TiO2基光催化剂结构调控及改性方法研究进展

徐贺龙, 王俊磊, 王雪芹*

化工新型材料 ›› 2020, Vol. 48 ›› Issue (6) : 38 -42.

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化工新型材料 ›› 2020, Vol. 48 ›› Issue (6) : 38-42.
综述与专论

TiO2基光催化剂结构调控及改性方法研究进展

    徐贺龙, 王俊磊, 王雪芹*
作者信息 +

Research progress in structure regulation and modification of TiO2-based photocatalyst

  • Xu Helong, Wang Junlei, Wang Xueqin
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文章历史 +
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摘要

TiO2半导体材料由于具有催化活性高、成本低廉且化学性质稳定等优点,在环境治理及能源转化领域受到广泛关注。然而TiO2本身禁带宽度较大,仅在紫外光范围内具有较高的催化活性,且电子-空穴对的再复合率较高,导致其对于太阳光的利用率较低。如何提高TiO2半导体材料对于太阳光的利用率并促进电子-空穴对的快速分离成为当前的研究热点。从TiO2纳米材料微观结构调控以及负载改性方式两方面综述了其最新研究进展,以期对进一步改善TiO2基纳米材料的光催化性能提供一定的指导意义。

Abstract

Due to the advantages of high catalytic activity,low cost and stable chemical properties,TiO2 semiconductor materials have attracted extensive attention in the field of environmental governance and energy conversion.However,TiO2 itself has a wide band gap and high catalytic activity only in the range of UV light.Moreover,the recombination rate of electron-hole pairs is high,resulting in its low utilization rate of sunlight.How to improve the utilization rate of TiO2 semiconductor materials for sunlight and promote the rapid separation of electron-hole pairs has become a research hotspot in the current field.The latest research progress of TiO2 nanomaterials was reviewed from the aspects of microstructure regulation and load modification methods,which had certain guiding significance for further improving the photocatalytic performance of TiO2 nanomaterials.

关键词

TiO2纳米颗粒 / 光催化 / 掺杂改性 / 结构调控

Key words

TiO2 nanoparticle / photocatalysis / doping modification / structure regulation

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TiO2基光催化剂结构调控及改性方法研究进展[J]. 化工新型材料, 2020, 48(6): 38-42 DOI:

