对NH4Al(SO4)2·12H2O蓄放热性能的影响[J].化工进展,2019,38(10):14.
[46] 吴东灵,李廷贤,何峰,等.三水醋酸钠相变储能复合材料改性制备及储/放热特性[J].化工学报,2018,69(7):2860-2868.
[47] Mao J,Dong X,Hou P,et al.Preparation research of novel composite phase change materials based on sodium acetate trihydrate[J].Applied Thermal Engineering,2017,118:817-825.
[48] Wu Y,Wang T.Hydrated salts/expanded graphite composite with high thermal conductivity as a shape-stabilized phase change material for thermal energy storage[J].Energy Conversion & Management,2015,101:164-171.
[49] Li T,Wu D,He F,et al.Experimental investigation on copper foam/hydrated salt composite phase change material for thermal energy storage[J].International Journal of Heat & Mass Transfer,2017,115:148-157.
[50] Shen Z,Kwon S,Lee H L,et al.Enhanced thermal energy storage performance of salt hydrate phase change material:effect of cellulose nanofibril and graphene nanoplatelet[J].Solar Energy Materials and Solar Cells,2021,225:111028.
[51] 蒋自鹏,铁生年.芒硝基相变材料性能及其在简易温室中升温效果试验[J].农业工程学报,2016,32(20):209-216.
[52] Zou T,X Liang,Wang S,et al.Effect of expanded graphite size on performances of modified CaCl2·6H2O phase change material for cold energy storage[J].Microporous and Mesoporous Materials,2020,305:110403.
[53] Hou P,Mao J,Liu R,et al.Improvement in thermodynamic characteristics of sodium acetate trihydrate composite phase change material with expanded graphite[J].Journal of Thermal Analysis & Calorimetry,2019.137(4):1295-1306.
[54] 盛强,邢玉明.Ba(OH)2·8H2O/泡沫铜相变复合材料的制备及传热性能[J].复合材料学报,2014,31(6):7.
[55] Cui W,Yuan Y,Sun L,et al.Experimental studies on the supercooling and melting/freezing characteristics of nano-copper/sodium acetate trihydrate composite phase change materials[J].Renewable Energy,2016,99:1029-1037.
[56] 汪翔,章学来,华维三,等.Na2HPO4·12H2O相变储能复合材料制备及热物性[J].化工进展,2019,38(12):5457-5464.
[57] 高剑晨,赵炳晨,何峰,等.六水硝酸镁相变储热复合材料改性制备及储/放热性能研究[J].化工学报,2021,72(6):3328-3337.
[58] 韩兴超,章学来,华维三,等.成核剂对相变材料Ba(OH)2·8H2O储热特性的影响[J].化工进展,2018,37(7):2727-2733.
[59] Zhu X,Vinokurov V,Kopitsyn D,et al.Sepiolite nanocarriers as a matrix for controlled thermal energy storage[J].ACS Omega,2021,6(39):25828-25834.
[60] 陈跃,纪珺,徐笑锋,等.十二水磷酸氢二钠纳米复合相变材料的过冷特性[J].化工进展,2018,37(7):285-290.
[61] 徐笑锋,章学来,李玉洋,等.十水硫酸钠低温相变材料的制备及稳定性[J].化学工程,2018,46(10):6.
[62] 凡海川,李玉香,郑召,等.不同粒径膨胀蛭石制备复合相变材料试验研究[J].非金属矿,2018,41(6):63-66.
[63] Shkatulov A I,Joosten R,Fischer H R,et al.Core-shell encapsulation of salt hydrates into mesoporous silica shells for thermochemical energy storage[J].ACS Applied Energy Materials,2020,3(7):6860-6869.
[64] Zhang W,Zhang Y,Ling Z,et al.Microinfiltration of Mg(NO3)2·6H2O into g-C3N4 and macroencapsulation with commercial sealants:a two-step method to enhance the thermal stability of inorganic composite phase change materials[J].Applied Energy,2019,253:113540.
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