开发与应用

硅酸盐矿物蛭石的改性及对水体中污染物的吸附研究进展

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  • 1.中国科学院水生生物研究所淡水生态和生物技术国家重点实验室,武汉430072;
    2.中国科学院大学,北京100049;
    3.武汉理工大学资源与环境工程学院,武汉430070
邹羿菱云(1997-),女,硕士研究生,主要从事水体生态修复等研究,E-mail:892734938@qq.com。

收稿日期: 2020-04-17

  修回日期: 2021-06-08

  网络出版日期: 2021-09-07

基金资助

国家自然科学基金(51709254);中国科学院知识创新工程青年人才领域前沿项目;中国科学院科技服务网络计划(KFJ-STS-ZDTP-038)

Research progress in modification of silicate mineral vermiculite and adsorption of pollutant in water

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  • 1. State Key Laboratory of Freshwater Ecology and Biotechnology,Institute of Hydrobiology,Chinese Academy of Sciences,Wuhan 430072;
    2. University of Chinese Academy of Sciences,Beijing 100049;
    3. School of Resource & Environmental Engineering,Wuhan University of Technology,Wuhan 430070

Received date: 2020-04-17

  Revised date: 2021-06-08

  Online published: 2021-09-07

摘要

天然硅酸盐矿物蛭石在自然界分布广,具有阳离子交换能力强、比表面积大等特点,经过改性后在水污染修复方面优势突出。介绍了多种蛭石的改性方法、对应的影响因素和改性机理,讨论了改性蛭石对水体污染物的吸附效果和研究进展,为进一步提高蛭石吸附性能和应用于水处理工程提供参考,并对改性蛭石研究发展方向进行了展望。

本文引用格式

邹羿菱云, 刘云利, 骆凤, 刘子森, 吴振斌, 张义 . 硅酸盐矿物蛭石的改性及对水体中污染物的吸附研究进展[J]. 化工新型材料, 2021 , 49(8) : 274 -280 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.08.059

Abstract

Vermiculite is widely distributed in nature,with the characteristics of strong cation exchange capacity and large specific surface area.It has outstanding advantages in water pollution remediation after modification.The modification methods of vermiculite,the corresponding influencing factors and modification mechanism were introduced,and discussed the adsorption effect and research progress of modified vermiculite on water pollutants.And a reference was provided for further improving the adsorption performance of vermiculite and its application in water treatment engineering.

