以有机硅改性环氧树脂,不仅使树脂具有优良的韧性、耐氧化性和热稳定性等性能,而且还会产生较好的经济效益,在众多领域表现出广阔的应用前景和巨大的开发价值。从物理共混改性和化学共聚改性两个方面介绍了有机硅改性环氧树脂的研究现状及改性机理;在此基础上对有机硅改性环氧树脂在裂纹修补领域的发展趋势进行了展望。
The modification of epoxy resin(EP) with silicone not only makes the resin have excellent toughness,oxidation resistance and thermal stability,but also produces better economic benefits,showing broad application prospects and great development value in many fields.The research status and modification mechanism of silicone modified EP were introduced from two aspects:physical blending and chemical copolymerization modification.
[1] 沈威,王小萍,贾德民.环氧树脂增韧改性技术研究进展[J].热固性树脂,2010,25(3):49-53.
[2] 杜茂平,魏伯荣.聚硅氧烷增韧环氧树脂研究新进展[J].有机硅材料,2007,22(1):46-48.
[3] 吴明军,李美江.有机硅改性环氧树脂的进展[J].化工新型料,2011,39(1):32-35.
[4] 张栾,潘恒,孔志祥,等.有机硅改性环氧树脂的研究进展[J].粘结,2015(8):82-85.
[5] 石新秀,袁崇凯,王传萍,等.有机硅改性环氧树脂的新进展[J].高分子通报,2015(4):18-37.
[6] 贺晨,苏峘,卢鹉,等.环氧有机硅韧性烧蚀防热涂层制备[J].表面技术,2018(5):167-171.
[7] 刘克祥,刘敏,侯丽华,等.有机硅改性环氧树脂的研究进展[J].化学试剂,2007(6):11-13.
[8] 苏倩倩,刘伟区,侯孟华.有机硅改性提高环氧树脂韧性和耐热性的研究[J].精细化工,2008,25(1):23-27.
[9] 廖波,李鸿岩,张步峰,等.环氧树脂增韧改性的研究进展[J].化工新型材料,2010,38(6):28-30.
[10] Ronda Lloret M,Rico Francés S,Sepúlveda Escribano A,et al.CuOx/CeO2 catalyst derived from metal organic framework for reverse water-gas shift reaction[J].Applied Catalysis A(General),2018,562:28-36.
[11] 陈伟,黄志良,刘羽,等.多孔HAp固体碱酯交换催化剂制备与表征[J].武汉工程大学学报,2008,30(1):70-72.
[12] Xu G,Zhang Y,Fu Y,et al.Efficient hydrogenation of various renewable oils over Ru-HAP catalyst in water[J].ACS Catalysis,2017,7(2):1158-1169.
[13] 童汉清,陈达明,王勐,等.烷基烷氧基硅烷改性环氧树脂的耐高温性研究[J].当代化工,2018,47(2):264-267.
[14] Huang W,Zhang Y,Yu Y Z,et al.Studies on UV-stable silicone-epoxy resins[J].Journal of Applied Polymer Science,2007,104(6):3954-3959.
[15] Fang Cheng,Guan Dongbo,Yao Weiguo,et al.Studies on mechanical and thermal properties of epoxy resin modified by fluorine-containing silicone[J].Applied Mechanics and Materials,2013,401-403:713-716.
[16] Chen M,Zhang G,Liang X,et al.Thermally stable transparent sol-gel based active siloxane-oligomer materials with tunable high refractive index and dual reactive groups[J].RSC Advances,6(75):70825-70831.
[17] 张冰,刘香鸾,黄英.氨基聚硅氧烷对改性环氧树脂的形态与性能的影响[J].功能高分子学报,2000,13(1):69.
[18] Lee M C,Ho T H,Wang C S,et al.Synthesis of tetrafunctional epoxy resin and their modification with polydimethyl siloxane for electronic application[J].Jounal of Applied Polymer Science,1996,62(1):217-225.
[19] 郑钦健,李航昱,陈少鹏,等.含氨基聚硅氧烷改性环氧树脂[J].厦门大学学报(自然科学版),2005,44(3):400-406.
[20] 张燕,张云飞,李因文,等.有机硅/聚醚胺复合改性环氧树脂合成及性能[J].精细化工,2014,31(10):1188-1191,1214.
[21] Ahmad S,Gupta A P,Sharmin E,et al.Synthesis,characterization and development of high performance siloxane-modified epoxy paints[J].Progress in Organic Coatings,2005,54(3):248-255.
[22] Yang S C,Kim J S,Jin J H,et al.Cycloaliphatic epoxy oligosiloxane-derived hybrid materials for a high-refractive index LED encapsulant[J].Journal of Applied Polymer Science,2011,122(4):2478-2485.
[23] 来国桥,颜立成,倪勇,等.有机硅改性环氧树脂在油墨中的应用[J].功能高分子学报,2004,17(1):131-134.
