综述与专论

秸秆基吸水材料的研究进展

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  • 吉林建筑大学材料科学与工程学院,长春130118
赵洪凯(1974-),男,博士,教授,主要从事复合材料的研究,E-mail:hkzhao003@126.com。

收稿日期: 2020-10-20

  修回日期: 2021-05-07

  网络出版日期: 2021-09-07

基金资助

“十三五”国家重点研发计划子课题(2016YFC0701002);吉林省教育厅“十三五”科学技术项目(JJKH20170239KJ);吉林省大学生创新创业训练计划项目(8570036505)

Research progress on strow-based water absorption material

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  • School of Materials Science and Engineering,Jilin Jianzhu University,Changchun 130118

Received date: 2020-10-20

  Revised date: 2021-05-07

  Online published: 2021-09-07

摘要

农作物秸秆中富含天然纤维素,将其引入吸水材料的制备,既可降低原材料的成本,又可提高吸水材料的生物降解性。目前,以秸秆为原材料制备吸水材料的主要方法是将极性单体与秸秆进行接枝共聚。总结归纳了制备秸秆基吸水材料的3种不同方法:自由基聚合法、光辐射聚合法和共混合复合法,并对所制备吸水材料的性能进行了分析。结果表明秸秆基吸水材料与传统的高吸水性材料相比,价格更低、工艺流程更简洁、降解性能更佳。

本文引用格式

赵洪凯, 赵培培 . 秸秆基吸水材料的研究进展[J]. 化工新型材料, 2021 , 49(8) : 42 -45 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.08.009

Abstract

The crop straw is rich in natural cellulose,and its introduction into the preparation of water-absorbing material can not only reduce the cost of raw materials,but also improve the biodegradability of absorbent materials.At present,the main method of preparing water absorbing material from straw is graft copolymerization of polar monomer and straw.Three different methods of straw based water absorbent were summarized:free radical polymerization,light radiation polymerization,blending and compounding.The properties of the prepared water absorbent were analyzed.The analysis shown that compared with the traditional super absorbent materials,the straw-based absorbent materials had the advantages of low cost,simple process and degradation performance was better.

