载铂Fe3O4碳球的制备及催化降解方面的应用

苏策, 黄雪莲, 白玲玲, 尚朝阳, 李思良

化工新型材料 ›› 2019, Vol. 47 ›› Issue (10) : 259 -263.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (10) : 259-263.
开发与应用

载铂Fe3O4碳球的制备及催化降解方面的应用

    苏策, 黄雪莲, 白玲玲, 尚朝阳, 李思良
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Preparation of platinum-containing ferroferric oxide carbon spheres and its application in catalytic degradation

  • Su Ce, Huang Xuelian, Bai Lingling, Shang Zhaoyang, Li Siliang
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摘要

生物质廉价易得且可再生,经水热法合成碳球及载铂Fe3O4碳球在对甲基橙的催化降解性能方面的应用和对环境保护都具有重要意义。以生物质葡萄糖为原料、水为溶剂,通过水热反应合成了碳球及制备出载铂Fe3O4碳球。采用场发射扫描电子显微镜(SEM)、场发射透射电子显微镜(TEM)、X射线衍射仪(XRD)和X射线光电子能谱仪(XPS)等测试手段,对碳球和磁性材料样品的形貌、结构、组成进行了表征。并以甲基橙与硼氢化钠的还原反应为模型,利用紫外-可见分光光度计(UV-Vis)来考察载铂磁性碳的催化降解性能。

Abstract

Biomass is cheap and readily available and renewable.The hydrothermal synthesis of carbon spheres and platinum-supported ferroferric oxide spheres is of great significance in the application of catalytic degradation of methyl orange and in environmental protection.Using biomass glucose as raw material and water as solvent,carbon spheres were synthesized by a hydrothermal reaction and a platinum-containing ferrous tetracarbonate sphere was prepared.Field emission electron microscopy (SEM),field emission transmission electron microscopy (TEM),X-ray diffraction (XRD),and X-ray photoelectron spectroscopy (XPS) were used to measure the morphology of spheres and magnetic materials.The structure,composition and composition were characterized.The degradation of platinum-bearing magnetic carbon was investigated by ultraviolet-visible spectrophotometer (UV-Vis) using the reduction reaction of methyl orange and sodium borohydride as models.

关键词

铂纳米粒子 / 磁性纳米碳球 / 水热法 / 甲基橙

Key words

platinum nanoparticle / magnetic nanocarbon sphere / hydrothermal method / methyl orange

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载铂Fe3O4碳球的制备及催化降解方面的应用[J]. 化工新型材料, 2019, 47(10): 259-263 DOI:

