甲烷为燃料的固体氧化物燃料电池钙钛矿基阳极的研究进展

闫飞, 董润泽, 杨浦, 李萍

doi:10.19817/j.cnki.issn1006-3536.2022.06.013

化工新型材料 >

2022 , Vol. 50 >Issue 6: 71 - 74

DOI: https://doi.org/10.19817/j.cnki.issn1006-3536.2022.06.013

综述与专论

甲烷为燃料的固体氧化物燃料电池钙钛矿基阳极的研究进展

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1.华北电力大学(保定)环境科学与工程系,保定 071003;
2.河北省燃煤电站烟气多污染物协同控制重点实验室,华北电力大学(保定),保定 071003

闫飞(1990-),男,博士,讲师,研究方向为固体氧化物燃料电池,E-mail:yanfeiican@tju.edu.cn。

收稿日期: 2021-03-10

修回日期: 2022-02-11

网络出版日期: 2022-07-06

基金资助

中央高校基本科研业务费专项资金(2020MS124和2020MS126);河北省自然科学基金项目(B2020502002和B2020502003)

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Research progress on perovskite based anode for methane fuel SOFC

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1. North China Electric Power University,Baoding Campus,Department of Environmental Science and Engineering,Baoding 071003;
2. Hebei Key Laboratory of Power Plant Flue Gas Multi-Pollutants Control,Department of Environmental Science and Engineering, North China Electric Power University,Baoding 071003

Received date: 2021-03-10

Revised date: 2022-02-11

Online published: 2022-07-06

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摘要

甲烷为燃料的固体氧化物燃料电池(SOFC)可有效地缓解能源危机和环境污染。钙钛矿基阳极材料表现出良好的抗积碳性能,被认为是传统金属阳极材料的良好替代。综述了钙钛矿基阳极催化剂的研究进展,包括钙钛矿型、双钙钛矿型以及相转变型钙钛矿阳极材料。目前,钙钛矿和双钙钛矿型阳极材料需要进一步提高材料的催化活性,降低操作温度;而对于相转变型钙钛矿材料,目前关键的问题是弄清其相转变-原位自组装机理,构筑高催化活性、高稳定性的阳极材料。

关键词： 甲烷; 固体氧化物燃料电池; 阳极; 钙钛矿

本文引用格式

闫飞, 董润泽, 杨浦, 李萍 . 甲烷为燃料的固体氧化物燃料电池钙钛矿基阳极的研究进展[J]. 化工新型材料, 2022 , 50(6) : 71 -74 . DOI: 10.19817/j.cnki.issn1006-3536.2022.06.013

Abstract

Solid oxide fuel cell (SOFC) fueled by methane can effectively alleviate energy crisis and environmental pollution.Perovskite-based anode materials exhibit good carbon deposition resistance,and are considered to be a good substitute for traditional metal anode materials.The research progress of perovskite-based anode catalysts was reviewed,including perovskite type,double perovskite type and phase transition type perovskite anode materials.At present,perovskite and double perovskite anode materials was need to further improve the catalytic activity,and reduced the operating temperature.For the phase transformation perovskite materials,the key problem was to clarify the phase transition in situ self-assembly mechanism,and to construct high catalytic activity and high stability anode materials.

Key words： methane; solid oxide fuel cell; anode; perovskite

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