基于新型材料PTB7-Th的串联结构聚合物太阳能电池仿真研究

黄智淼, 臧月*, 辛青, 林君

化工新型材料 ›› 2019, Vol. 47 ›› Issue (10) : 134 -136.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (10) : 134-136.
科学研究

基于新型材料PTB7-Th的串联结构聚合物太阳能电池仿真研究

    黄智淼, 臧月*, 辛青, 林君
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Optical modeling of tandem PSCs based on a new material PTB7-Th

  • Huang Zhimiao, Zang Yue, Xin Qin, Lin Jun
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摘要

采用新型给体材料PTB7-Th与受体材料PC71BM的混合层作为串联结构聚合物太阳能电池的后电池。通过光学传输矩阵理论,研究前后电池活性层厚度以及超薄金属Ag薄膜对串联器件短路电流密度的影响。结果表明:当前电池厚度为190nm、后电池厚度为90nm时,器件的短路电流密度达到最大值。通过在中间连接层引入超薄金属Ag薄膜,利用光学谐振微腔效应,实现前后电池的电流匹配,可以进一步提高串联结构聚合物太阳能电池的性能。

Abstract

Polymer solar cells (PSCs) that harvesting clean solar energy has been considered as a promising candidate for the next generation of photovoltaic technology to solve the impending energy crisis.Compared with conventional inorganic solar cells,PSCs exhibited advantages,such as low cost,light-weight,and roll-to-roll processing on flexible substrates.In order to improve the performance of PSCs,a highly efficient donor polymer PTB7-Th combined with acceptor fullerene PC71BM was introduced as the subcell in the series-connected polymer tandem solar cells.The effects of active layer thickness and use of ultrathin Ag film on the short-current density (JSC) were studied based on transfer matrix method.It was found that the maximum JSC was achieved in the tandem device with a front cell active layer thickness of 190nm and a back subcell blend layer thickness of 90nm.The performance of the tandem cells can be further improved by inserting an ultrathin Ag layer in the interconnection layer with micro-cavity effect to realize the current matching in the subcells.

关键词

聚合物太阳能电池 / 串联结构 / 光学仿真 / 超薄金属Ag薄膜

Key words

polymer solar cells / tandem structure / optical modeling / ultrathin metal Ag film

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基于新型材料PTB7-Th的串联结构聚合物太阳能电池仿真研究[J]. 化工新型材料, 2019, 47(10): 134-136 DOI:

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基金资助

国家重点研发计划重大科学仪器设备开发重点专项(2016YFF0101908);国家自然科学基金(61705054);浙江省自然科学基金(LQ17F050002)

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