综述与专论

提高铈酸钡基质子导体稳定性研究进展

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  • 1.华北理工大学化学工程学院,唐山063210;
    2.河北省环境光电催化材料重点实验室,唐山063210
张奔(1996-),男,硕士研究生,主要从事固体电解质的研究,E-mail:1048789153@qq.com。

收稿日期: 2020-05-11

  修回日期: 2021-04-25

  网络出版日期: 2021-09-07

基金资助

国家自然基金(51872090);河北省重点基金项目(E2017209260)

Research progress on improving the stability of BaCeO3 based proton conductor

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  • 1. College of Chemical Engineering,North China University of Science and Technology,Tangshan 063210;
    2. Hebei Province Key Laboratory of Photocatalytic and Electrocatalytic Materials for Environment,Tangshan 063210

Received date: 2020-05-11

  Revised date: 2021-04-25

  Online published: 2021-09-07

摘要

铈酸钡(BaCeO3)基质子导体因其良好的质子传导能力被广泛关注,并有着潜在的应用前景,但其固有的化学稳定性差的缺陷,限制了它的实际应用,因此许多研究者对如何提高其稳定性进行了探究。目前所提出的提高BaCeO3基质子导体稳定性的方法主要包括元素掺杂、改变Ba的化学计量比或形成核壳结构材料。总结归纳这3个方面的研究进展,为进一步研究BaCeO3基质子导体稳定性提供参考。

本文引用格式

张奔, 朱靖, 李跃华, 戴磊, 王岭 . 提高铈酸钡基质子导体稳定性研究进展[J]. 化工新型材料, 2021 , 49(8) : 60 -64 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.08.013

Abstract

The BaCeO3 based proton conductors are widely concerned because of their good proton conductivity,and potential application prospect.However,the inherent shortcoming of poor chemical stability limits their practical application.Therefore,many researchers have paid more attention to explore how to improve their stability.At present,the proposed methods to improve the stability of BaCeO3 based proton conductors mainly include element doping,changing the stoichiometric ratio of Ba or forming core-shell structure material.The research progress on these three aspects was summarized,and provided reference for further study on the stability of BaCeO3 based proton conductors.

