开发与应用

泡沫材料负载TiO2光催化剂的研究进展

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  • 中国矿业大学化工学院,徐州221116
杨玉寒(1997-),男,硕士研究生,主要从事光催化材料研究,E-mail:425012157@qq.com。

收稿日期: 2020-07-23

  修回日期: 2021-07-08

  网络出版日期: 2021-12-13

基金资助

国家自然科学基金(21706276和51674260)

Research progress on TiO2 photocatalyst supported on foam material

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  • School of Chemical Engineering,China University of Mining and Technology,Xuzhou 221116

Received date: 2020-07-23

  Revised date: 2021-07-08

  Online published: 2021-12-13

摘要

TiO2是一种光催化性能非常好的半导体材料,将其固载在合适的基质上形成复合催化剂可以达到化学性质稳定、易于回收、降低成本等目的。泡沫材料凭借其比表面积大、流体流动阻力小等优点,是负载TiO2的优良载体,有望解决TiO2规模化应用的问题。从TiO2光催化原理入手,分别介绍了有机泡沫材料、泡沫金属、泡沫陶瓷负载TiO2复合光催化剂的研究进展。最后结合泡沫材料负载TiO2光催化剂的现状,展望未来泡沫材料负载TiO2复合光催化剂的研究方向。

本文引用格式

杨玉寒, 杨小芹, 庞军国, 秦志宏, 林喆, 陈强 . 泡沫材料负载TiO2光催化剂的研究进展[J]. 化工新型材料, 2021 , 49(11) : 294 -299 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.11.060

Abstract

TiO2 is a kind of semiconductor material with very good photocatalytic performance.Immobilizing it on a suitable substrate to form a composite catalyst can achieve the purpose of stable chemical properties,easy recovery,and cost reduction.The foam materials are excellent carriers for supporting TiO2 by virtue of their large specific surface area and low fluid flow resistance.It is expected to solve the problem of large-scale application of TiO2.Starting from the principle of TiO2 photocatalysis,the research progress of organic foam materials,foam metals,and foam ceramics supported TiO2 photocatalysts were introduced.Finally,combined with the current status of foam material-loaded TiO2 composites,the future research direction of the photocatalysts was prospected.