参考文献

[1] Kiatkamjornwong S,Mongkolsawat K,Sonsuk M.Synthesis and property characterization of cassavastarch grafted poly[acrylamide-co-(maleic acid)] superabsorbent via g-irradiation[J].Polymer,2002,43(14),3915-3924.
[2] Liao R K,Yang P L,Ren S M.Review on super absorbent polymer application for improving fertilizer efficiency and controlling agricultural non-point source pollutions[J].Transactions of the Chinese Society of Agricultural Engineering,2012,28(17):1-10.
[3] Lanthong P,Nuisin R,Kiatkamjornwongc S,et al.Graft copolymerization,characterization,and degradation of cassava starch-g-acrylamide/itaconic acid superabsorbents[J].Carbohydrate Polymers,2006,66(2),229-245.
[4] Farag S,Al-Afaleq E I.Preparation and characterization of saponified delignified cellulose polyacrylonitrile-graft copolymer[J].Carbohydrate Polymers,2002,48(1):1-5.
[5] Chu M,Huang Z,Bang X U,et al.Preparation,characterization and salt-resistance of a coal based super absorbent composite[J].Mining Science and Technology(China),2010,20(6):864-871.
[6] Berber M R,Hafez I H,Minagawa K,et al.An efficient strategy of managing irrigation water based on formulating highly absorbent polymer-inorganic clay composites[J].Journal of Hydrology,2012,470-471:193-200.
[7] Farag S,Al-Afaleq E I.Preparation and characterization of saponified delignified cellulose polyacrylonitrile-graft copolymer[J].Carbohydrate Polymers,2002,48:1.
[8] Shogren R L,Willett J L,Biswas A.HRP-mediated synthesis of starch-polyacrylamide graft copolymers[J].Carbohydrate Polymers,2009,75:189.
[9] Zhang J P,Li A,Wang A Q.Study on superabsorbent composite.Ⅴ.synthesis,swelling behaviors and application ofpoly(acrylic acid-co-acrylamide)/sodium humate/attapulgite super-absorbent composite[J].Polymers for Advanced Technologies,2005,16:813.
[10] Karlsson J O,Gatenholm P.Preparation and characterization of cellulose-supported HEMA hydrogels[J].Polymer,1997,38(18):4727-4731.
[11] Teodorescu M,Lungu A,Stanescu P O.Preparation and properties of novel slow-release NPK agrochemical formulations based on poly(acrylic acid) hydrogels and liquid fertilizers[J].Industrial & Engineering Chemistry Research,2009,48(14):48-53.
[12] Stahl J D,Cameron M D,Haselbach J,et al.Biodegradation of superabsorbent polymers in soil[J].Environmental ence & Pollution Research,2000,7(2):83-88.
[13] Lepoutre P F,Hopfenberg H B,Stannett V.The effect of vinyl monomer grafting on the water sorption kinetics and equilibria in cellulose[J].Journal of Polymer Science Part C:Polymer Symposia,1972,37:309-324.
[14] Lepoutre P,Hui S H,Robertson A A.The water absorbency of hydrolyzed polyacrylonitrile-grafted cellulose fibers[J].Journal of Applied Polymer Ence,2010,17(10):3143-3156.
[15] Talebnia F,Karakashev D,Angelidaki I.Production of bioethanol from wheat straw:an overview on pretreatment,hydrolysis and fermentation[J].Bioresource Technology,2010,101(13):4744-4753.
[16] Garnett J L,Ng L,Viengkhou V,et al.Novel additives including charge-transfer complexes in grafting of methyl methacrylate to polypropylene,cellulose and wool,initiated by ionizing radiation and UV:significance of these studies in analogous curing processes[J].Polymer International,2015,48(10):1016-1026.
[17] Bhatnagar A,Sillanpää M.Utilization of agro-industrial and municipal waste materials as potential adsorbents for water treatment-a review[J].Chemical Engineering Journal,2010,157:277.
[18] Guo Y,Li X Y,Li C B,et al.Preparation of agricultural superabsorbent resin by wheat straw[J].Fine Chemicals,2006,23(4):322-326.
[19] Liu Z,Miao Y,Wang Z,et al.Synthesis and characterization of a novel super-absorbent based on chemically modified pulverized wheat straw and acrylic acid[J].Carbohydrate Polymers,2009,77(1):131-135.
[20] 喻弘,喻鹏.球磨改性稻秆复合高吸水树脂的工艺优化[J].食品工业,2019(5):4-8.
[21] Xie L,Liu M,Ni B,et al.New environment-friendly use of wheat straw in slow-release fertilizer formulations with the function of superabsorbent[J].Industrial & Engineering Chemistry Research,2012,51(10):3855-3862.
[22] Smyth G,Quinn F X,McBrierty V J.Water in hydrogels.a study of water in poly (hydroxyethyl methacrylate)[J].Macromolecules,1988,21:3198.
[23] Zhang P,Li H,Jia Z K,et al.Effects of straw returning on soil organic carbon and carbon mineralization in semi-arid areas of southern Ningxia,China[J].Journal of Agro-Environment Science,2011,30(12):2518-2525.
[24] Ma Z,Li Q,Yue Q,et al.Synthesis and characterization of a novel super-absorbent based on wheat straw[J].Bioresource Technology,2011,102(3):2853-2858.
[25] 张峰,李伟,岳美辰,等.尿素/秸秆基高吸水树脂的一步制备及其缓释性能[J].功能材料,2017,48(12):172-176.
[26] Lu S,Feng C,Gao C,et al.Multifunctional environmental smart fertilizer based on L-aspartic acid for sustained nutrient release[J].Journal of Agricultural & Food Chemistry,2016,64(24):4965-4974.
[27] Qiu J,Li Chaohai.The applications of the water saved polymer materials for slow release fertilizers[J].Journal of Agricultural Ences,2015,36(4):58-63.
[28] Sun Lin,Wang Cunguo,Lin L,et al.Study on superabsorbent resin to saline solution prepared by graft copolymerization with acrylic acid onto wheat straw[J].Applied Chemical Industry,2007(12):1194-1196.
[29] 鲍艳,马建中,李娜.利用秸秆纤维制备高吸水材料的研究[J].功能材料,2011,42(Z4):724-727.
[30] Peng N N,Li Q,Gao B Y,et al.Synthesis and characterization of a novel amphoteric super absorbent resin based on corn straw[J].Journal of Functional Materials,2013,44(1):79-83,87.
[31] Zheng Xuejiao,Zhang Yongli,Wu Fuxue,et al.Effect of nitrogen application on water use consumption characteristics and the water and nitrogen use of winter wheat under supplemental irrigation based on measuring soil moisture[J].Journal of Triticeae Crops,2017,37(10):1358-1363.
[32] Liang R,Yuan H,Xi G,et al.Synthesis of wheat straw-g-poly(acrylic acid) superabsorbent composites and release of urea from it[J].Carbohydrate Polymers,2009,77(2):181-187.
[33] 王晨,师晓鹏,魏浩钦,等.玉米秸秆基高吸水性树脂的试验研究[J].河南农业大学学报,2020,54(1):81-86.
[34] Tan Fengzhi,Cao Yafeng,Li Yuan,et al.Preparation of superabsorbent resin from corn straw[J].Journal of Dalian Polytechnic University,2009,28(2):S204.
[35] 汪昌保.秸秆基高吸水树脂辐照合成及其性能研究[D].扬州:扬州大学,2013.
[36] 杨连威,王瑞杰.秸秆-聚丙烯酸高吸水材料制备工艺及其性能研究[C].沈阳:有色金属先进材料及其制备技术学术研讨会,2016.
[37] Das R,Panda A B,Pal S.Synthesis and characterization of a novel polymeric hydrogel based on hydroxypropyl methyl cellulose grafted with polyacrylamide[J].Cellulose,2012(19):933-945.
[38] 赵洪凯,赵培培,芮守鹏,等.羟丙基甲基纤维素掺杂秸秆吸水材料的制备与分析[J].化工新型材料,2020,48(8):249-253.
[39] Lou Y,Xu M,Wang W,et al.Return rate of straw residue affects soil organic C sequestration by chemical fertilization[J].Soil & Tillage Research,2011,113(1):70-73.
[40] 程文忠.改性秸秆/锂皂石复合高吸水性树脂的研究[D].成都:成都理工大学,2015.
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