综述了不饱和聚酯树脂包覆层在推进剂中的应用及国内外研究现状,分析了不饱和聚酯树脂结构特征,讨论了当前不饱和聚酯树脂包覆层存在的问题,并提出了不饱和聚酯树脂包覆层的发展方向。
The application and research status of unsaturated polyester resin (UPR) as solid propellant inhibitors were reviewed.The structural characteristics of UPR were analyzed,and the current problems of UPR inhibitor were also discussed.In the end the development direction of UPR was proposed.
[1] 谭惠民.固体推进剂化学与技术[M].北京:北京理工大学出版社,2015,452-457.
[2] 张侃,王亮,朱脉勇,等.不饱和聚酯基多相复合材料的导热和力学性能研究[J].化工新型材料,2017,45(10):73-75,79.
[3] 吴淑新,姚逸伦,史爱娟,等.聚氨酯在固体推进剂包覆层中的应用[J].化学推进剂与高分子材料,2010,8(6):14-16.
[4] 吴淑新,史爱娟,姚逸伦,等.异氰脲酸酯改性聚氨酯弹性体包覆层研究[J].化学推进剂与高分子材料2011,9(2):53-55.
[5] 李冬,陈竚,任黎,等.三元乙丙基固体推进剂包覆层拉伸性能影响因素研究[J].化工新型材料,2011,39(9):98-99,137.
[6] 张中水,许进升,陈雄,等.EPDM包覆层热解状态下的力学行为及本构模型[J].固体火箭技术,2016,39(4):560-564.
[7] Huang Z P,Nie H Y,Zhang Y Y,et al.Migration kinetics and mechanisms of plasticizers,stabilizers at interfaces of NEPE propellant/HTPB liner/EDPM insulation[J].Journal of Hazardous Materials,2012,229-230:251-257.
[8] 王泽山.火炸药理论与实践[M].北京:中国北方工业化学总公司,2001,158-162.
[9] 陈国辉,常海.硅橡胶包覆层的研究进展[J].含能材料,2005,13(3):200-203.
[10] 曹继平,李东林,王吉贵.不饱和聚酯包覆含DNT双基推进剂的研究[J].火炸药学报,2006,29(4):41-43,46.
[11] 徐喻琼,游敏,瞿金平,等.二氧化硅增强增韧不饱和聚酯[J].华南理工大学学报(自然科学版),2008,36(7):106-110,116.
[12] Xiao Y H,Wang X,Yang X J,et al.Nanometre-sized TiO2 as applied to the modification of unsaturated polyester resin[J].Materials Chemistry and Physics,2003,77(2):609-611.
[13] Hou Y,Hu W,Gui Z,et al.Effect of cuprous oxide with different sizes on thermal and combustion behaviors of unsaturated polyester resin[J].Journal of Hazardous Materials,2017,334:39-48.
[14] Wang D,Kan Y,Yu X,et al.In situ loading ultra-small Cu2O nanoparticles on 2D hierarchical TiO2-graphene oxide dual-nanosheets:towards reducing fire hazardsof unsaturated polyester resin[J].Journal of Hazardous Materials,2016,320:504-512.
[15] Hapuarachchi T D,Bilotti E,Reynolds C T,et al.The synergistic performance of multiwalled carbon nanotubes and sepiolite nanoclays as flame retardants for unsaturated polyester[J].Fire and Materials,2011,35(3):157-169.
[16] Cai J,Heng H M,Hu X P,et al.A facile method for the preparation of novel fire-retardant layered double hydroxide and its application as nanofiller in UP[J].Polymer Degradation and Stability,2016,126:47-57.
[17] 许耀升.聚酯阻燃层之开发[D].台湾:国立中山大学材料科研究所,1994.
[18] Agrawal J P,Chowk M P,Satpute R S.Study on mixed glycols-based semi-flexible unsaturated polyester resins for inhibition of rocket propellants[J].British Polymer Journal,1982,14(1):29-34.
[19] Agrawal J P,Chowk M P,Satpute R S,et al.The role of alumina trihydrate filler on semiflexible unsaturated polyester resin-4 and inhibition of double-base rocket propellants[J].Propellants,Explosives,Pyrotechnics,1985,10(3):77-81.
[20] 李东林,曹继平,王吉贵.不饱和聚酯包覆层的耐烧蚀性能[J].火炸药学报,2006,29(3):17-19,22.
[21] 皮文丰,王吉贵.包覆红磷在UPR包覆层耐烧蚀改性中的应用[J].火炸药学报,2009,32(3):54-57.
[22] 杨士山,张伟,王吉贵.聚氨酯增韧不饱和聚酯包覆层的研究[J].现代化工,2011,31(4):59-61.
[23] 史爱娟,刘晨,强伟.纳米填料对不饱和聚酯树脂包覆层性能影响[J].化工新型材料,2017,45(3):122-123,127.
[24] 杨士山,刘晨,强伟.MMT/UPR包覆材料分散工艺研究[J].化工新型材料,2015,43(10):154-156.
[25] 杨士山,张伟,王吉贵.功能添加剂对不饱和聚酯包覆剂黏度和凝胶时间的影响[J].火炸药学报,2011,34(4):75-77,82.
[26] 强伟,王吉贵.纳米填料在不饱和聚酯(UP)包覆层改性中的应用前景[J].火炸药学报,2005,28(3):37-40.
[27] 马晓东,强伟,路向辉,等.纳米TiO2对不饱和聚酯树脂包覆层的改性[J].火炸药学报,2006,29(2):48-50.
基金资助
中国博士后科学基金(2019M653532)
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