阳离子聚丙烯酰胺是一种线性高分子材料,具有良好的去浊、粘合、脱色性能,广泛应用于化工环保、石油、造纸、建筑、食品等领域。综述了水溶液聚合法、反相乳液聚合法、反相微乳液聚合法、分散聚合法以及模板聚合法等阳离子聚丙烯酰胺的制备方法,介绍了阳离子聚丙烯酰胺在水处理、石油工业、造纸业等方面的应用并对其发展趋势进行了展望。
Cationic polyacrylamide(PAGE) is a linear polymer material,because of its good turbidity removal,adhesion and decolorization properties,it can be widely used in chemical environmental protection,petroleum,paper making,construction,food and other fields.The preparation methods of cationic PAGE,such as aqueous solution polymerization,inverse emulsion polymerization,inverse microemulsion polymerization,dispersion polymerization and template polymerization,etc.were mainly introduced.The application of cationic PAGE in water treatment,petroleum industry,paper industry and other fields was introduced,and the development trend of cationic PAGE was prospected.
[1] Razali M A A,Ahmad Z,Ahmad M S B,et al.Treatment of pulp and paper mill wastewater with various molecular weight of polyDADMAC induced flocculation[J].Chemical Engineering Journal,2011,166(2):529-535.
[2] Zhang W,Ma H,Wang Q,et al.Pretreatment technology for suspended solids and oil removal in an ethanol fermentation broth from food waste separated by pervaporation process[J].Desalination,2012,293:112-117.
[3] Wisniewska M,Chibowski S,Urban T.Effect of the presence of cationic polyacrylamide on the surface properties of aqueous alumina suspension-stability mechanism[J].Applied Surface Science,2014,320:843-851.
[4] Zheng H,Sun Y,Tang X,et al.UV-initiated polymerization of cationic polyacrylamide:synthesis,characterization,and sludge dewatering performance[J].Scientific World Journal,2013,2013:1-7.
[5] Zhu J,Zheng H,Jiang Z,et al.Synthesis and characterization of a dewatering reagent:cationic polyacrylamide [P(AM-DMC-DAC)] for activated sludge dewatering treatment[J].Desalination and Water Treatment,2013,51(13/14/15):2791-2801.
[6] Liao Y,Zheng H,Qian L,et al.UV-initiated polymerization of hydrophobically associating cationic polyacrylamide modified by a surface-active monomer:a comparative study of synthesis,characterization,and sludge dewatering performance[J].Industrial & Engineering Chemistry Research,2014,53(27):11193-11203.
[7] Barari M,Abd E M,Hemati M.Synthesis and characterization of high molecular weight polyacrylamide nanoparticles by inverse-emulsion polymerization[J].Iranian Polymer Journal,2011,21(1):65-76.
[8] 陈勇.丙烯酰胺/甲基丙烯酰氧乙基三甲基氯化铵反相乳液聚合[D].杭州:浙江大学,2018.
[9] 颜学敏,匡绪兵.阳离子聚丙烯酰胺的反相乳液合成及其絮凝性能[J].石油与天然气化工,2010,39(4):20.
[10] Yoon D H,Jang J W,Cheong I W.Synthesis of cationic polyacrylamide/silica nanocomposites from inverse emulsion polymerization and their flocculation property for papermaking[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2012,411:18-23.
[11] 李素莲,刘伟.反相微乳液制备无单体残留阳离子聚丙烯酰胺[J].信阳师范学院学报:自然科学版,2015,28(3):389-392.
[12] Li G,Zhang G,Wang L,et al.Cationic microgel emulsion with a high solid content by a multistep addition method in inverse microemulsion polymerization[J].Journal of Applied Polymer Science,2014,131(15):40585-40590.
[13] 王永贵.反相微乳液法合成阳离子型和两性聚丙烯酰胺[D].西安:西北大学,2012.
[14] Xu J,Zhao W P,Wang C X,et al.Preparation of cationic polyacrylamide by aqueous two-phase polymerization[J].Express Polym Lett,2010,4(5):275-283.
[15] Liu Z,Wei Y,Li B,et al.Synthesis of cationic polyacrylamide by aqueous two-phase polymerization in poly (ethylene glycol) chloride solution[J].Journal of Applied Polymer Science,2013,127(1):593-598.
[16] Wu W B,Gu J,Jing Y,et al.Preparation and retention performance of cross-linked and hydrophobically associating cationic polyacrylamide[J].Bio Resources,2012,7(4):4926-4937.
[17] Zheng H L,Zhu J R,Jiang Z Z,et al.Research on preparation and application of dewatering agents for tailings water treatment[J].Advanced Materials Research,2012,414:172-178.
[18] 卜道露,万涛,宋茂生,等.分散聚合法聚丙烯酰胺微球调剖剂的研究[J].化工新型材料,2013,41(3):42-44.