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参考文献

[1] 唐爱东,任艳萍.二氧化钛催化剂晶型调控技术的研究进展[J].中国粉体技术,2010,16(3):69-73.
[2] 张朋杰,秦丽慧,张亚非,等.水热法合成暴露{001}晶面TiO2的研究[J].计算机与应用化学,2018,35(5):385-389.
[3] 姚霞喜,王文寿.晶面调控和新型二氧化钛纳米结构的研究进展[J].中国材料进展,2017(36):860-867,859.
[4] 曹玉辉.具有{101}与{001}晶面异质结TiO2纳米晶的制备及其光催化还原CO2性能研究[D].郑州:河南大学,2016.
[5] 张文彬,谢利群,白元峰.纳米TiO2光催化机理及改性研究进展[J].化工科技,2005,13(6):52-57.
[6] 刘强,曹明飞,刘恩东,等.水热法制备TiO2纳米线及其煅烧温度影响的研究[J].环保科技,2017(6):12-15.
[7] Navab A A,Nemati A,Navab A A,et al.Hydrothermal synthesis of TiO2 nanorod for using as an electron transport material in perovskite solar cells[J].American Institute of Physics Conference,2018,1920(1):020015.
[8] Menglei C,Huawen H,Yuyuan Z,et al.Improving visible light-absorptivity and photoelectric conversion efficiency of a TiO2 nanotube anode film by sensitization with Bi2O3 nanoparticles[J].Nanomaterials,2017,7(5):104.
[9] Samsuri S A M,Rahman M Y A,Umar A A.Comparative study of the properties of TiO2 nanoflower and TiO2-ZnO composite nanoflower and their application in dye-sensitized solar cells[J].Ionics,2017,23:1897-1902.
[10] 郝贵敏,贾春阳,涂亮亮,等.TiO2光催化核壳材料的研究进展[J].材料导报,2011,25(13):25-30.
[11] Nguyen D T,Kim K S.Self-development of hollow TiO2 nanoparticles by chemical conversion coupled with Ostwald ripening[J].Chemical Engineering Journal,2016,286:266-271.
[12] 任艳梅,李银辉,王姝人,等.可见光响应TiO2中空球的制备及在降解水体中有机物的应用[J].纤维素科学与技术,2017,25(2):45-51.
[13] 梁可心,徐芸菲,许佩瑶,等.复合TiO2纳米管材料光催化裂解水产氢研究进展[J].化工进展,2017,36(11):4051-4056.
[14] 蒋建婷,张文静,王蔚,等.TiO2纳米材料在直接甲醇燃料电池阳极催化剂中应用的研究进展[J].材料科学与工程学报,2018,36(1):163-168.
[15] 董浩,黄秋安,石大为,等.TiO2有序纳米管阵列的阳极氧化法制备[J].湖北大学学报(自科版),2018,40(2):119-123.
[16] 马东,赵园园,童佩斐,等.Cu2O@TiO2核壳异质结的制备及其光催化性能研究[J].淮北师范大学学报(自然科学版),2017,38(1):41-45.
[17] Ma L,Wang G,Jiang C,et al.Synthesis of core-shell TiO2@g-C3N4,hollow microspheres for efficient photocatalytic degradation of rhodamine B under visible light[J].Applied Surface Science,2018,430:263-272.
[18] Ma J,Sun N,Wang C,et al.Facile synthesis of novel Fe3O4@SiO2@mSiO2 @TiO2 core-shell microspheres with mesoporous structure and their photocatalytic performance[J].Journal of Alloys and Compounds,2018,743:456-463.
[19] 张晶晶,李莉,张鑫悦,等.空心球形In2O3/ZrO2-TiO2纳米复合材料多模式光催化[J].化学通报,2017,80(10):935-941,975.
[20] 鲁盼,姚秉华,张文,等.PTF敏化TiO2中空微球的制备及可见光催化性能[J].功能材料,2014,45(20):20107-20112,20117.
[21] 刘阳龙,郑玉婴,曹宁宁,等.铁铕共掺杂的TiO2空心微球的制备及光催化活性[J].复合材料学报,2016,33(7):1492-1499.
[22] 郝翠玉.小尺寸中空二氧化钛纳米材料的制备、掺杂改性及光催化性能研究[D].长春:吉林大学,2018.
[23] Zhang Y,Zhao Z,Chen J,et al.C-doped hollow TiO2 spheres:in situ synthesis,controlled shell thickness,and superior visible-light photocatalytic activity[J].Applied Catalysis B Environmental,2015,165:715-722.
[24] 王家恒,宫长伟,付现凯,等.TiO2光催化剂的掺杂改性及应用研究进展[J].化工新型材料,2016,44(1):15-18.
[25] Yang X J,Wang S,Sun H M,et al.Preparation and photocatalytic performance of Cu-doped TiO2 nanoparticles[J].Chinese lournal of Nonferrous Metals(English edition),2015,25(2):504-509.
[26] Mehraz S,Konsong P,Taleb A,et al.Large scale and facile synthesis of Sn doped TiO2 aggregates using hydrothermal synthesis[J].Solar Energy Materials and Solar Cells,2019,189:254-262.
[27] 刘英吉,王松,韩璐,等.非金属掺杂TiO2光催化剂的研究进展[J].河北科技师范学院学报,2011,25(4):56-60.
[28] 张理元,涂秋梅,由耀辉,等.F-掺杂TiO2制备及光降解甲基橙性能研究[J].人工晶体学报,2018,47(11):2408-2416.
[29] Phung H N T,Tran V N K,Duong P A,et al.Effect of co-doping and tri-doping with transition metals and a nonmetal on photocatalytic activity in visible light of TiO2 thin film[J].Journal of the Korean Physical Society,2017,70(11):995-1000.
[30] Liu D,Jun Z,Wang J Q,et al.Enhanced visible light photoelectrocatalytic degradation of organic contaminants by F and Sn co-doped TiO2 photoelectrode[J].Chemical Engineering Journal,2018,344:332-341.
[31] 蒋乐,魏琪,周彬,等.Gd掺杂和Gd/N共掺杂TiO2光催化剂的制备及其光催化性能研究[J].浙江理工大学学报(自然科学版),2017,37(1):152-158.
[32] 张莹,龚昌杰,燕宁宁,等.贵金属改性TiO2光催化剂的机理及研究进展[J].材料导报,2011,25(15):46-49.
[33] Grabowska E,Marchelek M,Klimczuk T,et al.Noble metal modified TiO2 microspheres:surface properties and photocatalytic activity under UV-vis and visible light[J].Journal of Molecular Catalysis A:Chemical,2016,423:191-206.
[34] 路彦丽,王梦幻,张汀兰,等.改性TiO2光催化水解制氢的研究进展[J].化工新型材料,2018,46(3):10-13.
[35] Hassan S M,Ahmed A I,Mannaa M A.Structural,photocatalytic,biological and catalytic properties of SnO2/TiO2 nanoparticles[J].Ceramics International,2018,44(6):6201-6211.
[36] Faisal M,Harraz F A,Ismail A A,et al.Novel mesoporous NiO/TiO2,nanocomposites with enhanced photocatalytic activity under visible light illumination[J].Ceramics International,2018,44(6):7047-7056.
[37] Li Q,Xia Y,Yang C,et al.Building a direct Z-scheme heterojunction photocatalyst by ZnIn2S4,nanosheets and TiO2,hollowspheres for highly-efficient artificial photosynthesis[J].Chemical Engineering Journal,2018,349:287-296.
[38] Cano-Franco J C,Álvarez-Láinez M.Effect of CeO2 content in morphology and optoelectronic properties of TiO2-CeO2 nanoparticles in visible light organic degradation[J].Materials Science in Semiconductor Processing,2019,90:190-197.

基金资助

黑龙江省高等学校创新人才培养计划项目(UNPYSCT-2018042);黑龙江省自然科学基金青年基金(QC2017005);黑龙江省博士后基金面上项目(LBH-Z15032);东北石油大学校培育基金(2017PYQZL-06)

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