参考文献

[1] Siriwardane R,Poston J A,Fisher E P,et al.Characterization of ceramic-metal composite hydrogen separation membranes consisting of barium oxide,cerium oxide,yttrium oxide and palladium[J].Applied Surface Science,2003;217(1-4):43-49.
[2] Iwahara H,Esaka T,Uchida H,et al.Proton conduction in sintered oxides and its application to steam electrolysis for hydrogen production[J].Solid State Ionics,1981;3-4:359-363.
[3] Iwahara H,Uchida H,Ono K,et al.Proton conduction in sintered oxides based on BaCeO3[J].Journal of the Electrochemical Society,1988;135(2):529-533.
[4] Sawant P,Varma S,Gonal M R,et al.Effect of Ni concentration on phase stability,microstructure and electrical properties of BaCe0.8Y0.2O3-δ-Ni cermet SOFC anode and its application in proton conducting ITSOFC[J].Electrochimica Acta,2014,120:80-85.
[5] Qian J,Sun W,Shi Z,et al.Chemically stable BaZr0.7Pr0.1Y0.2O3-δ-BaCe0.8Y0.2O3-δ bilayer electrolyte for intermediate temperature solid oxide fuel cells[J].Electrochimica Acta,2015,151:497-501.
[6] 大连理工大学无机化学教研室.无机化学第六版[M].北京:高等教育出版社,2018,106.
[7] Kreuer K D.Proton-conducting oxides[J].Annual Review of Materials Research,2003,33(1):333-359.
[8] Saiful Islam M,Slater P R,Tolchard J R,et al.Doping and defect association in AZrO3 (A=Ca,Ba) and LaMO3 (M=Sc,Ga) perovskite-type ionic conductors[J].Dalton Transactions,2004(19):3061-3066.
[9] Zając W,Rusinek D,Zheng K,et al.Applicability of Gd-doped BaZrO3,SrZrO3,BaCeO3 and SrCeO3 proton conducting perovskites as electrolytes for solid oxide fuel cells[J].Open Chemistry,2013,11(4):471-484.
[10] Kosacki I,Schoonman J,Balkanski M.Raman scattering and ionic transport in SrCe1-xYbxO3[J].Solid State Ionics,1992,57(3-4):345-351.
[11] 靳超,王岭,戴磊,等.双相质子导体BaCe0.9Y0.1O3-δ/La1.95Ca0.05Ce2O7-δ的制备及性能研究[J].功能材料,2013,44(16):2348-2353.
[12] Hills M P,Schwandt C,Kumar R V.Oxide ion conduction in indium-oxide-substituted calcium zirconate[J].Journal of the Electrochemical Society,2006,153(10):189-194.
[13] Ma G L,Matsumoto H,Iwahara H.Ionic conduction and nonstoichiometry in non-doped BaxCeO3-α[J].Solid State Ionics,1999,122(1-4):237-247.
[14] Matsushita E.Tunneling mechanism on proton conduction in perovskite oxides[J].Solid State Ionics,2001,145(1-4):445-450.
[15] Iwahara H,Yajima T,Hibino T,et al.Protonic conduction in calcium,strontium and barium zirconates[J].Solid State Ionics,1993,61(1-3):65-69.
[16] Zuo C,Lee T H,Dorris S E,et al.Composite Ni-Ba(Zr0.1Ce0.7Y0.2)O3 membrane for hydrogen separation[J].Journal of Power Sources,2006;159(2):1291-1295.
[17] Fabbri E,Depifanio A,Dibartolomeo E,et al.Tailoring the chemical stability of Ba(Ce0.8-xZrx)Y0.2O3-δ protonic conductors for intermediate temperature solid oxide fuel cells (IT-SOFCs)[J].Solid State Ionics,2008,179(15-16):558-564.
[18] Song J,Meng B,Tan X Y.Stability and electrical conductivity of BaCe0.85Tb0.05M0.1O3-δ(M=Co,Fe,Y,Zr,Mn) high temperature proton conductors[J].Ceramics International,2016,42(11):13278-13284.
[19] Ryu K H,Haile S M.Chemical stability and proton conductivity of doped BaCeO3-BaZrO3 solid solutions[J].Solid State Ionics,1999,125(1-4):355-367.
[20] Kreuer K D.On the development of proton conducting materials for technological applications[J].Solid State Ionics,1997,97(1-4):1-15.
[21] Somekawa T,Matsuzaki Y,Sugahara M,et al.Physicochemical properties of Ba(Zr,Ce)O3-δ-based proton-conducting electrolytes for solid oxide fuel cells in terms of chemical stability and electrochemical performance[J].International Journal of Hydrogen Energy,2017,42(26):16722-16730.
[22] Yang Y,Zeng Y,Amirkhiz B S,et al.Promoting the ambient-condition stability of Zr-doped barium cerate:toward robust solid oxide fuel cells and hydrogen separation in syngas[J].Journal of Power Sources,2018,378:134-138.
[23] Kang W R,Lee K B.Development of rare earth element-doped Ni-Ba(Ce/Zr)O3 cermets for hydrogen-permeable membranes[J].Journal of Industrial and Engineering Chemistry,2015,29:194-198.
[24] Zhao F,Liu Q,Wang S,et al.Synthesis and characterization of BaIn0.3-xYxCe0.7O3-δ(x=0,0.1,0.2,0.3) proton conductors[J].International Journal of Hydrogen Energy,2010,35(9):4258-4263.
[25] 杨春利,严敏,李伟.In、Ta共掺对BaCeO3烧结性能及稳定性的影响[J].无机材料学报,2016,31(9):955-960.
[26] 马欣宇,杨春利,严敏,等.In、Gd共掺对BaCeO3基质子导体性能的影响[J].人工晶体学报,2017,46(12):2380-2385.
[27] Sari A,Biçer A.Preparation and thermal energy storage properties of building material-based composites as novel form-stable PCMs[J].Energy and Buildings,2012,51:73-83.
[28] Shin E,Anggia E,Park J.Effects of Al2O3 doping in BaCeO3 on chemical stability and electrical conductivity of proton conducting oxides[J].Solid State Ionics,2019,339:115007.
[29] Matsumoto H,Kawasaki Y,Ito N,et al.Relation between electrical conductivity and chemical stability of BaCeO3-based proton conductors with different trivalent dopants[J].Electrochemical and Solid-State Letters,2007,10(4):77-80.
[30] Madhuri Sailaja J,Murali N,Vijay Babu K,et al.Effect of Strontium the phase structure of Ba1-xSrxCe0.65Zr0.2Y0.15O3-δ(0≤x≤0.25) proton conductor by citrate-EDTA complexing sol-gel method[J].Journal of Asian Ceramic Societies,2018,5(1):18-30.
[31] Guan J,Dorris S E,Balachandran U,et al.The effects of dopants and A:B site nonstoichiometry on properties of perovskite-type proton conductors[J].Journal of the Electrochemical Society,1998,145(5):1780-1786.
[32] Yamazaki Y,Hernandezsanchez R,Haile S M.Cation non-stoichiometry in yttrium-doped barium zirconate:phase behavior,microstructure,and proton conductivity[J].Journal of Materials Chemistry,2010,20(37):8158.
[33] Zhang C,Zhao H.Structural characteristics,sinterability and electrical conductivity of Ba-site non-stoichiometric BaxCe0.50Zr0.40Y0.10O3-δ[J].Materials Research Bulletin,2010,45(11):1659-1663.
[34] Guo Y,Ran R,Shao Z,et al.Effect of Ba nonstoichiometry on the phase structure,sintering,electrical conductivity and phase stability of BaxCe0.4Zr0.4Y0.2O3-δ(0≤x≤0.20) proton conductors[J].International Journal of Hydrogen Energy,2011,36(14):8450-8460.
[35] Jin C,Zhou H,Lei D,et al.Effect of Ba nonstoichiometry on the phase composition,microstructure,chemical stability and electrical conductivity of BaxCe0.7Zr0.1Y0.1Yb0.1O3-δ(0.9≤x≤1.1) proton conductors[J].Ceramics International,2015,41(6):7796-7802.
[36] Wang L,Jin C,Dai L,et al.Synthesis and properties of core-shell structured BaCe0.9Y0.1O2.95:BaZr0.9Y0.1O2.95[J].Ceramics International,2013,39(7):7959-7966.
[37] Lacz A,Silarska K,Piecha I,et al.Structure,chemical stability and electrical properties of BaCe0.9Y0.1O3-δ proton conductors impregnated with Ba3(PO4)2[J].International Journal of Hydrogen Energy,2016,41(31):13726-13735.
[38] Jhuang J,Lee K,Chang J,et al.Chemical stability and electrical and mechanical properties of BaZrxCe0.8-xY0.2O3 with CeO2 protection method[J].International Journal of Hydrogen Energy,2017,42(34):22259-22265.
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