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参考文献

[1] He H B,Li B,Dong L,et al.Mesostructured nanomagnetic polyhedral oligomeric silsesquioxanes (POSS) incorporated with dithiol organic anchors for multiple pollutants capturing in wastewater[J].ACS Appl Mater Interfaces,2013,5(16):8058-8066.
[2] 王慧.磁性纳米材料在有机染料污染物去除中的应用研究[D].重庆:西南大学,2012.
[3] Bhatnagar A,Jain A K.A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water[J].Journal of Colloid and Interface Science,2005,281(1):49-55.
[4] Wesenberg D,Kyriakides I,Agathos S N.White-rot fungi and their enzymes for the treatment of industrial dye effluents[J].Biotechnology Advances,2003,22(1):161-187.
[5] Zhou L B,He B,Huang J.One-step synthesis of robust amine- and vinyl-cappedmagnetic iron oxide nanoparticles for polymer grafting,dye adsorption,and catalysis[J].ACS Appl Mater Interfaces,2013,5(17):8678-8685.
[6] Sekar S,Surianarayanan M,Ranganathan V D R,et al.Choline-based ionic liquids-enhanced biodegradation of azo dyes[J].Environmental Science & Technology,2012,46(9):4902.
[7] Cañizares P,Martínez F,Jiménez C J,et al.Coagulation and electrocoagulation of wastes polluted with dyes[J].Environmental Science & Technology,2006,40(20):6418-24.
[8] Laera G,Cassano D,Lopez A,et al.Removal of organics and degradation products from industrial wastewater by a membrane bioreactor integrated with ozoneor UV/H2O2 treatment[J].Environmental Science & Technology,2012,46(2):1010.
[9] Oller I,Malato S,Sánchez-Pérez J.Combination of advanced oxidation processes and biological treatments for wastewater decontamination-a review[J].A Science of the Total Environment,2011,409(20):4141-4166.
[10] Dong Y,Sun C,Xu S,et al.Polychlorinated organic compounds (PCOCs) in the yangtse river water samples using SPE and GC/ECD[J].Bulletin of Environmental Contamination and Toxicology,2000,64(3):383-389.
[11] Su Y,Lu X,Xie M,et al.A one-pot synthesis of reduced graphene oxide-Cu2S quantum dot hybrids for optoelectronic devices[J].Nanoscale,2013,5(19):8889-8893.
[12] Chen X,Wu G,Chen J,et al.Synthesis of “clean” and well-dispersive Pd nanoparticles with excellent electrocatalytic property on graphene oxide[J].Journal of the American Chemical Society,2011,133(11):3693-5.
[13] Revati A K,Pandey,B D.Microbial synthesis of iron-based nanomaterials-a review[J].Bulletin of Materials Science,2011,34(2):191-198.
[14] Cobley C M,Chen J,Cho E C,et al.Gold nanostructures:a class of multifunctional materials for biomedical applications[J].Chem Soc Rev,2011,40(1):44-56.
[15] Deng Y,Cai Y,Sun Z,et al.Multifunctional mesoporous composite microspheres with well-designed nanostructure:a highly integrated catalyst system[J] Journal of the American Chemical Society,2010,132(24):8466-8473.
[16] Gagné F,Blaise C,Bermingham N.Lethal and sublethal effects of marine sediment extracts on rainbow trout hepatocytes[J].Toxicology Letters,1996,87(2):85-92.
[17] Ghosh Chaudhuri R,Paria S.Visible light induced photocatalytic activity of sulfur doped hollow TiO2 nanoparticles,synthesized via a novel route[J].Dalton Transactions,2014,43(14):5526-5534.
[18] Fu G,Tao L,Zhang M,et al.One-pot,water-based and high-yield synthesis of tetrahedral palladium nanocrystal decorated graphene[J].Nanoscale,2013,5(17):8007-8014.
[19] 吴雪艳,王开学,陈接胜.多孔碳材料的制备[J].化学进展,2012,24(Z1):262-274.
[20] 范艾爱,陈立潮,王广龙.基于三维石墨烯的重金属吸附及控制研究[J].太原理工大学学报,2014,45(6):727-730.
[21] 陈赞,李银辉,丁硼行,等.碳球的水热合成法制备及其对重金属离子的净化[J].工业水处理,2015,35(7):40-42,46.
[22] Xu L Q,Zhang W Q,Yang Q,et al.A novel route to hollow and solid carbon spheres[J].Carbon,2005,43(5):1084-1114.
[23] Jin Y Z,Gao C,Wen K H,et al.Large-scale synthesis and characterization of carbonspheres prepared by direct pyrolysis of hydrocarbons[J].Carbon,2005,43(9):1944-1953.
[24] Deshmukh A A,Mhlanga S D,Coville N J.Carbon spheres[J].Materials Science and Engineering R,2010,70(1-2):1-28.
[25] 杨永珍.重油残渣定向转化新型碳功能材料的研究[D].太原:太原理工大学,2007.
[26] Yang Y Z,Liu X G,Zhan C Y,et al.Controllable synthesis and modification of carbon micro-spheres from deoiled asphalt[J].Journal of Physics and Chemistry of Solids,2010,71(3):235-241.
[27] 马名杰,张爱芸.碳膜制备及应用研究发展[J].河南理工大学学报:自然科学版,2008,27(6):696-700.
[28] 杨永珍,刘伟峰,郭明聪,等.MnO2/碳微球复合材料的制备及其电化学性能[J].复合材料学报,2011,28(4):149-155.
[29] 金琳.钌/碳微球复合材料的制备及电化学性能的研究[D].太原:太原理工大学.
[30] 金琳,刘旭光,杨永珍,等.碳微球负载钌纳米颗粒复合材料的化学键制备[J].材料导报,2010,24(16):21-24.
[31] Yang T,Shen C,Li Z,et al.Highly ordered self-assembly with large area of Fe3O4 nanoparticles and the magnetic properties[J].J Phys Chem B,2005,109:23233-23237.
[32] Amali A J,Rana R K.Stabilisation of Pd(0) on surface functionalised Fe3O4 nanoparticles:magnetically recoverable and stable recyclable catalyst for hydrogenation and Suzuki-Miyaura reactions[J].Green Chem,2009,11:1781-1785.

基金资助

国家自然科学基金(21761019)

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