参考文献

[1] Moraes D S,Rodrigues E M S,Lamarao C N,et al.New sodium activated vermiculite process.testing on Cu2+ removal from tailing dam waters[J].J Hazard Mater,2019,366:34-38.
[2] Leofanti G,Padovan M,Tozzola G,et al.Surface area and pore texture of catalysts[J].Catalysis Today,1998,41(1-3):207-219.
[3] Jin L,Dai B.TiO2 activation using acid-treated vermiculite as a support:characteristics and photoreactivity[J].Appl Surf Sci,2012,258(8):3386-3392.
[4] Wegrzyn A,Chmielarz L,Zjezdzalka P,et al.Adsorbents for Iron removal obtained from vermiculite[J].Acta Geodynamica Et Geomaterialia,2013,10(3):353-361.
[5] Stawinski W,Freitas O,Chmielarz L,et al.The influence of acid treatments over vermiculite based material as adsorbent for cationic textile dyestuffs[J].Chemosphere,2016,153:115-129.
[6] Taxiarchou M,Douni I.The effect of oxalic acid activation on the bleaching properties of a bentonite from Milos Island[M].Greece Clay Miner,2014:541-549.
[7] 武艳,苗春光.改性蛭石去除水体中蓝藻效果的研究[J].安徽农学通报,2019,25(21):127-129.
[8] Chambi-Peralta M M,Coelho A C V,Carvalho F M D,et al.Effects of exchanged cation,acid treatment and high shear mechanical treatment on the swelling and the particle size distribution of vermiculite[J].Appl Clay Sci,2018,155:1-7.
[9] Komadel P.Acid activated clays:materials in continuous demand[J].Appl Clay Sci,2016,131:84-99.
[10] 雷明婧,朱健,王平,等.粘土矿物无机柱撑改性及其吸附研究进展[J].中南林业科技大学学报,2012,32(12):67-71.
[11] Silva A,Martinho S,Stawinski W,et al.Application of vermiculite-derived sustainable adsorbents for removal of venlafaxine[J].Environ Sci Pollut R,2018,25(17):17066-17076.
[12] Stawinski W,Wegrzyn A,Danko T,et al.Acid-base treated vermiculite as high performance adsorbent:Insights into the mechanism of cationic dyes adsorption,regeneration,recyclability and stability studies[J].Chemosphere,2017,173:107-115.
[13] Yao J,Chen Y,Yu H Q,et al.Efficient and fast removal of Pb(Ⅱ) by facile prepared magnetic vermiculite from aqueous solution[J].RSC Adv,2016,6(103):101353-60.
[14] Wei S Y,Wang R,Niu P J,et al.Preparation,characterization and fluoride adsorption characteristics of iron-oxide-modified vermiculite[J].Chinese J Inorg Chem,2016,32(9):1619-1628.
[15] Yao J,Chen Y,Yu H Q,et al.Efficient and fast removal of Pb(Ⅱ) by facile prepared magnetic vermiculite from aqueous solution[J].RSC Adv,2016,6(103):101353-101360.
[16] Sari A,Tuzen M.Adsorption of silver from aqueous solution onto raw vermiculite and manganese oxide-modified vermiculite[J].Micropor Mesopor Mat,2013,170:155-163.
[17] Chen M Q,Wu P X,Li S S,et al.The effects of interaction between vermiculite and manganese dioxide on the environmental geochemical process of thallium[J].Sci Total Environ,2019,669:903-910.
[18] Huo X X,Wu L M,Liao L B,et al.The effect of interlayer cations on the expansion of vermiculite[J].Powder Technol,2012,224:241-246.
[19] Thanos A G,Katsou E,Malamis S,et al.Cr(Ⅵ) removal from aqueous solutions using aluminosilicate minerals in their Pb-exchanged forms[J].Appl Clay Sci,2017,147:54-62.
[20] Lima R R C,De Lima P D S,Greati V R,et al.Sodium-modified vermiculite for calcium ion removal from aqueous solution[J].Ind Eng Chem Res,2019,58(22):9380-9389.
[21] Karathanasis A D,Shumaker P D.Organic and inorganic phosphate interactions with soil hydroxy-interlayered minerals[J].J Soil Sediment,2009,9(5):501-510.
[22] Liu D C,Deng S B,Vakili M,et al.Fast and high adsorption of Ni(Ⅱ) on vermiculite-based nanoscale hydrated zirconium oxides[J].Chem Eng J,2019,360:1150-1157.
[23] Huang W Y,Li D,Liu Z Q,et al.Kinetics,isotherm,thermodynamic,and adsorption mechanism studies of La(OH)3-modified exfoliated vermiculites as highly efficient phosphate adsorbents[J].Chem Eng J,2014,236:191-201.
[24] Huang W Y,Yu C L,Li D.La-modified vermiculites for efficient adsorption of congo red[J].Asia-Pac J Chem Eng,2017,12(6):969-979.
[25] Hillier S,Marwa E M M,Rice C M.On the mechanism of exfoliation of ‘Vermiculite’[J].Clay Miner,2013,48(4):563-582.
[26] Lee T,Lee S,Lee J,et al.Modification of vermiculite for the preparation of floating adsorbent for phosphate in wastewater[J].Water Environ Res,2016,88(8):724-731.
