开发与应用

低品质硅源制备多孔气凝胶的研究进展

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  • 吉林建筑大学材料科学与工程学院,长春130118
赵洪凯(1974-),男,博士,教授,硕士研究生导师,主要从事复合材料研究,E-mail:hkzhao003@126.com。

收稿日期: 2020-11-20

  修回日期: 2021-04-23

  网络出版日期: 2021-06-10

基金资助

国家重点研发计划课题(2020YFD1100303)

Progress on preparation of porous aerogel from low quality silicon source

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  • School of Materials Science and Engineering,Jilin Jianzhu University,Changchun 130118

Received date: 2020-11-20

  Revised date: 2021-04-23

  Online published: 2021-06-10

摘要

传统硅源成本较高不利于长期发展,而低品质硅源资源丰富且廉价易得,大幅降低了制备成本。综述了以水玻璃、硅藻土、粉煤灰以及稻壳灰等作为硅源制备气凝胶的研究进展,具有工艺便捷、制备周期较短以及成本低等优异特点,使大规模工业化制备气凝胶成为可能。最后,对共前驱体法和一步法制备气凝胶的未来发展进行了总结与展望。

本文引用格式

赵洪凯, 张力化 . 低品质硅源制备多孔气凝胶的研究进展[J]. 化工新型材料, 2021 , 49(5) : 232 -236 . DOI: 10.19817/j.cnki.issn 1006-3536.2021.05.052

Abstract

The high cost of traditional silicon source is not conducive to long-term development,while the low-quality silicon source is rich and cheap,which greatly reduces the preparation cost.The research progress on preparing aerogels with silica glass,diatomite,fly ash and rice husk ash as silicon sources was reviewed.It had the advantages of convenient process,short preparation period and low cost,making it possible to prepare aerogels in large scale industrialization.Finally,the future development of aerogels prepared by the one-step method and the co-precursor method were summarized and prospected.

