介孔TiO2载银纳米复合材料的制备及性能研究

邬艳君, 成程, 倪怡静, 张曼莹*

化工新型材料 ›› 2019, Vol. 47 ›› Issue (10) : 105 -109.

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化工新型材料 ›› 2019, Vol. 47 ›› Issue (10) : 105-109.
新材料与新技术

介孔TiO2载银纳米复合材料的制备及性能研究

    邬艳君, 成程, 倪怡静, 张曼莹*
作者信息 +

Preparation and property of m-TiO2/Ag nanocomposite

  • Wu Yanjun, Cheng Cheng, Ni Yijing, Zhang Manying
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摘要

运用醇热法制备介孔二氧化钛(m-TiO2),并借助光还原法制备m-TiO2载银(m-TiO2/Ag)复合材料,通过透射电镜和X射线衍射等手段对复合材料的形貌和组成进行表征,并以亚甲基蓝(MB)的脱色降解来表征不同Ag含量样品的光催化性能,通过生长曲线、最小抑菌浓度和抑菌环对其抗菌性能进行表征。结果表明:用醇热法制备的m-TiO2是以锐钛矿为主含有少量板钛矿的混晶,金属Ag颗粒沉积在m-TiO2表面;纳米银负载可显著提高m-TiO2的可见光光催化性能;亚甲基蓝的光催化降解反应遵循一级反应动力学模型;m-TiO2/Ag复合材料的抗菌性能随着载银量的增加而逐渐提高。

Abstract

Mesoporous titanium dioxide was prepared by the alcohol-thermal method.Silver modified mesoporous titania silver (m-TiO2/Ag) composite material was prepared by photoreduction method.The morphologies and compositions of the composites were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD).The photocatalytic performances of samples with different Ag content were characterized by degradation test of methylene blue (MB).The antibacterial properties were characterized by growth curves,minimal inhibitory concentrations and inhibition rings.The results showed that the prepared m-TiO2 was an anatase-based mixed crystal with a small amount of brookite and the metal Ag particles were deposited on the surface of m-TiO2.Nano-silver loading significantly improved the visible light photocatalytic performance of m-TiO2.The photocatalytic degradation reaction of methylene blue followed a first-order kinetic model.The antibacterial performance of mesoporous titanium dioxide gradually increased with the increase of silver loading.

关键词

介孔TiO2 / 纳米银 / 光催化 / 抗菌

Key words

mesoporous titanium dioxide / nanosilver / photocatalysis / antibacterial

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介孔TiO2载银纳米复合材料的制备及性能研究[J]. 化工新型材料, 2019, 47(10): 105-109 DOI:

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基金资助

国家自然科学基金青年基金(51508239);江苏省自然科学基金青年基金(BK20150245);江苏省研究生科研与实践创新计划项目(SJCX17-0778)

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