[27] Marcos C,Rodriguez I.Thermoexfoliated commercial vermiculites for Ni2+ removal[J].Appl Clay Sci,2016,132:685-693.
[28] 郑易安,王爱勤.不同方式处理蛭石对磷吸附性能研究[J].应用化工,2010,39(2):204-208.
[29] Marcos C,Rodriguez I.Expansibility of vermiculites irradiated with microwaves[J].Appl Clay Sci,2011,51(1-2):33-37.
[30] Hashem F S,Amin M S,El-Gamal S M A.Chemical activation of vermiculite to produce highly efficient material for Pb2+ and Cd2+ removal[J].Appl Clay Sci,2015,115:189-200.
[31] Miao Z,Peng T J,Xi Y G,et al.Preparation of expanding vermiculite by chemical and microwave methods[J].Adv Mater Res-Switz,2010,96:155-160.
[32] Marcos C,Rodriguez I.Exfoliation of vermiculites with chemical treatment using hydrogen peroxide and thermal treatment using microwaves[J].Appl Clay Sci,2014,87:219-227.
[33] 贺壹城,钱玉鹏,高惠民,等.物理法对蛭石膨胀特性及脆性的影响[J].硅酸盐通报,2017,36(2):564-569.
[34] 田维亮,薛东虎,曹婉婧,等.不同剥离方式对蛭石膨胀性能的影响及其机理研究[J].化工矿物与加工,2018,47(4):42-59.
[35] 安向静,齐誉,乔秀文,等.改性蛭石对HgCl2吸附性能研究[J].水处理技术,2013,39(12):69-73.
[36] Zana R.Dimeric and oligomeric surfactants.behavior at interfaces and in aqueous solution:a review[J].Adv Colloid Interfac,2002,97(1-3):205-53.
[37] Shen T,Gao M L,Ding F,et al.Organo-vermiculites with biphenyl and dipyridyl gemini surfactants for adsorption of bisphenol A:structure,mechanism and regeneration[J].Chemosphere,2018,207:489-496.
[38] Wang J,Gao M L,Shen T,et al.Insights into the efficient adsorption of rhodamine B on tunable organo-vermiculites[J].J Hazard Mater,2019,366:501-511.
[39] Liu S,Wu P X,Chen M Q,et al.Amphoteric modified vermiculites as adsorbents for enhancing removal of organic pollutants:bisphenol A andtetrabromobisphenol A[J].Environ Pollut,2017,228:277-286.
[40] Yu M M,Gao M L,Shen T,et al.Organo-vermiculites modified by low-dosage Gemini surfactants with different spacers for adsorption toward p-nitrophenol[J].Colloid Surface A,2018,553:601-611.
[41] Liu S,Wu P X,Yu L F,et al.Preparation and characterization of organo-vermiculite based on phosphatidylcholine and adsorption of two typical antibiotics[J].Appl Clay Sci,2017,137:160-167.
[42] Haro A G,Menezes H C,Ribeiro-Santos T A,et al.Improved method for quantification of persistent organic pollutants and its remediation using modified clays materials[J].Microchemical Journal,2019,150.
[43] Tuchowska M,Wolowiec M,Solinska A,et al.Organo-modified vermiculite:preparation,characterization,and sorption of arsenic compounds[J].Minerals,2019,9(8):483.
[44] Gu S Q,Wang L,Mao X Y,et al.Selective adsorption of Pb(Ⅱ) from aqueous solution by triethylenetetramine-grafted polyacrylamide/vermiculite[J].Materials,2018,11(4).
[45] Long H,WuPX,YangL,et al.Efficient removal of cesium from aqueous solution with vermiculite of enhanced adsorption property through surface modification by ethylamine[J].Journal of Colloid and Interface Science,2014,428.
[46] Adewuyi A,Oderinde R A.Chemically modified vermiculite clay:a means to remove emerging contaminant from polluted water system in developing nation[J].Polymer Bulletin,2019,76(10):4967-4989.
[47] De Mesquita J P,Reis L S,Purceno A D,et al.Carbonclay composite obtained from the decomposition of cellulose nanocrystals on the surface of expanded vermiculite[J].J Chem Technol Biot,2013,88(6):1130-1135.
[48] Purceno A D,Barrioni B R,Dias A,et al.Carbon nanostructures-modified expanded vermiculites produced by chemical vapor deposition from ethanol[J].Appl Clay Sci,2011,54(1):15-19.
[49] Stawinski W,Wegrzyn A,Mordarski G,et al.Sustainable adsorbents formed from by-product of acid activation of vermiculite and leached-vermiculite-LDH hybrids for removal of industrial dyes and metal cations[J].Appl Clay Sci,2018,161:6-14.
[50] Zang W L,Gao M L,Shen T,et al.Facile modification of homoionic-vermiculites by a gemini surfactant:Comparative adsorption exemplified by methyl orange[J].Colloid Surface A,2017,533:99-108.
[51] Nashtifan S G,Azadmehr A,Maghsoudi A.Comparative and competitive adsorptive removal of Ni2+ and Cu2+ from aqueous solution using iron oxide-vermiculite composite[J].Appl Clay Sci,2017,140:38-49.
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