以污泥为基质的碳量子点的制备及表征

张婷婷, 张家乐, 薛少宸, 单凤君

化工新型材料 ›› 2020, Vol. 48 ›› Issue (6) : 288 -290.

PDF (1360KB)
化工新型材料 ›› 2020, Vol. 48 ›› Issue (6) : 288-290.
开发与应用

以污泥为基质的碳量子点的制备及表征

    张婷婷, 张家乐, 薛少宸, 单凤君
作者信息 +

Preparation and characterization of CQDs based on sludge

  • Zhang Tingting, Zhang Jiale, Xue Shaochen, Shan Fengjun
Author information +
文章历史 +
PDF (1392K)

摘要

以污泥作为基质,经高温碳化后利用乙酸/过氧化氢(HAc/H2O2)氧化法制备碳量子点。通过荧光光谱仪和紫外-可见分光光度计对制备的碳量子点进行表征。结果表明:碳量子点在激发波长为320nm时荧光强度最高,达到9999,可与以传统石墨粉、碳棒为基质制备的碳量子点相媲美,并且在波长320nm和400nm处有明显的紫外吸收峰。傅里叶变换红外光谱分析表明,碳量子点表面含有丰富的含氧官能团,有利于其进一步功能化。以污泥为基质、采用HAc/H2O2氧化法制备的碳量子点具有较高的应用潜力,能够为污泥的资源化利用开辟新途径。

Abstract

Sludges were used as substrate to prepared carbon quantum dots (CQDs).After high temperature carbonization of sludges,CQDs were prepared by HAc/H2O2 oxidation method.CQDs were characterized by photoluminescence spectra (PL) and UV-visible spectroscopy (UV-Vis).The results shown that the fluorescence intensity of CQDs was the highest with the excitation wavelength 320nm,reached 9999.It had UV-Vis spectrums at 320nm and 400nm,respectively.The fluorescence property of CQDs can rival that of traditional CQDs which prepared with graphite powder and carbon rods.The fourier transform infrared spectroscopy (FT-IR) results shown that there were some oxygen-containing functional groups on CQDs surface.That was conducive to the further functionalization of CQDs.This indicated that CQDs prepared with sludge had high application potential.It provided a new developing orientation on the resource utilization of sludge.

关键词

污泥 / 碳量子点 / 化学氧化法

Key words

sludge / carbon quantum dots / chemical oxidation method

引用本文

引用格式 ▾
以污泥为基质的碳量子点的制备及表征[J]. 化工新型材料, 2020, 48(6): 288-290 DOI:

登录浏览全文

4963

注册一个新账户 忘记密码

参考文献

[1] 查湘义.浅谈我国污水处理厂污泥利用现状[J].农业科技与信息,2016(22):47-48.
[2] 朱玉珍,潘悝.我国城市污泥处理现状及资源化简述[J].山东工业技术,2018,19(211):245.
[3] 胡春云,陈鹏,吴家桦,等.城市污泥处理处置技术现状及展望[J].东方电气评论,2018,32(127):16-19.
[4] Wang Y,Hu A.Carbon quantum dots synthesis properties and applications[J].Journal of Materials Chemistry C,2014,2(34):6921-6939.
[5] Li S,Shen W,Gao Z.Carbon quantum dots and their spplications[J].Chemical Society Reviews,2015,44(1):362-381.
[6] Li H,Kang Z,Liu Y,et al.Carbon nanodots synthesis properties and applications[J].Journal of Materials Chemistry,2012,22(46):24230-24253.
[7] Luo P,Yang F,Yang S,et al.Carbon-based quantum dots for fluorescence imaging of cells and tissues[J].RSC Advances,2014,4(21):10791-10807.
[8] Zhao Qiaoling,Zhang Zhiling,Huang Bihai,et al.Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite[J].Chemical Communications,2008,41:5116-5118.
[9] Chen Guanxiong,Wu Shuilin,Hui Liwei,et al.Assembling carbon quantum dots to a layered carbon for high-density supercapacitor electrodes[J].Scientific Reports,2016,6:19028-19037.
[10] Shiral Fernando K A,Sushant Sahu,Liu Yamin,et al.Carbon quantum dots and applications in photocatalytic energy conversion[J].ACS Appl Mater Interfaces,2015,7:8363-8376.
[11] Li Chenxiong,Yu Chao,Wang Caifeng,et al.Facile plasma-induced fabrication of fluorescent carbon dots toward high-performance white LEDs[J].J Mater Sci,2013,48:6307-6311.
[12] Nargish Parvin,Tapas Manda K,Dually Emissive P.N-Co-doped carbon dots for fluorescent and photoacoustic tissue imaging in living mice[J].Microchim Acta,2017,184:1117-1125.
[13] Zhang Tingting,Zhao Huimin,Fan Xinfei,et al.Electrochemilumine science immunosensor for highly ensitive detection of 8-hydroxy-2′-deoxyguanosine based on carbon quantum dot coated Au/SiO2 core-shell nanoparticles[J].Talanta,2015,131:379-385.
[14] 武仪,张海容.微波法一步合成柠檬酸碳量子点及其分析应用[J].化工时刊,2018,32(1):5-8.
[15] Zhao H X,Liu L Q,Liu D Z,et al.Highly selective detection of phosphate in very complicated matrixes with an off-on fluorescent probe of europium-adjusted carbon dots[J].Chemical Communications,2011,47(9):2604-2606.
[16] Zhu S,Meng Q,Wang L,et al.Highly photoluminescent carbon dots for multicolor patterning,sensors,and bioimaging[J].Angewandte Chemie-International Edition,2013,125(14):4045-4049.
[17] Zhou J J,Sheng Z,Han H,et al.Facile synthesis of fluorescent carbon dots using watermelon peel as a carbon sou[J].Materials Letters,2012,66(1):222-224.
[18] 莫测辉,蔡全英,王江海.城市污泥在矿山废弃地复垦的应用探讨[J].生态学杂志,2001,20(2):44-47.
[19] 卢庆.碳量子点的制备及其在环境与生物分析中的应用[D].镇江:江苏大学,2016.
[20] 吴鹏飞,敖燕辉,王沛芳,等.碳量子点的合成和应用[J].材料导报,2016,30(7):30-35.

基金资助

辽宁省教育厅高校基本科研项目(JQL201715403);工业生态与环境工程教育部重点实验室开放基金(KLIEEE-16-07)

AI Summary AI Mindmap
PDF (1360KB)

771

访问

0

被引

导航
相关文章

AI思维导图

/