综述与专论

富镍三元正极材料的改性研究进展

展开
  • 1.青海民族大学物理与电子信息工程学院,西宁810007;
    2.青海民族大学化学化工学院,西宁810007
马生花(1990-),女,硕士,助教,主要研究方向为新能源材料,E-mail:1105615252@qq.com。

收稿日期: 2020-04-20

  修回日期: 2021-04-24

  网络出版日期: 2021-08-19

基金资助

青海省科技厅基础研究计划项目(2019-ZJ-7013);青海省科技厅应用基础研究项目(2017-ZJ-750)

Research progress on modification of nickel-rich ternary cathode material

Expand
  • 1. School of Physics and Electronic Information Engineering,Qinghai Nationalities University, Xining 810007;
    2. School of Chemistry and Chemical Engineering,Qinghai Nationalities University, Xining 810007

Received date: 2020-04-20

  Revised date: 2021-04-24

  Online published: 2021-08-19

摘要

富镍三元正极材料随镍含量的增高伴随着循环性能差、热稳定性差、安全性能低等问题,使它的商业应用受到了一定限制。对富镍三元锂电正极材料存在的问题进行了简单的概述,重点总结和分析了对其进行改性方面的最新研究进展,并对其未来的发展方向进行了展望。

本文引用格式

马生花, 解玉龙, 王万玺 . 富镍三元正极材料的改性研究进展[J]. 化工新型材料, 2021 , 49(7) : 42 -46 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.07.010

Abstract

With the increase of nickel content,the commercial application of nickel-rich ternary cathode materials is limited because of its poor cycle performance,poor thermal stability,low safety performance and so on.The existing problems of nickel-rich ternary lithium cathode materials were briefly summarized,and introduced and analyzed the latest research progress on its modification.Its future development direction was prospected.