参考文献

[1] Fujishima A,Honda K.Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238:37-38.
[2] Dahl M,Liu Y,Yin Y.Composite titanium dioxide nanomaterials[J].Chemical Reviews,2014,114(19):9853-9889.
[3] Mamaghani A H,Haghighat F,Lee C S.Hydrothermal/solvothermal synthesis and treatment of TiO2 for photocatalytic degradation of air pollutants:preparation,characterization,properties,and performance[J].Chemosphere,2019,219:804-825.
[4] Wang C,Cao M,Wang P,et al.Preparation of graphene-carbon nanotube-TiO2 composites with enhanced photocatalytic activity for the removal of dye and Cr(Ⅵ)[J].Applied Catalysis A:General,2014,473:83-89.
[5] Malato S,Maldonado M I,Blanco J,et al.Decontamination and disinfection of water by solar photocatalysis:recent overview and trends[J].Catalysis Today,2009,147(1):1-59.
[6] Karran W,Georgios P,Wolfgang S.Photocatalytic carbon-nanotube-TiO2 composites[J].New Journal of Chemistry,2011,35(2):353-359.
[7] Yan X J,Li L Z.Regenration methods of deactivated photocatalyst:a review[J].Advances in Environmental Protection,2015,5(5):113-118.
[8] Fernández A,Lassaletta G,Jiménez V M,et al.Preparation and characterization of TiO2 photocatalysts supported on various rigid supports (glass,quartz and stainless steel).comparative studies of photocatalytic activity in water purification[J].Applied Catalysis B:Environmental,1995,7(1-2):49-63.
[9] Petronella F,Truppi A,Ingrosso C,et al.Nanocomposite materials for photocatalytic degradation of pollutants[J].Catalysis Today,2017,281(1):85-100.
[10] 胡海.泡沫金属负载纳米TiO2的制备、表征及其光催化性能的研究[D].上海:上海交通大学,2007.
[11] Aminian M K,Taghavinia N,Irajizad A,et al.Adsorption of TiO2 nanoparticles on glass fibers[J].The Journal of Physical Chemistry C,2007,111(27):9794-9798.
[12] Dunlop P S M,Galdi A,McMurray T A,et al.Comparison of photocatalytic activities of commercial titanium dioxide powders immobilised on glass substrates[J].Journal of Advanced Oxidation Technologies,2010,13(1):99-106.
[13] Sirirerkratana K,Kemacheevakul P,Chuangchote S.Color removal from wastewater by photocatalytic process using titanium dioxide-coated glass,ceramic tile,and stainless steel she-ets[J].Journal of Cleaner Production,2019,215:123-130.
[14] Abdennouri M,Baâlala M,Galadi A,et al.Photocatalytic degradation of pesticides by titanium dioxide and titanium pillared purified clays[J].Arabian Journal of Chemistry,2016,9:S313-S318.
[15] Srikantha B,Goutham R,Badri Narayan R,et al.Recent advancements in supporting materials for immobilised photocatalytic applications in waste water treatment[J].Journal of Environmental Management,2017,200:60-78.
[16] Al-Mamun M R,Kader S,Islam M S,et al.Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment:a review[J].Journal of Environmental Chemical Engineering,2019,7(5):103248.
[17] 关磊,张力嫱,张宇航,等.三维多孔泡沫石墨烯的制备与应用研究进展[J].合成化学,2018,26(5):383-388.
[18] 刘芳,樊丰涛,吕玉翠,等.石墨烯/TiO2复合材料光催化降解有机污染物的研究进展[J].化工学报,2016,5(5):1635-1643.
[19] 汪洋,林喆,秦志宏,等.泡沫炭的制备工艺及应用[J].炭素技术,2020,39(2):1-6.
[20] Qin Z,Chang P,Ma L,et al.Preparation and modulation of a novel thin-walled carbon foam[J].International Journal of Mining Science and Technology,2019,29(2):281-287.
[21] 秦志宏.煤嵌布结构模型理论[J].中国矿业大学学报,2017,46(5):939-958.
[22] Men X,Wu Y,Chen H,et al.Facile fabrication of TiO2/graphene composite foams with enhanced photocatalytic properties[J].Journal of Alloys and Compounds,2017,703:251-257.
[23] 刘平.纳米二氧化钛/石墨烯泡沫复合材料的制备及其光催化性能研究[D].哈尔滨:哈尔滨工业大学,2017.
[24] Qian X,Ren M,Yue D,et al.Mesoporous TiO2 films coated on carbon foam based on waste polyurethane for enhanced photocatalytic oxidation of VOCs[J].Applied Catalysis B:Environmental,2017,212(2):1-6.
[25] Parale V G,Kim T,Phadtare V D,et al.Enhanced photocatalytic activity of a mesoporous TiO2 aerogel decorated onto three-dimensional carbon foam[J].Journal of Molecular Liquids,2019,277(1):424-433.
[26] Banhart J.Manufacture,characterisation and application of cellular metals and metal foams[J].Progress in Materials Science,2001,46(6):559-632.