参考文献

[1] Huo T,Ren H,Zhang X,et al.China's energy consumption in the building sector:a statistical yearbook-energy balance sheet based splitting method[J].Journal of Cleaner Production,2018,185:665-679.
[2] 彭罗文,艾明星,柳培玉,等.二氧化硅气凝胶材料在建筑领域的应用研究及发展概述[J].建筑节能,2018,46(1):71-77.
[3] Lucchi E,Becherini F,Tuccio M C,et al.Thermal performance evaluation and comfort assessment of advanced aerogel as blown-in insulation for historic buildings[J].Building and Environment,2017,122:258-268.
[4] Tang L,Zhuang S,Hong B,et al.Synthesis of light weight,high strength biomass-derived composite aerogels with low thermal conductivities[J].Cellulose,2019,26(16):8699-8712.
[5] Randall J P,Meador M A B,Jana S C.Tailoring mechanical properties of aerogels for aerospace applications[J].ACS Appl Mater Interfaces,2011,3(3):613-626.
[6] Riffat S B,Qiu G.A review of state-of-the-art aerogel applications in buildings[J].International Journal of Low-carbon Technologies,2013,8(1):1-6.
[7] Obaidat R M,Alnaief M,Mashaqbeh H,et al.Investigation of carrageenan aerogel microparticles as a potential drug carrier[J].Aaps Pharmscitech,2018,19(5):2226-2236.
[8] 路国忠,郭建平,何光明,等.SiO2气凝胶制备技术及在建材中应用研究[J].新型建筑材料,2013,40(1):83-86.
[9] Du A,Zhou B,Zhang Z,et al.A special material or a new state of matter:a review and reconsideration of the aerogel[J].Materials,2013,6(3):941-968.
[10] 王妮,任洪波.不同硅源制备二氧化硅气凝胶的研究进展[J].材料导报,2014,28(1):42-45.
[11] 刘金玲,郭慰彬,白欣,等.改性二氧化硅气凝胶研究进展[J].广州化工,2019,47(6):16-18.
[12] El-Naggar M E.Synthesis,drying process and medical application of polysaccharide-based aerogels[J].International Journal of Biological Macromolecules,2020,145:1115-1128.
[13] 万郁楠,张波.以水玻璃为源制备SiO2气凝胶的最佳工艺研究[J].中国陶瓷工业,2016,23(2):22-25.
[14] Pan Y,Cheng X,Zhou T,et al.Spray freeze-dried monolithic silica aerogel based on water-glass with thermal superinsulating properties[J].Materials Letters,2018:265-268.
[15] Pan Y,He S,Cheng X,et al.A fast synthesis of silica aerogel powders-based on water glass via ambient drying[J].Journal of Sol-Gel Science and Technology,2017,82(2):594-601.
[16] Huang Y,He S,Feng M,et al.Organic solvent-saving preparation of water glass based aerogel granules under ambient pressure drying[J].Journal of Non-crystalline Solids,2019,521:119507.
[17] He S,Huang D,Bi H,et al.Synthesis and characterization of silica aerogels dried under ambient pressure bed on water glass[J].Journal of Non-Crystalline Solids,2015,410:58-64.
[18] Lee K J,Kim Y H,Lee J K,et al.Fast synthesis of spherical silica aerogel powders by emulsion polymerization from water glass[J].Chemistryselect,2018,3(4):1257-1261.
[19] Bhagat S D,Kim Y,Ahn Y,et al.Textural properties of ambient pressure dried water-glass based silica aerogel beads:one day synthesis[J].Microporous and Mesoporous Materials,2006,96(1):237-244.
[20] Zhao S,Stojanovic A,Angelica E,et al.Phase transfer agents facilitate the production of superinsulating silica aerogel powders by simultaneous hydrophobization and solvent- and ion-exchange[J].Chemical Engineering Journal,2020,381:122421.
[21] Dong G R,Su Z Q,Wang J B.Diatomite modification and its application in wastewater treatment[J].Advanced Materials Research,2014,850-851:1355-1359.
[22] Chen F,Miao Y,Ma L,et al.Optimization of pore structure of a clayey diatomite[J].Particulate Science and Technology,2019,38(5):522-528.
[23] Wang B,Ma H,Song K,et al.Preparation and characterization of silica aerogels from diatomite via ambient pressure drying[J].Russian Journal of Physical Chemistry A,2014,88(7):1196-1201.
[24] 王宝民,宋凯,韩瑜,等.硅藻土制备介孔SiO2气凝胶[J].土木建筑与环境工程,2013,35(2):141-146.
[25] Ma Hainan,Wang Baomin,Zhao Lei,et al.Preparation and properties of PMMA modified silica aerogels from diatomite[J].Journal of Wuhan University of Technology,2014,29(005):877-884.
[26] Gollakota A R K,Volli V,Shu C M.Progressive utilisation prospects of coal fly ash:a review[J].Ence of the Total Environment,2019,672:951-989.
[27] Lee Y R,Soe J T,Zhang S,et al.Synthesis of nanoporous materials via recycling coal fly ash and other solid wastes:a mini review[J].Chemical Engineering Journal,2017,317:821-843.
[28] Wu X,Fan M,Mclaughlin J F,et al.A novel low-cost method of silica aerogel fabrication using fly ash and trona ore with ambient pressure drying technique[J].Powder Technology,2018,323:310-322.
[29] Cheng Y,Xia M,Luo F,et al.Effect of surface modification on physical properties of silica aerogels derived from fly ash acid sludge[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2016,490:200-206.
[30] Shi F,Liu J,Song K,et al.Cost-effective synthesis of silica aerogels from fly ash via ambient pressure drying[J].Journal of Non-crystalline Solids,2010,356(43):2241-2246.
[31] Mao N D,Lee S Y,Shin H J,et al.Biomass fly ash as an alternative approach for synthesis of amorphous silica nanoparticles with high surface area[J].Journal of Nanoscience and Nanotechnology,2018,18(5):3329-3334.
[32] Shen M,Jiang X,Zhang M,et al.Synthesis of SiO2-Al2O3 composite aerogel from fly ash:a low-cost and facile approach[J].Journal of Sol Gel Science & Technology,2020,93(2):281-290.
[33] Pode R.Potential applications of rice husk ash waste from rice husk biomass power plant[J].Renewable & Sustainable Energy Reviews,2016,53:1468-1485.
[34] Tang Q,Wang T.Preparation of silica aerogel from rice hull ash by supercritical carbon dioxide drying[J].Journal of Supercritical Fluids,2005,35(1):91-94.
[35] Rajanna S K,Vinjamur M,Mukhopadhyay M,et al.Mechanism for formation of hollow and granular silica aerogel microspheres from rice husk ash for drug delivery[J].Journal of Non-crystalline Solids,2015,429:226-231.
[36] Feng Q,Chen K,Ma D,et al.Synthesis of high specific surface area silica aerogel from rice husk ash via ambient pressure drying[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2018,539:399-406.
[37] Cui S,Yu S,Lin B,et al.Preparation of amine-modified SiO2 aerogel from rice husk ash for CO2 adsorption[J].Journal of Porous Materials,2016,24(2):1-7.
[38] Zulhelmi A A H,Muhamad A M Y,Halimaton H.Effects of solvent exchange period and heat treatment on physical and chemical properties of rice husk derived silica aerogels[J].Silicon,2020,13(4):251-257.
[39] Tadjarodi A,Haghverdi M,Mohammadi V.Preparation and characterization of nano-porous silica aerogel from rice husk ash by drying at atmospheric pressure[J].Materials Research Bulletin,2012,47(9):2584-2589.
[40] Ban G,Song S,Lee H W,et al.Effect of acidity levels and feed rate on the porosity of aerogel extracted from rice husk under ambient pressure[J].Nanomaterials,2019,9(2):300.
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