参考文献

[1] Ohzuku T,Makimura Y.Layered lithium insertion material of LiNi1/3Co1/3Mn1/3O2 for lithium-ion batteries[J].Chemistry Letters,2001,1(7):642-643.
[2] Belharouak I,Sun Y K,Liu J,et al.Li(Ni1/3Co1/3Mn1/3)O2 as a suitable cathode for high power applications[J].Journal of Power Sources,2003,123(2):247-252.
[3] Noh H J,Youn S,Yoon C S,et al.Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2(x=1/3,0.5,0.6,0.7,0.8 and 0.85) cathode material for lithium-ion batteries[J].Jounral of Power Sources,2013,233(1):121-130.
[4] Yamamoto Y,Ohtsuka M,Azumaet Y,et al.Cation mixing in LiNi0.8Co0.15Al0.05O2 positive electrode material studied using high angular resolition electron channeling X-ray spectroscopy[J].Journal of Power Sources,2018,401:263-270.
[5] Koyama Y,Arai H,Tanaka I,et al.Defect chemistry in layered LiMO2 (M=Co,Ni,Mn,andLi1/3Mn2/3) by first-principles calculations[J].ChemInForm,2012,24(20):3886-3894.
[6] Liu X,Ren D S,Hsu H J,et al.Thermal runaway of lithium-ion batteries without internal short circuit[J].Joule,2018,2(10):1-18.
[7] Liu H,Wolf M,Karki K,et al.Inter-granular cracking as a major cause of long-term capacity fading of layered cathodes[J].Nano Letters,2017,17(6):3452-3457.
[8] Ruan Y L,Song X Y,Fu Y B,et al.Structural evolution and capacity degradation mechanism of LiNi0.6Mn0.2Co0.2O2 cathode materials[J].Journal of Power Sources,2018,400(1):539-548.
[9] Sun H H,Manthiram A.Impact of microcrack generation and surface degradation on nickel-rich layered Li[Ni0.9Co0.05Mn0.05]O2 cathode for lithium-ion batteries[J].Chemistry of Materials,2017,29(19):8486-8493.
[10] 朱晓沛,张家文,张媛娇,等.高镍层状正极材料失效机理及改性的研究进展[J].硅酸盐学报,2019,47(6):742-751.
[11] Li W D,Liu X M,Celio H G,et al.Mn versus Al in layered oxide cathodes in lithium-ion batteries:a comprehensive evaluation on long-term cyclability[J].Advanced Energy Materials,2018,8(15):1703154.
[12] Lin Q Y,Guan W H,Meng J,et al.A new insight into continuous performance decay mechanism of Ni-rich layered oxide cathode for high energy lithium ion batteries[J].Nano Energy,2018,54:313-321.
[13] Zhang C,Qi J X,Zhao H,et al.Facile synthesis silkworm-like Ni-rich layered LiNi0.8Co0.1Mn0.1O2 cathode material for lithium-ion batteries[J].Materials Letters,2017,201:1-4.
[14] Tian J,Su Y F,Wu F,et al.High-rate and cycling-stable nickel-rich cathode materials with enhanced Li+ diffusion pathway[J].ACS Applied Materials & Interfaces,2016,8(1):582-587.
[15] Su Y F,Chen G,Chen L,et al.Exposing the {010} planes by oriented self-assembly with nanosheets to improve the electrochemical performances of Ni-Rich Li[Ni0.8Co0.1Mn0.1]O2 microspheres[J].ACS Applied Materials & Interfaces,2018,10(7):6407-6414.
[16] Lee Y H,Kima H,Yim T,et al.Compositional core-shell design by nickel leaching on the surface of Ni-rich cathode materials for advanced high-energy and safe rechargeable batteries[J].Journal of Power Sources,2018,400(1):87-95.
[17] Chen X L,Jia X B,Qu Y Y,et al.High-voltage performance of concentrationgradient Li[Ni0.6Co0.2Mn0.2]O2 layered oxide cathode materials for lithium batteries[J].New Journal of Chemistry,2018,42(8):5868-5874.
[18] Dong H,Liu G B,Li S M,et al.Design of a 3D-porous structure with residual carbon for high performance Ni-rich cathode materials[J].ACS Applied Materials & Interfaces,2019,11(2):2500-2506.
[19] Huang Z J,Wang Z X,Jing Q,et al.Investigation on the effect of Na doping on structure and Li-ion kinetics of layered LiNi0.6Co0.2Mn0.2O2 cathode material[J].Electrochimica Acta,2016,192(2):120-126.
[20] Mo Y,Guo L J,Cao B K,et al.Correlating structural changes of the improved cyclability upon Nd-substitution in LiNi0.5Co0.2Mn0.3O2 cathode materials[J].Energy Storage Materials,2019,18:260-268.
[21] Li Y C,Xiang W,Wu Z G,et al.Construction of homogeneously Al3+ doped Ni rich Ni-Co-Mn cathode with high stable cycling performance and storage stability via scalable continuous precipitation[J].Electrochimica Acta,2018,291:84-94.
[22] Wang D,Li X H,Wang Z X,et al.Role of zirconium dopant on the structure and high voltage electrochemical performances of LiNi0.5Co0.2Mn0.3O2 cathode materials for lithium ion batteries[J].Electrochimica Acta,2016,188(10):48-56.
[23] Yue P,Wang Z X,Guo H J,et al.A low temperature fluorine substitution the electrochemical performance of layered LiNi0.8Co0.1Mn0.1O2-zFz cathode materials[J].Electrochimica Acta,2013,92(1):1-8.
[24] Chen T,Li X,Wang H,et al.The effect of gradient boracic polyanion-doping on structure,morphology,and cycling performance of Ni-rich LiNi0.8Co0.15Al0.05O2 cathode material[J].Journal of Power Sources,2018,374(15):1-11.
[25] Ghorbanzadeh M,Farhadi S,Riahifar R,et al.Influence of Na and Nb co-substitution on electrochemical performance of ternary cathode materials for Li-ion batteries[J].New Journal of Chemistry,2018,42(5):3444-3451.
[26] Chen W H,Li Y Y,Zhao J J,et al.Controlled synthesis of concentration gradient LiNi0.84Co0.10Mn0.04Al0.02O1.90F0.10 with improved electrochemical property in Li-ion batteries[J].RSC Advances,2016,6(63):58173-58181.
[27] Hu G R,Zhang M F,Liang,L W,et al.Mg-Al-B co-substitution LiNi0.5Co0.2Mn0.3O2 cathode materials with improved cycling performance for lithium-ion battery under high cutoff voltage[J].Electrochimica Acta,2016,190(1):264-275.
[28] Dai S C,Yuan M L,Wang L,et al.Ultrathin-Y2O3-coated LiNi0.8Co0.1Mn0.1O2 as cathode materials for Li-ion batteries:synthesis,performance and reversibility[J].Ceramics International,2019,45(1):674-680.
[29] Chen Y X,Li Y J,Tang S Y,et al.Enhanced electrochemical properties of the Cd-modified LiNi0.6Co0.2Mn0.2O2 cathode materials at high cut-off voltage[J].Journal of Power Sources,2018,395:403-413.
[30] Kong J Z,Wang S S,Tai G A,et al.Enhanced electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode material by ultrathin ZrO2 coating[J].Journal of Alloys and Compounds,2016,657(5):593-600.
[31] Hyejung K,Min G K,Hu Y J,et al.A new coating method for alleviating surface degradation of LiNi0.6Co0.2Mn0.2O2 cathode material:nanoscale surface treatment of primary particles[J].Nano Letters,2015,15(3):2111-2119.
[32] Kim H,Lee S,Cho H,et al.Enhancing interfacial bonding between anisotropically oriented grains using a glue-nanofiller for advanced Li-ion battery cathode[J].Advanced Materials,2016,28(23):4705-4712.
[33] Yan P F,Zheng J M,Liu J,et al.Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries[J].Nature Energy,2018,3:600-605.
[34] Chen S,He T,Su Y F,et al.Ni-rich LiNi0.8Co0.1Mn0.1O2 oxide coated by dual-conductive layers as high performance cathode material for lithium-ion batteries[J].ACS Applied Materials & Interfaces,2017,9(35):29732-29743.
[35] Luo W B,Zheng B L.Improved electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode material by double-layer coating with graphene oxide and V2O5 for lithium-ion batteries[J].Applied Surface Ence,2017,404:310-317.
[36] Qiu Z P,Zhang Y J,Huang X S,et al.Benefical effect of incorporating Ni-rich oxide and layered over-lithiated oxide into high-energy-density cathode materials for lithium-ion batteries[J].Journal of Power Source,2018,400:341-349.
Options
文章导航

/