[19] Guan Q,Zheng H,Zhai J,et al.Effect of template on structure and properties of cationic polyacrylamide:characterization and mechanism[J].Industrial & Engineering Chemistry Research,2014,53(14):5624-5635.
[20] Zhang Z,Zheng H,Huang F,et al.Template polymerization of a novel cationic polyacrylamide:sequence distribution,characterization,and flocculation performance[J].Industrial & Engineering Chemistry Research,2016,55(37):9819-9828.
[21] Li X,Zheng H,Gao B,et al.UV-initiated template copolymerization of AM and MAPTAC:microblock structure,copolymerization mechanism,and flocculation performance[J].Chemosphere,2017,167:71-81.
[22] Feng L,Zheng H,Gao B,et al.Enhancement of textile-dyeing sludge dewaterability using a novel cationic polyacrylamide:role of cationic block structures[J].RSC Advances,2017,7(19):11626-11635.
[23] Abdelkader R,Mohammed B.Green synthesis of cationic polyacrylamide composite catalyzed by an ecologically catalyst clay called maghnite-H+ (algerian MMT) under microwave irradiation[J].Bulletin of Chemical Reaction Engineering & Catalysis,2016,11(2):170-175.
[24] Lee C S,Robinson J,Chong M F.A review on application of flocculants in wastewater treatment[J].Process Safety and Environmental Protection,2014,92(6):489-508.
[25] Ma J,Fu K,Fu X,et al.Flocculation properties and kinetic investigation of polyacrylamide with different cationic monomer content for high turbid water purification[J].Separation and Purification Technology,2017,182:134-143.
[26] Zhao C,Zheng H,Gao B,et al.Ultrasound-initiated synthesis of cationic polyacrylamide for oily wastewater treatment:enhanced interaction between the flocculant and contaminants[J].Ultrasonics Sonochemistry,2018,42:31-41.
[27] 孙永军.紫外光引发聚合P(AM-DAC-BA)及其污泥脱水研究[D].重庆:重庆大学,2014.
[28] Lee K E,Morad N,Poh B T,et al.Comparative study on the effectiveness of hydrophobically modified cationic polyacrylamide groups in the flocculation of kaolin[J].Desalination,2011,270(1/2/3):206-213.
[29] Abdollahi Z,Frounchi M,Dadbin S.Synthesis,characterization and comparison of PAM,cationic PDMC and P (AM-co-DMC) based on solution polymerization[J].Journal of Industrial and Engineering Chemistry,2011,17(3):580-586.
[30] Zheng H,Liao Y,Zheng M,et al.Photoinitiated polymerization of cationic acrylamide in aqueous solution:synthesis,characterization,and sludge dewatering performance[J].Scientific World Journal,2014,2014:1-11.
[31] Ma J,Shi J,Ding H,et al.Synthesis of cationic polyacrylamide by low-pressure UV initiation for turbidity water flocculation[J].Chemical Engineering Journal,2017,312:20-29.
[32] Sun Y,Zheng H,Zhai J,et al.Effects of surfactants on the improvement of sludge dewaterability using cationic flocculants[J].Plos One,2014,9(10):111036.
[33] 张昊.超支化聚丙烯酰胺的合成与双重交联凝胶堵水剂的研究[D].大庆:东北石油大学,2017.
[34] Li X,Zou C,Cui C.Synthesis and characterization of a novel β-cyclodextrin modified cationic polyacrylamide and its application for enhancing oil recovery[J].Starch-Stärke,2015,67(7/8):673-682.
[35] Yang Z L,Gao B Y,Li C X,et al.Synthesis and characterization of hydrophobically associating cationic polyacrylamide[J].Chemical Engineering Journal,2010,161(1/2):27-33.
[36] Peng Y,He B,Zhao L.Lime mud CaCO3 for use as a filler material in papermaking:impact of its preflocculation with cationic polyacrylamide[J].Journal of Applied Polymer Science,2015,132(11):41640-41647.
[37] Petroudy S R D,Syverud K,Chinga-Carrasco G,et al.Effects of bagasse microfibrillated cellulose and cationic polyacrylamide on key properties of bagasse paper[J].Carbohydrate Polymers,2014,99:311-318.
[38] Xue Y,Pan Y,Xiao H,et al.Novel quaternary phosphonium-type cationic polyacrylamide and elucidation of dual-functional antibacterial/antiviral activity[J].RSC Advances,2014,4(87):46887-46895.
[39] Raj P,Varanasi S,Batchelor W,et al.Effect of cationic polyacrylamide on the processing and properties of nanocellulose films[J].Journal of Colloid and Interface Science,2015,447:113-119.
[40] Wang Q,Liu S,Yang G,et al.Cationic polyacrylamide enhancing cellulase treatment efficiency of hardwood kraft-based dissolving pulp[J].Bioresource Technology,2015,183:42-46.
基金资助
国家自然科学基金资助项目(51568048)
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