[27] 张士卫.泡沫金属的研究与应用进展[J].粉末冶金技术,2016,34(3):222-227.
[28] 丁震,冯小刚,陈晓东,等.金属泡沫镍负载纳米TiO2光催化降解甲醛和VOCs[J].环境科学,2006,27(9):1814-1819.
[29] Hu H,Xiao W,Yuan J,et al.Preparations of TiO2 film coated on foam nickel substrate by sol-gel processes and its photocatalytic activity for degradation of acetaldehyde[J].Journal of Environmental Sciences,2007,19(1):80-85.
[30] Jia L,Li D,Cheng X,et al.Construction of graphite/TiO2/nickel foam photoelectrode and its enhanced photocatalytic activity[J].Applied Catalysis A:General,2016,525:128-136.
[31] Liu G,Zhang J,He X,et al.Research on photocatalytic activity of Nano-TiO2 coating on foam Al by composite electroplating[C].Shanghai:2nd IEEE International Nanoelectronics Conference,2008.
[32] Levchuk I,Guillard C,Dappozze F,et al.Photocatalytic activity of TiO2 fifilms immobilized on aluminum foam by atomic layer deposition technique[J].Journal of Photochemistry and Photobiology A:Chemistry,2016,328:16-23.
[33] Wang X,Han F,Wei X,et al.Microstructure and photocatalytic activity of mesoporous TiO2 fifilm coated on an aluminumfoam[J].Materials Letters,2010,64(18):1985-1988.
[34] Wang Q,Qiu L,Tan X,et al.Amorphous TiO2 granular nanodisks on porous Ti foam for highly effective solar cells and photocatalysts[J].Journal of the Taiwan Institute of Chemical Engineers,2019,102:85-91.
[35] Xue C,Lia D,Li Y,et al.3D-carbon dots decorated black TiO2 nanotube array@Ti foam with enhanced photothermal and photocatalytic activities[J].Ceramics International,2019,45:17512-17520.
[36] 吴庆祝,刘永先,李福功,等.泡沫陶瓷及其应用[J].陶瓷,2002(2):12-14.
[37] Amoin N K,Romain M,Didier R,et al.β-SiC foams as a promising structured photocata-lytic support for water and air detoxifification[J].Catalysis Today,2013,209:13-20.
[38] Ignace C M,Patricia G M,Patrick D,et al.Heterogeneous photodegradation of pyrimethanil and its commercial formulation with TiO2 immobilized on SiC foams[J].Journal of Photochemistry & Photobiology A:Chemistry,2019,368:1-6.
[39] Marisa R S,Patricia G M,Valerie K,et al.Alveolar TiO2-β-SiC photocatalytic composite foams with tunable properties for water treatment[J].Catalysis Today,2019,328:235-242.
[40] Hao D,Yang Z,Jiang C,et al.Synergistic photocatalytic effect of TiO2 coatings and p-type semiconductive SiC foam supports for degradation of organic contaminant[J].Applied Catalysis B:Environmental,2014,144:196-202.
[41] Ishiguro H,Yao Y,Nakano R,et al.Photocatalytic activity of Cu2+/TiO2-coated cordierite foam inactivates bacteriophages and Legionella pneumophila[J].Applied Catalysis B:Enviro-nmental,2013,129:56-61.
[42] Yao Y,Ochiai T,Ishiguro H,et al.Antibacterial performance of a novel photocataly-tic-coated cordierite foam for use in air cleaners[J].Applied Catalysis B:Environmental,2011,106:592-599.
[43] Vargová M,Plesch G,Ulrich F V,et al.TiO2 thick films supported on reticulated macroporous Al2O3 foams and their photoactivity in phenol mineralization[J].Applied Surface Science,2011,257:4678-4684.
[44] Minoo T,Kamila K,Miroslava E,et al.Pt/TiO2 photocatalysts deposited on commercial support for photocatalytic reduction of CO2[J].Journal of Photochemistry and Photobiology A:Chemistry,2018,366:72-80.
[45] Tuba Y,Yatmaz H C,Öztürk K.Anatase TiO2 powder immobilized on reticulated Al2O3 ceramics as a photocatalyst for degradation of RO16 azo dye[J].Ceramics International,2020,46:8651-8657.
[46] M-Sómer M,Pablos C,de Diego A,et al.Novel macroporous 3D photocatalytic foams for simultaneous wastewater disinfection and removal of contaminants of emerging concern[J].Chemical Engineering Journal,2019,366:449-459.
[47] Sophie G,Guillaume L,Hicham M,et al.Dip-coating on TiO2 foams using a suspension of Pt-TiO2 nanopowder synthesized by laser pyrolysis-preliminary evaluation of the catalytic performances of the resulting composites in deVOC reactions[J].Journal of the European Ceramic Society,2017,27:931-936.
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